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Acrylic acid hydration

K = Equilibrium constant for acrylic acid hydration, dimension-... [Pg.263]

This concept covers most situations in the theory of AB cements. Cements based on aqueous solutions of phosphoric acid and poly(acrylic acid), and non-aqueous cements based on eugenol, alike fall within this definition. However, the theory does not, unfortunately, recognize salt formation as a criterion of an acid-base reaction, and the matrices of AB cements are conveniently described as salts. It is also uncertain whether it covers the metal oxide/metal halide or sulphate cements. Bare cations are not recognized as acids in the Bronsted-Lowry theory, but hydrated... [Pg.15]

AB cements are not only formulated from relatively small ions with well defined hydration numbers. They may also be prepared from macromolecules which dissolve in water to give multiply charged species known as polyelectrolytes. Cements which fall into this category are the zinc polycarboxylates and the glass-ionomers, the polyelectrolytes being poly(acrylic acid) or acrylic add copolymers. The interaction of such polymers is a complicated topic, and one which is of wide importance to a number of scientific disciplines. Molyneux (1975) has highlighted the fact that these substances form the focal point of three complex and contentious territories of sdence , namely aqueous systems, ionic systems and polymeric systems. [Pg.45]

Water occurs in glass-ionomer and related cements in at least two different states (Wilson McLean, 1988 Prosser Wilson, 1979). These states have been classified as evaporable and non-evaporable, depending on whether the water can be removed by vacuum desiccation over silica gel or whether it remains firmly bound in the cement when subjected to such treatment (Wilson Crisp, 1975). The alternative descriptions loosely bound and tightly bound have also been applied to these different states of water combination. In the glass-poly(acrylic acid) system the evaporable water is up to 5 % by weight of the total cement, while the bound water is 18-28 % (Prosser Wilson, 1979). This amount of tightly bound water is equivalent to five or six molecules of water for each acid group and associated metal cation. Hence at least ten molecules of water are involved in the hydration of each coordinated metal ion at a carboxylate site. [Pg.49]

Yokoyama, T. Hiraoko, K. (1979). Hydration and thermal transition of poly(acrylic acid) salts. Polymer Preprints of the American Chemical Society, Division of Polymer Chemistry, 20, 511-13. [Pg.55]

Figure 4.8 Cylindrical and spherical hydration regions around poly(acrylic acid) at various degrees of neutralization (or charge densities). Based on Ikegami (1964). Figure 4.8 Cylindrical and spherical hydration regions around poly(acrylic acid) at various degrees of neutralization (or charge densities). Based on Ikegami (1964).
Flocculants cause colloidal clay particles to coagulate thus promoting separation from the drilling fluid which has been circulated down the wellbore and returned to the surface. The treated fluid may then be pumped back down the well bore. Sodium chloride, hydrated lime, gypsum, sodium tetraphosphate, polyacrylamide, poly(acrylamide-co-acrylic acid), cationic polyacrylamides, and poly(ethylene oxide) have been used commercially. [Pg.12]

Ring opening of the pyrazole ring of 133 with benzylamine, ammonium hydroxide, and hydrazine hydrate takes place regioselectively affording the acrylic acid esters 134 (Equation 13) <2003MI1>. [Pg.388]

The fundamental property at work is the interaction of water and polymer, hi the Kuhn experiments, the acrylic acid functioned as the contractile unit. A change in pH or ionic strength will either hydrate or dehydrate a gel. This affects the size of the molecule, which in turn causes the molecule to contract or expand. This phenomenon is most pronounced in ionic polymers. [Pg.178]

Like alkenes, the double bonds of ,/3-unsaturated acids can be brominated, hydroxylated, hydrated, and hydrobrominated, although the reactions often are relatively slow. In the addition of unsymmetrical reagents the direction of addition is opposite to that observed for alkenes (anti-Markownikoff). Thus propenoic (acrylic) acid adds hydrogen bromide and water to form 3-bromo-and 3-hydroxypropanoic acids ... [Pg.841]

Superficially, it might be expected that coordinated acrylic acid would undergo a similar type of hydration reaction with nucleophilic addition taking place at the /3-carbon (the acid is ester-like when coordinated). Experimentally21 hydration is not observed (Scheme 48), but both the 2- and... [Pg.476]

