Textile fibers polyesters

Corrections of the apparent crystallinity values of fibers materials have been carried out by taking into account a disorder parameter k, following Ruland s method. Peculiar care was taken about samples preparation (cutting and pelleting of fibers), data collection and reduction, which will be briefly described. Crystallinity and disorder parameter measurements have been performed on main textile fibers (polyester, polyamide, aramid, polypropylene, cellulosic fibers) and the results will be discussed comparatively, with those got by more conventional x-ray crystallinity determinations. The complementarities of these different approaches will be illustrated with several examples. For instance,... 

Poly(ethylene terephthalate), the predominant commercial polyester, has been sold under trademark names including Dacron (Du Pont), Terylene (ICI), Eortrel (Wellman), Trevira (Hoechst-Celanese), and others (17). Other commercially produced homopolyester textile fiber compositions iaclude p oly (1,4-cyc1 oh exa n e- dim ethyl en e terephthalate) [24936-69-4] (Kodel II, Eastman), poly(butylene terephthalate) [26062-94-2] (PBT) (Trevira, Hoechst-Celanese), and poly(ethylene 4-oxyben2oate) [25248-22-0] (A-Tell, Unitika). Other polyester homopolymer fibers available for specialty uses iaclude polyglycoHde [26124-68-5] polypivalolactone [24937-51-7] and polylactide [26100-51-6],... 

In the late 1980s, new fully aromatic polyester fibers were iatroduced for use ia composites and stmctural materials (18,19). In general, these materials are thermotropic Hquid crystal polymers that are melt-processible to give fibers with tensile properties and temperature resistance considerably higher than conventional polyester textile fibers. Vectran (Hoechst-Celanese and Kuraray) is a thermotropic Hquid crystal aromatic copolyester fiber composed of -hydroxyben2oic acid [99-96-7] and 6-hydroxy-2-naphthoic acid. Other fully aromatic polyester fiber composites have been iatroduced under various tradenames (19). 

Since the early 1980s, the viscose-based staple fibers have, like the cuprammonium and viscose filament yams in the 1970s, ceased to be commodities. They have been repositioned from the low cost textile fibers that were used in a myriad of appUcations regardless of suitabUity, to premium priced fashion fibers dehvering comfort, texture, and attractive colors in ways hard to achieve with other synthetics. They are stiU widely used in blends with polyester and cotton to add value, where in the 1980s they would have been added to reduce costs. 

Among the bast textile fibers, the density is close to 1.5 g/cm, or that of cellulose itself, and they are denser than polyester, as shown iu Table 5. Moisture regain (absorbency) is highest iu jute at 14%, whereas that of polyester is below 1%. The bast fibers are typically low iu elongation and recovery from stretch. Ramie fiber has a particularly high fiber length/width ratio. 

Properties. As prepared, the polymer is not soluble in any known solvents below 200°C and has limited solubiUty in selected aromatics, halogenated aromatics, and heterocycHc Hquids above this temperature. The properties of Ryton staple fibers are in the range of most textile fibers and not in the range of the high tenacity or high modulus fibers such as the aramids. The density of the fiber is 1.37 g/cm which is about the same as polyester. However, its melting temperature of 285°C is intermediate between most common melt spun fibers (230—260°C) and Vectran thermotropic fiber (330°C). PPS fibers have a 7 of 83°C and a crystallinity of about 60%. 

Typical textile fibers used, for example, in a needle-punched filter fabric, are a blend of 3.3- and 6.6-dtex (3- and 6-denier) polyester staple. These fibers are - 5 cm long, have diameters ranging from 18 to 25 pm, mass-per-unit-length or linear density values ranging from - 350 to 650 mg per 1000 m, and length-to-width ratios in the order of 1000 to 1. 

Classification by usage or appHcation is the principal system adopted by the Colour Index (5). Because the most important textile fibers are cotton (qv) and polyester, the most important dye types are those used for dyeing these two fibers, including polyester—cotton blends (see Fibers, polyester). 

Basic (Cationic) Dyes. The use of basic dyes is confined mainly to acryUc textile fibers, acetate, and as complementary dyes for acid-modified polyester fibers that accept this class of dyes. 

Special mention must be made of poly(lactic acid), a biodegradable/bio-resorbable polyester, obtained from renewable resources through fermentation of com starch sugar. This polymer can compete with conventional thermoplastics such as PET for conventional textile fibers or engineering plastics applications. Hie first Dow-Cargill PLA manufacturing facility is scheduled to produce up to 140,000 tons of Nature Works PLA per year beginning in 200245 at an estimated price close to that of other thermoplastic resins U.S. l/kg.46 Other plants are planned to be built in the near future.45... 

Both terephthalic acid (TPA) and dimethyl terephthalate (DMT) are used exclusively for the manufacture of polyesters for textile fibers (e.g,. Dacron ), films, soft-drink bottles, and engineering resins for automotive applications. The glycol used for most TPA-based polyesters is ethylene glycol. The polyester is then known as polyethylene terephthalate, or PET. 

Coatings and Surface Modifications. Probably the one application of photopolymer chemistry that has the most worldwide commercial value in terms of product sales is the use of photopolymer materials for curable coatings. Most of the wood paneling and less expensive furniture manufactured today utilize UV or electron-beam curable materials for decorative finishes (e.g. simulation of wood grain) and protective coatings. In addition, the surfaces of many commercially important materials (e.g. textile fibers and polyester films) are being modified by photopolymer processes. 

The second major use of germanium is as catalyst in the production of polyesters [e.g. poly(ethylene terephthalate)] and synthetic textile fibers (especially those produced in Europe and Japan). 

It was previously mentioned was that a large number of minor copolymers of PET have been developed over the past 50 years, with the intent of modifying textile fiber properties and processability [2, 3], Of broader interest is that some of these textile modifications, such as PET copolymers with metal salts of 5-sulfoisophthalic acid (SIPA), have their own rich chemistries when the extent of polymer modification is increased beyond textile levels. An example of such a modification is that changing the counterions associated with SIPA can significantly effect the kinetics of polyester transesterification reactions (the... 

PET is by far the largest-volume thermoplastic polyester in production today. It was first synthesized by J. R. Winfield in the UK in the 1940s and its first commercial application was as a textile fiber. PET was also produced as a film for packaging and blow molded into bottles for beverages long before it had any... 

Together, antifreeze, PET, and polyester polymers account for about 98% of the ethylene glycol produced in the United States. It is also used sometimes as a deicer for aircraft surfaces. The two hydroxyl groups in the EG molecule also make EG suitable for the manufacture of surfactants and in latex paints. Other applications include hydraulic brake fluid, the manufacture of alkyd resins for surface coatings, and stabilizers for water dispersions of urea-formaldehyde and melamine-formaldehyde The hygroscopic properties (absorbs moisture from the air) make EG useful as a humectant for textile fibers, paper, leather, and adhesives treatment. 

Polyester fibers represent the most important group of man-made fibers. With an annual production volume of 19.2 Mt, polyester fibers hold second position in world production of textile fibers [10]. Polyester is usually dyed with disperse dyes. 

Along with nylons, polyester fibers approach and exceed common natural fibers such as cotton and wool in heat stability, wash-and-wear properties, and wrinkle resistance. Blended textiles from polyester, cotton, and wool also can be made to be permanent-press and... 

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