Zinc stearate additive

The basic metal salts and soaps tend to be less cosdy than the alkyl tin stabilizers for example, in the United States, the market price in 1993 for calcium stearate was about 1.30— 1.60, zinc stearate was 1.70— 2.00, and barium stearate was 2.40— 2.80/kg. Not all of the coadditives are necessary in every PVC compound. Typically, commercial mixed metal stabilizers contain most of the necessary coadditives and usually an epoxy compound and a phosphite are the only additional products that may be added by the processor. The requited costabilizers, however, significantly add to the stabilization costs. Typical phosphites, used in most flexible PVC formulations, are sold for 4.00— 7.50/kg. Typical antioxidants are bisphenol A, selling at 2.00/kg Nnonylphenol at 1.25/kg and BHT at 3.50/kg, respectively. Pricing for ESO is about 2.00— 2.50/kg. Polyols, such as pentaerythritol, used with the barium—cadmium systems, sells at 2.00, whereas the derivative dipentaerythritol costs over three times as much. The P-diketones and specialized dihydropyridines, which are powerful costabilizers for calcium—zinc and barium—zinc systems, are very cosdy. These additives are 10.00 and 20.00/kg, respectively, contributing significantly to the overall stabilizer costs. Hydrotalcites are sold for about 5.00— 7.00/kg. 

EPDM-Derived Ionomers. Another type of ionomer containing sulfonate, as opposed to carboxyl anions, has been obtained by sulfonating ethylene—propjlene—diene (EPDM) mbbers (59,60). Due to the strength of the cross-link, these polymers are not inherently melt-processible, but the addition of other metal salts such as zinc stearate introduces thermoplastic behavior (61,62). These interesting polymers are classified as thermoplastic elastomers (see ELASTOLffiRS,SYNTHETIC-THERMOPLASTICELASTOLffiRS). 

Butyl slurry at 25—35 wt % mbber continuously overflows from the reactor through a transferline to an agitated flash dmm operating at 140—160 kPa (1.4—1.6 atm) and 55—70°C. Steam and hot water are mixed with the slurry in a nozzle as it enters the dmm to vaporize methyl chloride and unreacted monomers that pass overhead to a recovery system. The vapor stream is compressed, dried over alumina, and fractionated to yield a recycle stream of methyl chloride and isobutylene. Pure methyl chloride is recovered for the coinitiator (AlCl ) preparation. In the flash dmm, the polymer agglomerates as a coarse cmmb in water. Metal stearate, eg, aluminum, calcium, or zinc stearate, is added to control the cmmb size. Other additives, such as antioxidants, can also be introduced at this point. The polymer cmmb at 8—12 wt % in water flows from the flash dmm to a stripping vessel operated under high vacuum to... 

Accelerated sulphur systems also require the use of an activator comprising a metal oxide, usually zinc oxide, and a fatty acid, commonly stearic acid. For some purposes, for example where a high degree of transparency is required, the activator may be a fatty acid salt such as zinc stearate. Thus a basic curing system has four components sulphur vulcanising agent, accelerator (sometimes combinations of accelerators), metal oxide and fatty acid. In addition, in order to improve the resistance to scorching, a prevulcanisation inhibitor such as A -cyclohexylthiophthalimide may be incorporated without adverse effects on either cure rate or physical properties. 

After reaction for 15 min, the band near 3295 cm (not shown in Fig. 13) decreased significantly in intensity, indicating that the mono-substituted acetylene groups were reacting. New bands also appeared near 1539 and 1512 cm . After reaction for 30 min, several additional bands appeared near 1011, 1030, 1085, 1232, 1320, 1430, and 1515 cm. The bands near 1011, 1030, 1085, 1232, 1320, and 1430 cm were clearly related to the benzothiazole sulfenamide fragment of DCBS while the band near 1539 cm was related to zinc stearate. 