Reaction of 2-aminopyridines with acrylic acid or methacrylic acid in boiling water for 2-20 hours gave betaine hydrates 262 (R3 = H) in 11-88% yields (Scheme 20) (92KGS80). When 2-aminopyridine reacted with methyl metharylate in acetic acid for 24 hours or 2-aminopyridine and its 5-bromo and 5-chloro derivatives reacted with acrylic acid in boiling toluene for 24 hours or 2-aminopyridine reacted with crotonic acid in boiling toluene for 20 hours, 3-(2-pyridylamino)propionic acid derivatives 263 were the products. When 5-chloro-2-aminopyridine reacted with acrylic... [Pg.166]

More recently, Gangneux et al (11) developed a method for grafting acrylic acid onto cellulose powder, "Solka Floe," for use in textile waste treatment. The cellulose was treated with ceric ion in aqueous solution prior to its reaction with acrylic acid. A benzene-acrylic acid solution was used for grafting to reduce homopolymerization. Presumably, the hydrated ceric ion would not diffuse into the monomer solution to initiate homopolymerization although the reverse could still take place. They obtained grafting yields up to approximately 70% accompanied by 45% homopolymer. In the present investigation, their method is extended to fibers and additional emphasis is placed on the reduction of homopolymerization. [Pg.46]

The following substances are recommended starting materials for unsaturated polyesters fumaric acid, maleic acid, methacrylic acid, adipic acid, phthalic acid, resi-nic acid, isophthalic acid, terephthalic acid, hydrated or halogenated phthalic acids, aliphatic and substituted aliphatic single and multi-functional alcohols up to C)8, alkoxylated and hydrated phenols and bisphenols, styrene, vinyltoluene, acrylic acid and methacrylic acid esters of the Ci-C4 alcohols, and tricyclodecane dimethanol. [Pg.37]

The reactivity of an organic compound toward eaq depends on its functional groups because the main hydrocarbon chain is non-reactive. Aliphatic alcohols, ethers, and amines are also nonreactive (k 106 M 1 s-1), although alkylammonium ions show a slight reactivity and can transfer a proton to the hydrated electron. Isolated double bonds are practically nonreactive, for ethylene k <2-5 X 106 M -1 s-1, but conjugated systems or double bonds with an electron withdrawing group attached to them are very reactive. For example, butadiene and acrylic acid react with practically diffusion controlled rates ( 10 0 M -1 s-1). [Pg.233]

Acrylamide with a demand of 200,000 tons year" is one of the most important commodities in the world. It is used for the preparation of coagulators, soil conditioners, stock additives for paper treatment, and in leather and textile industry as a component of synthetic fibers. Conventional chemical synthesis involving hydration of acrylonitrile with the use of copper salts as a catalyst has some disadvantages rate of acrylic acid formation higher than acrylamide, by-products formation and polymerization, and high-energy inputs. To overcome these limits since 1985, the Japanese company Nitto Chemical Industry developed a biocatalyzed process to synthesize... [Pg.400]

Propenoic acid is commonly known as acrylic acid (p. 172), and j(3-hydroxy propionic acid is therefore named hydracrylic acid, i.e., hydrated acrylic acid. [Pg.246]

Here the relationship is that of loss or addition of water, the name hydr-acrylic meaning hydrated acrylic, whereas the relationship between ciimamic acid and hydrociimamic is loss or addition of hydrogen, the name hydro-cinnamic meaning hydrogenated cinnamic. The same relationship is expressed in the case of propionic acid if we name it hydro-acrylic acid. [Pg.697]


See other pages where Acrylic acid hydration is mentioned: [Pg.263]    [Pg.415]    [Pg.263]    [Pg.415]    [Pg.502]    [Pg.564]    [Pg.74]    [Pg.75]    [Pg.36]    [Pg.73]    [Pg.590]    [Pg.335]    [Pg.769]    [Pg.604]    [Pg.285]    [Pg.192]    [Pg.125]    [Pg.218]    [Pg.273]    [Pg.55]    [Pg.56]    [Pg.141]    [Pg.75]    [Pg.135]    [Pg.181]    [Pg.331]    [Pg.130]    [Pg.1611]    [Pg.217]   
See also in sourсe #XX -- [ Pg.868 ]

See also in sourсe #XX -- [ Pg.868 ]




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Acid hydrates

Acids hydrated

Acrylic hydration

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