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Threshold values theory

The adsorption of HPAM on sand (Figure 4) is not detected below a threshold value of Ca2+ due to strong electrostatic repulsion between the polyelectrolyte and the highly charged negative surface. This threshold value, which was also observed in the case of monovalent ions (9), represents the point where the critical adsorption energy is overcome, and once this value is surpassed, adsorption increases sharply. This form of adsorption behavior is in line with predictions of theories on polyelectrolyte adsorption (20). [Pg.232]

The second RPT criterion relates to the temperature of the hot liquid. That is, this temperature must exceed a threshold value before an RPT is possible. From one theory of RPTs, the superheated-liquid model (described later), this criterion arises naturally, and the threshold hot-liquid temperature is then equal to the homogeneous nucleation temperature of the colder liquid T. This temperature is a characteristic value for any pure liquid or liquid mixture and can be measured in independent experiments or estimated from theory. From alternate RPT theories, the threshold temperature may be equated, approximately, to the hot fluid temperature at the onset of stable film boiling. [Pg.107]

According to filler theory, connectivity can be achieved at lower values when the filler form is plates rather than spheres. Depending on the proportions of the plates and whether or not an inactive phase is included in the blend, connectivity can be achieved at 8 to 16% (v/v) filler (4). The starch-plastic blends developed by Otey (2) have a laminate structure when the starch content is under 30% by volume (Figure 1) and the threshold for microbial attack on these materials is under 13% starch by volume (Figure 2). This low threshold value can be explained by considering the LDPE as a non-conductive (enzyme-impermeable) phase combined with a conductive phase of starch-EAA complex. [Pg.77]

Below a certain threshold resolution, no valley can be observed between two adjacent peaks in a chromatogram. In that case the value for any of the peak-valley ratios would equal zero. In theory, the value for Rs and S would exceed zero for any two peaks that have different retention times (At > 0). In practice, this difference vanishes if the presence of two peaks cannot be discerned from the chromatogram. However, the occurrence of ill-resolved peaks in a chromatogram may be recognized visually at resolutions well below 0.6 (the threshold value below which P equals zero for Gaussian peaks of equal height) (see ref. [401], figure 2.11, p.38). Moreover, there are several techniques which may be of... [Pg.129]

Bedaux and Kooijman 1994 Kooijman 1996 Newman and McCloskey 1996, 2000 Zhao and Newman 2007). This is not just an academic discussion the 2 theories lead to different time courses of mortality at constant exposure (Kooijman 1996) (see Figure 2.10) and have very different consequences for sequential exposure (Newman and McCloskey 2000 Zhao and Newman 2007). In reality, both sensitivity difference and stochasticity are likely to play a role in mortality. Individuals also differ in sensitivity, especially in field populations, but there is clearly a substantial stochastic component involved in mortality that cannot be ignored. The method to deal with stochastic events in time is survival analysis or time-to-event analysis (see Bedaux and Kooijman 1994 Newman and McCloskey 1996). For industrial practices, this method has a long history as failure time analysis (see, e.g., Muenchow 1986). Bedaux and Kooijman (1994) link survival analysis to a TK model to describe survival as a function of time (i.e., the hazard rate is taken proportional to the concentration above a threshold value). Newman and McCloskey (1996) take an empirical relationship between external concentration and hazard rate. [Pg.78]

An odor can be described by the combination of threshold value and odor quality. The threshold value, the lowest concentration that creates an odor impression, can be considered the intensity factor, whereas the odor quality describes the character of the aroma. As has been mentioned under olfactory theories, attempts at reducing the number of characteristic odor qualities to a small number have not been successful. In many cases, the aroma and flavor of a food can be related to the presence of one or a few compounds that create an impression of a particular food when smelled alone. Such compounds have been named contributory flavor compounds by Jennings and Sevenants (1964). Some such compounds are the pyrazines, which give the odor quality of green bell peppers nootkatone for grapefmit esters for fruits ... [Pg.202]