ADCA is activated by zinc oxide, zinc stearate (strongly) and urea (slowly). Barium stearate, calcium stearate and triethanolamine, when added at 10 phr, moderately activate gas evolution from ADCA. They do not have very much effect on decomposition rate when the cure temperature is at 170 °C, but a marked effect above 180 °C. The rate of decomposition of ADCA is significantly influenced by the particle size of the additive. Effective dispersion and heat transfer through the particle can be a means of controlling the cell quality and the manufacturing method for the product. The correct particle size is selected to achieve the optimum balance between cure and cell development. 

Zinc stearate is formed during the vulcanisation process with sulphur accelerated compounds, but the addition of zinc stearate alone as replacement for stearic acid and zinc oxide does not produce... 

Kyowa Chemical Industries (Japan) were the first to demonstrate that adding Mg/Al LDHs to PVC in combination with other additives such as zinc stearate and tin maleate leads to an enhancement in thermal stability of the resin [231]. The role of the LDH in absorbing HCl was confirmed experimentally by Van der Ven et al. [232], who measured the capacity of LDHs... 

Typically, solid stabilizers utilize natural saturated fatty acid ligands with chain lengths of Cg—Clg. Zinc stearate [557-05-1], zinc neodecanoate [27253-29-8], calcium stearate [1592-23-0], barium stearate [6865-35-6], and cadmium laurate [2605-44-9] are some examples. To complete the package, the solid products also contain other solid additives such as polyols, antioxidants, and lubricants. Liquid stabilizers can make use of metal soaps of oleic acid, tall oil acids, 2-ethyl-hexanoic acid, octylphenol, and nonylphenol. Barium bis(nonylphenate) [41157-58-8], zinc 2-ethylhexanoate [136-53-8], cadmium 2-ethylhexanoate [2420-98-6], and overbased barium tallate [68855-79-8] are normally used in the liquid formulations along with solubilizers such as plasticizers, phosphites, and/or epoxidized oils. The majority of the liquid barium—cadmium formulations rely on barium nonylphenate as the source of that metal. There are even some mixed metal stabilizers supplied as pastes. The U.S. FDA approved calcium—zinc stabilizers are good examples because they contain a mixture of calcium stearate and zinc stearate suspended in epoxidized soya oil. Table 4 shows examples of typical mixed metal stabilizers. 

Another good example of using Raman spectroscopy in the polymer industry is to investigate polymer blends. Raman microimages have been used to investigate the spatial distributions of the components in a blend of brominated poly(isobutylene-co-para-methylstyrene (BIMS) and cis-1-4-polybutadiene (BR) containing silica, zinc stearate, thiate, and other additives (21). A Raman spectrum of a blend is shown in Fig. 7-33. Specific bands can be assigned to BIMS, BR, silica, and zinc stearate. A 10 x 10 xm contour... 

Figure 7-33 Typical Raman spectrum for a BIMS-BR blend with silica, zinc stearate, thiate U, and other additives, (a) A band at about 490cm-1 assigned to silica (b) a band at 714cm-1 assigned to the CH2 rocking mode of the BIMS backbone (c) a band at 1,118cm-1 assigned to hydrocarbon chain vibrations of zinc stearate (d) a band at 1,648 cm-1 assigned to the C=C stretching vibrations of the cis-polybutadiene backbone. (Reproduced with permission from Ref. 21.)...

Zinc is used in ointments and eye-lotions and is a constituent of different forms of insulin. In the former type of applications zinc oxide, zinc stearate and zinc undecanoate may be encountered in a variety of creams, ointments and pastes. Moody and Taylor [104] dissolved the residue from such samples after ether extraction (lg in 5 ml ether) in concentrated hydrochloric acid. After dilution, the determination can be completed at 213.9 nm in the air/acetylene flame where interferences are not normally encountered. Various analytical techniques for determining zinc in insulin injections have been critically compared [105] atomic absorption was preferred as being accurate, fast and precise. Spielhotz and Toralballa [106] reported a method capable of determining low levels of zinc in insulin. The sample (5 mg) was suspended in water (10 ml), 1 drop of 6M hydrochloric acid was added to effect dissolution. After making up to 50 ml the determination was completed using an air/acetylene flame. Alternatively protamine insulin solution (1 ml) may be diluted to 50 ml after the addition of 1 drop of acid. 

