Tin-based alloys

Solders. In spite of the wide use and development of solders for millennia, as of the mid-1990s most principal solders are lead- or tin-based alloys to which a small amount of silver, zinc, antimony, bismuth, and indium or a combination thereof are added. The principal criterion for choosing a certain solder is its melting characteristics, ie, soHdus and Hquidus temperatures and the temperature spread or pasty range between them. Other criteria are mechanical properties such as strength and creep resistance, physical properties such as electrical and thermal conductivity, and corrosion resistance. 

The secondary production of lead begins with the recovery of old scrap from worn-out, damaged, or obsolete products and with new scrap. The chief source of old scrap is lead-acid batteries other sources include cable coverings, pipe, sheet, and other lead-bearing metals. Solder, a tin-based alloy, may be recovered from the processing of circuit boards for use as lead charge. 

Similar effect of relatively stable cycling on the level of discharge capacity of 500 mA-h/g can be achieved, for example, using tin-based alloys with different metals (please, see the detailed investigation of such alloys in this book [5]). These metals perform probably the functions of elastic matrix in such alloys and gave possibility to compensate for the volumetric changes of Sn. 

The capabilities of thin tin films and tin-based alloys with different metals as active materials for lithium - ion battery negative electrodes are considered. Electrochemical characteristics of such films at different substrates and mechanisms of their functioning are discussed. 

Tin, tin-based alloys, lithium-ion batteries, negative active material... 

The lead-base babbitts are based upon the lead—antimony—tin system, and, like the tin-base, have a structure of hard crystals in a relatively soft matrix. The lead-base alloys are, however, more prone to segregation, have a lower thermal conductivity than the tin-base babbitts, and are employed generally as an inexpensive substitute for the tin-base alloys. Properly lined, however, they function satisfactorily as bearings under moderate conditions of load and speed. 

BEARING, BABBITT - A bearing metal of non-ferrous material, containing several tin-based alloys, mainly copper, antimony, tin and lead. 

Several tin-based alloys, usually containing lead, antimony and copper, with a melting point of about 230 °C, are also die-cast where the very highest accuracy is required and great strength is not of importance. Their excellent corrosion-resistance to moisture makes them suitable for such components as number wheels in gas and water meters, and they have also found use in small complex components of electrical instruments. 

Table 11.1 Overview of composite tin-based alloying anodes ... 

SEI ON LITHIUM, GRAPHITE, DISORDERED CARBONS AND TIN-BASED ALLOYS... 

SEI on Lithium, Graphite, Disordered Carbons and Tin-Based Alloys 3... 

This chapter addresses several issues dealing with the mechanism of SEI formation on inert substrates, lithium, carbonaceous materials and tin-based alloys. Attention is currently focused on the correlation between the composition and morphology of the solid-electrolyte interphase forming on the different planes of highly ordered pyrolytic graphite (HOPG) and different types of disordered carbon electrodes in lithium-ion cells. 

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