Temperature gradient tests

Figure 3. Comparison of water content distribution in the specimen between TH analysis and measured results of temperature gradient test...

Through analysis of the effect of fitting various time scales of data for predicting long term behavior, it was found that for the 700/100°C gradient tests, the predictions of the 7,500 and 12,500 hour fits were the best. For the lower temperature gradient tests, results varied. 

Considering the above-mentioned conditions, and aiming at improving the accuracy of laboratory HTC tests and evaluating the corrosion lifetime of various materials more easily and quickly, a new temperature gradient test (TGT) with a thermal cycle component has been developed. The application of the TGT is mainly for waste combustion environments in which thermal cycles and A Ts strongly influence corrosion. " " ... 

For the examination of the applied metallic or ceramic layer, the test object is heated up from the outside The heat applying takes place impulse-like (4ms) by xenon-flash lamps, which are mounted on a rack The surface temperature arises to approx 150 °C Due to the high temperature gradient the warmth diffuses quickly into the material An incorrect layer, e g. due to a delamiation (layer removal) obstructs the heat transfer, so that a higher temperature can be detected with an infrared camera. A complete test of a blade lasts approximatly 5 minutes. This is also done automatically by the system. In illustration 9, a typical delamination is to be recognized. 

In general, it is fair to state that one of the major difficulties in interpreting, and consequently in establishing definitive tests of, corrosion phenomena in fused metal or salt environments is the large influence of very small, and therefore not easily controlled, variations in solubility, impurity concentration, temperature gradient, etc. . For example, the solubility of iron in liquid mercury is of the order of 5 x 10 at 649°C, and static tests show iron and steel to be practically unaltered by exposure to mercury. Nevertheless, in mercury boiler service, severe operating difficulties were encountered owing to the mass transfer of iron from the hot to the cold portions of the unit. Another minute variation was found substantially to alleviate the problem the presence of 10 ppm of titanium in the mercury reduced the rate of attack to an inappreciable value at 650°C as little as 1 ppm of titanium was similarly effective at 454°C . 

Loop Tests Loop test installations vary widely in size and complexity, but they may be divided into two major categories (c) thermal-convection loops and (b) forced-convection loops. In both types, the liquid medium flows through a continuous loop or harp mounted vertically, one leg being heated whilst the other is cooled to maintain a constant temperature across the system. In the former type, flow is induced by thermal convection, and the flow rate is dependent on the relative heights of the heated and cooled sections, on the temperature gradient and on the physical properties of the liquid. The principle of the thermal convective loop is illustrated in Fig. 19.26. This method was used by De Van and Sessions to study mass transfer of niobium-based alloys in flowing lithium, and by De Van and Jansen to determine the transport rates of nitrogen and carbon between vanadium alloys and stainless steels in liquid sodium. 

B) The number of points in space or time within one such batch A that needs to be tested (spacial inhomogeneity due to viscosity, temperature gradients, etc.) temporal inhomogeneity due to process start-up and shut-down. 

To develop an alternative MIEC cathode not only the ex situ properties, e.g., cr, TEC, /), and k, but also the electrocatalytic activity, structural and chemical stability, and Cr-tolerance must be considered. Beyond testing in small SOFC button cells, the viability of new cathode materials must ultimately be proven in large-scale stack cells under practical current and temperature gradients. The issues involved in the development of cathode materials for large-scale stacks are significantly more complex than those in the small button cells briefly reviewed in this chapter. However, this does provide serious challenges as well as opportunities for materials scientists and engineers in the development of commercially viable ITSOFCs. 

Some of the NPP models are based on the color imagery and some are not. In the latter, phytoplankton growth is estimated from coupled global circulation and biogeo-chemical models in which water motion controls nutrient availability. The water motion is controlled by climatic factors, such as temperature gradients and wind stress. The latest effort to compare model outputs was conducted with 31 different models and foimd that global estimates for a test year (1998) differed by as much as a factor of 2 The mean results from this model intercalibration experiment are shown in Table 23.7. 

Preliminary residence time distribution studies should be conducted on the reactor to test this assumption. Although in many cases it may be desirable to increase the radial aspect ratio (possibly by crushing the catalyst), this may be difficult with highly exothermic solid-catalyzed reactions that can lead to excessive temperature excursions near the center of the bed. Carberry (1976) recommends reducing the radial aspect ratio to minimize these temperature gradients. If the velocity profile in the reactor is significantly nonuniform, the mathematical model developed here allows predictive equations such as those by Fahien and Stankovic (1979) to be easily incorporated. 

Consider a molecular-level view of a portion of the fluid shown schematically in Fig. 12.9. A test plane is placed at height z, where the temperature is T (z). Molecules in the upper plane at z + L (L is the mean-free-path length) have temperature T + L(dT/dz) molecules in the lower plane at z — L have temperature T — L(dT/dz). Because of the temperature gradient, the average energy per molecule e will vary with height ... 

THERMAL PRECIPITATION. Sinclair (13D, Chap. 8) describes an apparatus developed to test the theory of thermal precipitation. An aerosol particle will move in a temperature gradient from a hot body toward a colder body with a velocity proportional to the temperature gradient. 

---