Slurry is transferred from reactor to a stirred flash drum where it is mixed with steam and hot water (=60° C, 1.5 bar). Methyl chloride and unreacted monomers are flashed off overhead and recycled, whereas particles agglomerate as coarse crumbs, the size of which is controlled by addition of zinc stearate. The suspension is then stripped to eliminate traces of volatiles, and the rubber is separated by filtration, dewatered by extrusion, dried and sent to a finishing unit for baling, packaging, and weighing. 

A further example is the zinc stearate-catalyzed addition of malonic ester derivatives to acetylene. The reaction also takes place with monosubstituted malonic esters [46]. C-vinyl malonic esters have found an application, for example, in the synthesis of barbiturates. 

The binders and lubricants added to the UO2 powder prior to granulation include materials such as polyethylene glycol (Carbowax), polyvinyl alcohol (PVA), paraffin, zinc stearate, or stearic acid. The additives may be incorporated dry (in amounts up to 3 wt %), or in solution (aqueous, in alcohol, or in carbon tetrachloride). The binders... 

Duvdevani(40) have been directed at modification of ionomer properties by employing polar additives to specifically interact or plasticize the ionic interactions. This plasticization process is necessary to achieve the processability of thermoplastic elastomers based on S-EPDM. Crystalline polar plasticizers such as zinc stearate can markedly affect ionic associations in S-EPDM. For example, low levels of metal stearate can enhance the melt flow of S-EPDM at elevated temperatures and yet improve the tensile properties of this ionomer at ambient temperatures. Above its crystalline melting point, ca. 120°C, zinc stearate is effective at solvating the ionic groups, thus lowering the melt viscosity of the ionomer. At ambient temperatures the crystalline additive acts as a reinforcing filler. 

In order to enable melt processing of ion containing polymers, such as S-EPDM, it is necessary to introduce a mechanism that weakens the ionic interactions. This can be achieved by the addition of a polar ingredient that would plasticize" ionic domains at elevated temperatures only. A variety of such ionic-plasticizers were described by Makowski and Lundberg (10). A particularly attractive combination was found to be zinc stearate with a zinc salt of S-EPDM. It was shown that for such a combination melt... 

This paper attempts to further explore the modification of ionic associations by a crystalline ionic plasticizer, such as zinc stearate, at the solid state. Mechanical properties, swelling behavior, and morphological aspects were studied in order to better understand the role of such crystalline polar additives. 

From the various data reviewed and presented here, it is evident that a crystalline polar additive such as zinc stearate acts as... 

Metal sulfonate-containing ethylene-propylene-diolefin ter-polymers (EPDM) were plasticized with stearic acid and derivatives for the reduction of the melt viscosities of these ionomers through interaction with the very strong ionic associations. Substantial improvements in melt flow were achieved with stearic acid and the zinc, lead, and ammonium stearates, while other metal stearates were ineffective. Zinc stearate and lead stearate not only markedly improved melt flow but, remarkably, also enhanced the mechanical properties of the plasticized systems. These unique additives were fully compatible with the EPDM ionomers and provided thermoelastic systems with excellent physical properties and ready processability. 

Therefore, plasticized compositions using DOP and zinc stearate at various levels were prepared by melt blending, and their tensile properties and flow behavior are shown in Table II. It is seen that the addition of zinc stearate at modest levels (5 and 10 pph) markedly improves melt flow as measured by melt index. Furthermore, this improvement in flow is achieved without a loss in tensile properties in fact, a modest improvement is noted. For comparison, the unplasticized, unsulfonated PS exhibited a melt index of 30 under these conditions. Therefore, a combi-... 

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