Metal sintering

The methanation reaction is carried out over a catalyst at operating conditions of 503—723 K, 0.1—10 MPa (1—100 atm), and space velocities of 500—25,000 h . Although many catalysts are suitable for effecting the conversion of synthesis gas to methane, nickel-based catalysts are are used almost exclusively for industrial appHcations. Methanation is extremely exothermic (AT/ qq = —214.6 kJ or —51.3 kcal), and heat must be removed efficiently to minimise loss of catalyst activity from metal sintering or reactor plugging by nickel carbide formation. 

PROCESS MATERIAL. IMPACT EXTRUSION COLD FORMING COLD EXTRUSION SHEET METALWORK MACHINING POWDER METAL SINTERING... 

There is a material to process compatibility risk for impact extrusion, cold forging, cold extmsion, sheet metalworking, machining and powder metal sintering processes because their respective process capability maps relate to the ideal material case. 

POWDER METAL SINTERING PROCESS CAPABILITY MAP (RADIAL TOLERANCES ONLY)... 

As was noted for experiments HGR-12, HGR-13, and HGR-14, the rate of catalyst deactivation increased as the fresh gas feed rate increased. It is possible that higher rates of carbon deposition and metal sintering occur at the higher feed rates with resultant higher deactivation rates. 

The long-term stability of the Ru/Ti02 catalyst was studied under various reaction conditions and the spent catalysts were characterized for assessing the reasons of deactivation. It was observed that the rate exhibits a rapid reduction at the initial several hours of reaction, followed by a slow and continuous deactivation. Analysis of the spent catalyst, by H2 adsorption after removing surface carbon, showed that the initial rapid reduction of activity is mainly due to metal sintering, while the continuous and slow deactivation is related to the occurrence of the SMSl phenomenon at the later part of the catalyst bed, where reducing conditions prevail. In order to avoid these processes which lead to catalyst deactivation, Ti02... 

Like NiO, CoO and FeO are characterized by the same crystal structure as MgO and have comparable lattice parameters, and, hence, can form CoO/MgO and FeO/MgO solid solutions. Therefore, it was expected that CoO/MgO and FeO/MgO would inhibit carbon deposition and metal sintering, just as Ni/MgO does, resulting in high stability (171). 

There seems to be several mechanisms leading to the activity loss oxidation of cobalt metal, sintering of cobalt metal particles as well as sintering of the support and formation of stable cobalt-support metal oxides (silicates or aluminates). Oxidation by water is a key issue, possibly occurring on all supports and on unsupported cobalt. A thermodynamic analysis of this effect was reported by van Steen et al.,40 and they describe the FTS reaction system in terms of reactions (1) and (2) below ... 

Catalysts were prepared by deposition-precipitation method over a commercial CeOz. Among the catalysts, Ir/Ce02 exhibited a stable activity for 300 h time-onstream due to the prevention of metal sintering and coke resistance of highly dispersed Ir... 

Special metals Sinter processes Silicon chemistry Float glass... 

An efficient, low temperature oxidation catalyst was developed based on highly disperse metal catalyst on nanostructured Ti02 support. Addition of dopants inhibits metal sintering and prevents catalyst deactivation. The nanostructured catalyst was formulated to tolerate common poisons found in environments such as halogen- and sulfur-containing compounds. The nanocatalyst is capable of oxidizing carbon monoxide and common VOCs to carbon dioxide and water at near ambient temperatures (25-50 °C). 

Promoters are added to Pt catalysts because the promoted catalyst with modified electronic properties leads to a decrease in the activity for coke formation and also in the rate of metal sintering. Several promoted systems have been reported in the literature including for environmnetal pollution (vehicle exhaust emission) control and some are summarized here. 

Support—filtration foil made from an organic material plate, tube, or molder made from a ceramic, carbon, or metal sinter... 

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