THICK-WALL

Figure 9.4 A thick-walled pressure vessel might be economical when compared with a thin-walled vessel and its relief and venting system.

Carius tube A thick-walled glass lube originally used in the Carius method but used in any reaction involving volatile materials. 

The discovery of perfect geodesic dome closed structures of carbon, such as C o has led to numerous studies of so-called Buckminster fullerene. Dislocations are important features of the structures of nested fullerenes also called onion skin, multilayered or Russian doll fullerenes. A recent theoretical study [118] shows that these defects serve to relieve large inherent strains in thick-walled nested fullerenes such that they can show faceted shapes. 

This type of filtration is almost invariably performed with the aid of a Buchner flask and funnel, by means of which a rapid and almost complete separation can be obtained. The Buchner flask A (Fig. 4) consists of a simple thick-walled conical flask with a short side-arm for connection to a water-pump. Into the neck of the flask is fitted the Buchner funnel B which consists usually of a cylindrical porcelain funnel, the bed of which is pierced by a... 

In order to save the cost of the distilling-flask (which after the above treatment is useless for further work), the mixture may be distilled from a small retort made by blowing a suitable bulb on the end of a rather thick-walled tube of about 8-10 mm. internal diameter the tube is then bent through almost 90° a few cm. above the bulb, cut to a suitable length, and the Open end fitted into the boiling ube as before. 

The technique of the filtration of hot solutions has already been described in Section 11,28. The filtration of cold solutions will now be considered this operation is usually carried out when it is desired to separate a crystalline solid from the mother liquor in which it is suspended. When substantial quantities of a solid are to be handled, a Buchner funnel of convenient size is employed. The ordinary Buchner fimnel (Fig. 11,1, 7, a) consists of a cylindrical porcelain funnel carrying a fixed, flat, perforated porcelain plate. It is fitted by means of a rubber stopper or a good cork into the neck of a thick-walled filtering flask (also termed filter flask, Buchner flask or suction flask) (Fig. 11,1, 7, c), which is connected by means of thick-walled rubber tubing (rubber pressure tubing) to a similar flask or safety bottle, and the latter is attached by rubber pressure tubing to a filter pump the safety bottle or trap is essential since a sudden fall in water pressure may result in the water sucking back. The use of suction renders rapid filtration possihle... 

Oleum is marketed in all strengths up to ca. 70 per cent. SO3. From 0 to 40 per cent, free SO3, it is a liquid from 40 to 60 per cent, free SO3, it is a solid from 60 to 70 per cent, free SO3, it is liquid above 70 per cent, free SO3, it is a solid. The acid must be kept in ground glass stoppered, thick-walled bottles. If it is required to melt the acid, the stopper is removed, a watch glass placed on the mouth of the bottle, and the bottle placed in a layer of sand in an air bath which is warmed with a small flame. The bottle is fitted with a wash bottle attachment, and any desired quantity of acid is forced out by gentle air pressure from a hand or foot bellows (the mouth must not be used) this procedure is far more satisfactory than that of pouring the liquid acid from the bottle. 

Thick film technology Thick-walled cylinders Thielavia basicola Thiele-Geddes model Thiele modulus Thiele s hydrocarbon... 

Design of thick-walled cylinders, Design of removable closures, Manufacture of pressure vessels. Manufacture of tubing. 

Elastic Behavior. In the following discussion of the equations relevant to the design of thick-walled hoUow cylinders, it should be assumed that the material of which the cylinder is made is isotropic and that the cylinder is long and initially free from stress. It may be shown (1,2) that if a cylinder of inner radius, and outer radius, is subjected to a uniform internal pressure, the principal stresses in the radial and tangential directions, and <7, at any radius r, such that > r > are given by... 

Partially Plastic Thick-Walled Cylinders. As the internal pressure is increased above the yield pressure, P, plastic deformation penetrates the wad of the cylinder so that the inner layers are stressed plasticady while the outer ones remain elastic. A rigorous analysis of the stresses and strains in a partiady plastic thick-waded cylinder made of a material which work hardens is very compHcated. However, if it is assumed that the material yields at a constant value of the yield shear stress (Fig. 4a), that the elastic—plastic boundary is cylindrical and concentric with the bore of the cylinder (Fig. 4b), and that the axial stress is the mean of the tangential and radial stresses, then it may be shown (10) that the internal pressure, needed to take the boundary to any radius r such that is given by... 

Bursting tests have been carried out on neatly a hundred thick-walled cylinders made of carbon, low alloy, and stainless steels, together with some nonferrous materials. The diameter ratio of the cylinders varied from 1.75 to 5.86, and some tests were carried out at 660°C. An analysis of the results (19) showed that 90% of the cylinders burst within 15% of the value given by equation 17. 

Eig. 7. Pressure expansion curve of a thick-walled cylinder undergoing autofrettage (22). 

Creep of Thick-walled Cylinders. The design of relatively thick-walled pressure vessels for operation at elevated temperatures where creep caimot be ignored is of interest to the oil, chemical, and power industries. In steam power plants, pressures of 35 MPa (5000 psi) and 650°C are used. Quart2 crystals are grown hydrothermaHy, using a batch process, in vessels operating at a temperature of 340—400°C and a pressure of 170 MPa (25,000 psi). In general, in the chemical industry creep is not a problem provided the wall temperature of vessels made of Ni—Cr—Mo steel is below 350°C. 

The fifth component is the stmcture, a material selected for weak absorption for neutrons, and having adequate strength and resistance to corrosion. In thermal reactors, uranium oxide pellets are held and supported by metal tubes, called the cladding. The cladding is composed of zirconium, in the form of an alloy called Zircaloy. Some early reactors used aluminum fast reactors use stainless steel. Additional hardware is required to hold the bundles of fuel rods within a fuel assembly and to support the assembhes that are inserted and removed from the reactor core. Stainless steel is commonly used for such hardware. If the reactor is operated at high temperature and pressure, a thick-walled steel reactor vessel is needed. 

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