The recognition accuracy estimation described above faces one very important problem what is the best choice for the threshold value 0 To solve this problem, statistical decision theory is used. ° The basis for this is an analysis of the so-called the Received Operating Characteristic (ROC) curve. By tradition, ROC is plotted as a function of true positive rate TPj TP + FN) (or sensitivity) versus false positive rate FPj TN+FP) (or 1-Specificity) for all possible threshold values 0. Figure 6.5 presents an example of such a ROC curve for the results obtained with our computer program PASS in predicting antineoplastic activity. [Pg.196]

Thus, we see that the qualitative change in the structural properties near the point x = 4 is rather general feature of asymmetric two-component plasma and the threshold value obtained in MC simulations of this system is in a good agreement with the studies of nonlinear screening of a single grain based on the continuous PB theory. [Pg.301]

There are many cases in which a scientist or an engineer needs to compare the mean of a data set with a known value. In some cases, the known value is the true or accepted value based on prior knowledge or experience. In other situations, the known value might be a value predicted from theory or it might be a threshold value that we use in making decisions about the presence or absence of a constituent. In all these cases, we use a statistical hypothesis test to draw conclusions about the population mean y. and its nearness to the known value, which we call p.Q. [Pg.149]

Thus the theory predicts increasing stability with increasing nuclcarity beginning with a threshold value of 4 for n. [Pg.402]

One theory is based on the concept that growth occurs layer by layer on the crystal face, and that each new layer begins as a two-dimensional nucleus attached to the face. This theory predicts that growth does not start until an appreciable threshold supersaturation is reached and that the rate of growth then increases rapidly until, at some fairly high value of supersaturation, it becomes linear with supersaturation. Actually, the growth rate of most crystals is linear with supersaturation at all supersaturations, even at very low values. There seems to be no threshold value required. [Pg.901]

According to percolation theory, a branch of mathematics dealing with phenomena such as the for mation of connected channels (otherwise called Percolating clusters ) from randomly distributed sites on a grid, such a system would be expected to have a strongly nonlinear response if the number of sites per volume (otherwise called degree of space filling ) is close to a threshold value called the percolation threshold. For more details, see, for example, D. Staufer, Introduction to Percolation Theory, Taylor Francis, London (1985). [Pg.525]

Universal interfacial energy constant (this model assumes that all systems percolate at a universally valid threshold value of the interfacial energy Ag [28]), The merit of this work is that they have drawn attention to the role of the interfaces, even if they have failed to develop any ideas about the nature of the interaction at the interfaces, or the percolation structures, or the mechanisms of formation. For this reason it is not immediately obvious that two cornerstones of this theory, namely Ag and the influence of polymer viscosity, are not sufficiently well founded experimentally and cannot explain the percolation phenomenon. [Pg.510]

Decision theory operates on the basis of an "objective function" which is in some way optimized through the setting of a decision threshold. A lucid presentation to alternative strategies for formulating detection decisions has been given by Liteanu and Rica (S, p. 192). The essence of the matter is that a threshold value kg for the Likelihood Ratio is derived from a) prior probabilities for the null and alternative hypotheses, b) a cost or... [Pg.7]

A comparison of the formulas (5.91) and (5.79) might lead one to conclude that use of the Lie differential equation formalism has enabled us to eliminate the uncertainty associated with the choice of the threshold value T for the self-similarity scale. This is not so. The self-similarity threshold, like the period of a periodic function, is an inherent feature of each physical object expected to exhibit self-similarity. By adopting the differential equation formulation of the GPRG theory one implicitly has selected a threshold scale equal to unity, that is, t = 1. [Pg.291]

The molecular mechanism operative in the change in ion channel conductances is not yet clearly understood. However, it is likely that these ion channels are composed of lipid-protein complexes. There are at least two theories for the opening of the sodium channel (1) Voltage-dependent ion channel conductance When the depolarization potential is greater than the threshold value, the sodium channel opens. (2) Ca " removal from the membrane outer surface (probably, from the outer part of the sodium channel) Such removal acts as a trigger for opening the sodium channel. It seems... [Pg.96]


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See also in sourсe #XX -- [ Pg.271 , Pg.272 , Pg.273 ]




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