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Transport behavior, lead

The residence time and, therefore, the reaction behavior of particles depend on the transport conditions of particles in the laminar flo v, if homogeneous fluids are applied. The non-linear velocity gradients inside microchannels cause unsymme-trical shear forces. As a result, particles are not only brought to rotation, but are also transported to the central region of the microchannel (Magnus effect). Therefore, the fluid transport behavior leads to an enhancement of particle concentration in the center of microchannels and to a lo vering of their concentration near the valls. [Pg.792]

It is also evident that this phenomenological approach to transport processes leads to the conclusion that fluids should behave in the fashion that we have called Newtonian, which does not account for the occurrence of non-Newtonian behavior, which is quite common. This is because the phenomenological laws inherently assume that the molecular transport coefficients depend only upon the thermodyamic state of the material (i.e., temperature, pressure, and density) but not upon its dynamic state, i.e., the state of stress or deformation. This assumption is not valid for fluids of complex structure, e.g., non-Newtonian fluids, as we shall illustrate in subsequent chapters. [Pg.8]

The transport behavior of Li+ across membranes has been the focus of numerous studies, the bulk of which have concentrated upon the human erythrocyte for which the Li+ transport pathways have been elucidated and are summarized below. The movement of Li+ across cell membranes is mediated by transport systems which normally transport other ions, therefore the normal intracellular and subcellular electrolyte balance is likely to be disturbed by this extra cation. Additionally, Li+ has been shown to increase membrane phospholipid unsaturation in rat brain, leading to enhanced fluidity in the membrane, which could have repercussions for membrane-associated proteins and for membrane transport properties. [Pg.12]

Summary. We study how the single-electron transport in clean Andreev wires is affected by a weak disorder introduced by impurity scattering. The transport has two contributions, one is the Andreev diffusion inversely proportional to the mean free path i and the other is the drift along the transverse modes that increases with increasing . This behavior leads to a peculiar re-entrant localization as a function of the mean free path. [Pg.291]

Diffusive and convective transport processes introduce flexibility in the design of catalyst pellets and in the control of FT synthesis selectivity. Transport restrictions lead to the observed effects of pellet size, site density, bed residence time, and hydrocarbon chain size on chain growth probability and olefin content. The restricted removal of reactive olefins also allows the introduction of other intrapellet catalytic functions that convert olefins to other valuable products by exploiting high intrapellet olefin fugacities. Our proposed model also describes the catalytic behavior of more complex Fe-... [Pg.295]

Nanoparticle transport in aifeous systems. Nanoparticles are intermediate in size between most clay-sized materials (and colloids) and molecules. Their transport behavior should vary accordingly. Important factors will be nanoparticle size and aggregation state. However, size-dependent surface properties may lead to unanticipated behavior. This could arise, for example, due to modified surface reactivity compared to macroscopic equivalents. Most research on transport of submicron-scale materials has dealt with larger particles or colloidal aggregates. Specific consideration of transport of very small particles may be worthwhile. [Pg.50]

Often it is the economics implicit in the FOQ equation, or a similar thought process, that governs decisions such as those made by production control and transportation managers up and down the supply chain. The company selling to the final customer orders material in fixed amounts from suppliers according to reorder points and minimum order quantities. Others back up the chain duplicate the behavior, leading to a supply chain bloated with extra inventory and operating expense. [Pg.355]

As mentioned earlier, CB is prone to oxidation, the so-called carbon corrosion, which results in the loss of surface area, changes in the pore structure and finally also leads to sintering of the supported nanoparticles and eventually their loss from the support surface. This affects both the kinetics of the reaction and the electrode s mass transport behavior resulting in a significant loss of performance with operation time. Consequently, carbon support durability is considered to be a major barrier for the successful commercialization of fuel cell technology in the automotive sector. So much so, during the last decade, more than 60 publications dealt with carbon corrosion mechanisms in fuel cell apphcation [82]. [Pg.258]

The analysis of a-active components in hot particles showed a quantitative relationship which allowed the calculation of the integral a activity from the measured Ce Y-ray intensity about 80% of the measured a activity was caused by m. In the release and transport behavior, the actinides proved to behave similar to cerium. A comparative evaluation of the results of analyses of different particles leads to the conclusion that the composition of the fuel of various fuel rods differed considerably. Likewise, comparison with the results reported from Scandinavia led to the suggestion that hot particles deposited in Poland probably originated from a different region of the Chernobyl reactor. [Pg.708]

Akey performance limitation in the polymer electrolyte fuel cell (PEFC) originates from the multiple, coupled and competing, transport interactions in the constituent porous components. The suboptimal transport behavior resulting from the underlying complex and multifunctional microstmctures in the catalyst layer (CL), gas diffusion layer (GDL) and microporous layer (MPL) leads to water and thermal management issues and undesirable performance loss. Therefore, it is imperative to understand the profoimd influence of the disparate porous microstmctures on the transport characteristics. In this chapter, we highhght the stochastic microstmcture reconstmction technique and direct transport simulation in the CL, GDL and MPL porous stmctmes in order to estimate the effective transport properties and imderstand the microstmctural impact on the imderlying transport behavior in the PEFC. [Pg.233]

Serotonin, also known as 5-hydroxytryptamine (5-HT) is biosynthesized from tryptophan and is a neurotransmitter. Serotonin plays an important role in many behaviors including sleep, appetite, memory, and mood [52]. People with depressive disorders exhibit low levels of serotonin in the synapses. Protonated serotonin binds to a serotonin reuptake transporter protein, sometimes referred to as the serotonin transporter (SERT) and is then moved to an inward position on the neuron and subsequently released into the cjdoplasm. Selective serotonin reuptake inhibitors (SSRI) bind with high affinity to the serotonin binding site of the transporter. This leads to antidepressant effects by increasing extracellular serotonin levels which in turn enhances serotonin neurotransmission [53]. The SSRI class of antidepressants has fewer side effects than the monoamine oxidase inhibitors. [Pg.199]


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See also in sourсe #XX -- [ Pg.12 ]




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