Adhesives shear tests

Pressure-sensitive adhesives are used in a great variety of applications, most commonly for adhesive tapes. In that case, they have to be tested by static shear test or dynamic shear test The difference between these two methods is that in static shear test a standard force is being applied to the test specimen and the adhesive failure is reported as the time it takes for failure to occur. The dynamic shear test involves a force being applied to the PSA tape at a specific rate of speed (typically 0.25 mm or 0.1 in. per minute). The value reported is as the peak force per unit area (Ib/in, also abbreviated as psi, and in SI units MPa) required to cause adhesive failure. The standards for adhesion shear tests are ASTM D3654, ISO EN 1943, and PSTC-107.i i ... 

Figure 1 Test specimen for adhesive shear testing.

NF 776-141 1988 Structural adhesives. Shear test for determining the stress/strain curve of an adhesive in a glued assembly. Test method. 

The principal type of shear test specimen used in the industry, the lap shear specimen, is 2.54 cm wide and has a 3.23-cm overlap bonded by the adhesive. Adherends are chosen according to the industry aluminum for aerospace, steel for automotive, and wood for constmction appHcations. Adhesive joints made in this fashion are tested to failure in a tensile testing machine. The temperature of test, as weU as the rate of extension, are specified. Results are presented in units of pressure, where the area of the adhesive bond is considered to be the area over which the force is appHed. Although the 3.23-cm ... 

Fig. 8. The dependence on contact angle of the magnitude and location of maximum stress concentration in a lap shear test. As the contact angle decreases, the stress concentration decreases, and its locus moves toward the center-plane of the adhesive phase. Redrawn from ref. [51].

Fig. 1, Schematic of commonly u.sed methods for testing the strength of adhesive joints, (a) Peel test. Note that the peel angle can be changed depending on the test requirements, (b) Double overlap shear test. In this test, the failure is predominantly mode II. (c) Single overlap shear test. In this test the failure mode is mixture of mode I and mode II. (d) Blister test.

One of the other benefits of incorporating polar monomers in the PSA is the enhancement in cohesive strength. This can be observed in the form of higher shear holding in a static shear test and/or better creep resistance of the adhesive when subject to a constant load. 

Low surface energy substrates, such as polyethylene or polypropylene, are generally difficult to bond with adhesives. However, cyanoacrylate-based adhesives can be effectively utilized to bond polyolefins with the use of the proper primer/activa-tor on the surface. Primer materials include tertiary aliphatic and aromatic amines, trialkyl ammonium carboxylate salts, tetraalkyl ammonium salts, phosphines, and organometallic compounds, which are initiators for alkyl cyanoacrylate polymerization [33-36]. The primer is applied as a dilute solution to the polyolefin surface, solvent is allowed to evaporate, and the specimens are assembled with a small amount of the adhesive. With the use of primers, adhesive strength can be so strong that substrate failure occurs during the course of the shear tests, as shown in Fig. 11. 

Resistance to common aircraft fluids such as water, salt water, hydraulic fluid and jet fuel is determined by additional shear testing after exposure to these fluids. Since adhesives are typically only exposed at bond edges, are protected by secondary primers and enamels and are not expected to be exposed to these fluids (save for water) for extended periods, exposure time prior to testing is relatively short. Lastly, the adhesive is tested for propensity to creep rupture under load in standard and aggressive environments. This testing indicates whether the polymer is crosslinked sufficiently to resist long-term creep under low load. 

The lap shear test involves measuring the adhesive shear strength between two surface fluorinated polyolefin sheet tokens that are adhesively secured with a reinforcement resin. The tokens are individually reinforced with steel backing plates to eliminate flexural distortion in the shear joint. Lap shear tests carried out with various reinforcing polyester-type resins, contrasting fluorination and oxyfluorination as surface treatment, are shown in Table 16.8. 

Flat laminated panels are manufactured using fluorinated sheet substrates. The manufacturing of these test panels simulates the production process used to manufacture the fiberglass-reinforced pipes. The BS6464 test prescribes a minimum adhesive shear and peel strength of 7 MPa and 7 N/mm, respectively. Representative values for both tests are given in Tables 16.9 and 16.10 below. 

The 6th material Is a condensation-cure product which has been previously used for medical Implant protection (I). As verified by lap shear tests, (described below), the first 3 elastomers provide minimal adhesion In the absence of a surface primer. The last 3 are self-prlmlng materials. To permit visual examination, we tried to select clear materials. All of the elastomers are clear except for types 5 and 6. 

Thus, fundamentally the interest is in testing the limits and theory of polymer behavior in end-tethered systems, e.g., viscoelastic behavior, wetting and surface energies, adhesion, shear forces relevant to tribology, etc. It should be noted that relevant surfaces and interfaces can also refer to polymers adsorbed in liquid-liquid, liquid-gas, solid-gas, and solid-liquid interfaces, which makes these polymer systems also of prime importance in interfacial science and colloidal phenomena (Fig. 2). Correspondingly, a wide number of potential applications can be enumerated ranging from lubrication and microelectronics to bioimplant surfaces. 

Another type of shear test involves testing under heated conditions. The shear adhesion failure test (SAFT) (FINAT FTM 8, PSTC-7) is a static shear test administered to a PSA sample under increasing temperature at a rate typically of 1 or 2°C per minute. The recorded SAFT value is the temperature at which the adhesive bond fails. 

Two types of composite physical property tests were conducted to measure properties which are sensitive to the degree of adhesion and failure mode of the fiber-matrix interphase. Short beam shear tests (ASTM D2344-84) were conducted on 18 ply unidirectional laminates. The support span-to-thickness ratio... 

Quantitative confirmation of this outcome was obtained by shear tests, for which specimens were prepared both with and without the primer, a steel strip being bonded over the grit by an epoxide adhesive and the test carried out after curing of the second adhesive. Adhesion strengths recorded for the grit and adhesive were as shown in Table VII. 

In applications where possible degrading elements exist, candidate adhesives must be tested under simulated service conditions. Standard lap shear tests, such as ASTM D1002, which use a single rate of loading and a standard laboratory environment, do not yield optimal information on the service life of the joint. Important information such as the maximum load that the adhesive joint will withstand for extended periods and the degrading effects of various chemical environments are addressed by several test methods. Table 15.2 lists common ASTM environmental tests that are often reported in the literature. 

Tensile Shear Tests. The lap shear or tensile shear test measures the strength of the adhesive in shear. It is the most common adhesive test because the specimens are inexpensive,... 

D 5999 D 6004 D 6005 D 6105 Test Method for Noninterference of Adhesives in Repulping Test Method for Determining Adhesive Shear Strength of Carpet Adhesives Test Method for Determining Slump Resistance of Carpet Adhesives Practice for Application of Electrical Discharge Surface Treatment (Activation) of Plastics for Adhesive Bonding... 

High peel strength with cohesive failure is possible by increasing the 0K/NC0 ratio. At a higher ratio, slight creep is observed at room temperature in the static shear test., 0H/NC0 ratios above 2.0 for Hycar 2103 and 1.8 for Hycar 2106 result in adhesives having incomplete cures with low peel values and poor static shear strength. 

Figure V demonstrates the effect of adhesive dry coating weight on 180° peel strength and rolling ball tack with OH/NCO ratios of 1.7 and 1.3 for Hycar 2103 and Hycar 2106, respectively. Static shear tests run both at room temperature and 70°C show no creep for both systems throughout the thickness range tested.

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