Surface acoustic wave resonator

Bulk and surface imprinting strategies are straightforward tools to generate artificial antibodies. Combined with transducers such as QCM (quartz crystal microbalance), SAW (surface acoustic wave resonator), IDC (interdigital capacitor) or SPR (surface plasmon resonator) they yield powerful chemical sensors for a very broad range of analytes. 

Rapp, M., Boss, B., Voigt, A., Gemmeke, H. and Ache, H. J. (1995) Development of an analytical microsystem for organic gas-detection based on surface-acoustic-wave resonators. Fresenius Journal of Analytical Chemistry 352, 699-704. 

Electrospun nanofibers of several polymers, among others PVB were used in a surface acoustic wave resonator (30). The surface acoustic wave resonator is used as an ultrafast response humidity sensor. 

Lozano J, Fernandez MJ, Fontecha JL, Aleixandre M, Santos JP, Sayago 1, Arroyo T, Cabellos JM, Gutierrez FJ, Horrillo MC (2006) Wine classification with a zinc oxide SAW sensor array. Sens Actuators B 120 166-171 Martin SJ, Schweizer KS, Schwartz SS, Gunshor RL (1984) Vapor sensing by means of a ZnO-on-Si surface acoustic wave resonator. Proc IEEE Ultrason Symp 1984 207-213... 

Bell, A. 2006. Sensors, motors, and tuning in the cochlea Interacting cells could form a surface acoustic wave resonator. Bioinsp. Biomim., 1(3),96-101. 

Hgure 1. Surface acoustic wave resonator (SAW resonator) with cheinically selective coating. 

The major piezoelectric applications are sensors (pickups, keyboards, microphones, etc.), electromechanical transducers (actuators, vibrators, etc ), signal devices, and surface acoustic wave devices (resonators, traps, filters, etc ). Typical materials are ZnO, AIN, PbTiOg, LiTaOg, and Pb(Zr.Ti)03 (PZT). 

A number of methods are available for the characterization and examination of SAMs as well as for the observation of the reactions with the immobilized biomolecules. Only some of these methods are mentioned briefly here. These include surface plasmon resonance (SPR) [46], quartz crystal microbalance (QCM) [47,48], ellipsometry [12,49], contact angle measurement [50], infrared spectroscopy (FT-IR) [51,52], Raman spectroscopy [53], scanning tunneling microscopy (STM) [54], atomic force microscopy (AFM) [55,56], sum frequency spectroscopy. X-ray photoelectron spectroscopy (XPS) [57, 58], surface acoustic wave and acoustic plate mode devices, confocal imaging and optical microscopy, low-angle X-ray reflectometry, electrochemical methods [59] and Raster electron microscopy [60]. 

A piezoelectric mass sensor is a device that measures the amount of material adsorbed on its surface by the effect of the adsorbed material on the propagation of acoustic waves. Piezoelectric devices work by converting electrical energy to mechanical energy. There are a number of different piezoelectric mass sensors. Thickness shear mode sensors measure the resonant frequency of a quartz crystal. Surface acoustic wave mode sensors measure the amplitude or time delay. Flexure mode devices measure the resonant frequency of a thin Si3N4 membrane. In shear horizontal acoustic plate mode sensors, the resonant frequency of a quartz crystal is measured. 

Mass Mass change Measurements of surface acoustic waves, piezoelectric crystal resonance... 

Most SAW transducers are inadequate for operation in liquids because most types of surface acoustic waves are completely damped in this viscous environment. Therefore, QCM transducers are used instead. For successful operation of an MIP-QCM chemosensor in liquid, the MIP film should be sufficiently stable with respect to dissolution and peeling off from the resonator surface. Moreover, this film should be relatively rigid, neither shrinking nor swelling in the test solution. 

Fig. 4.20 Schematic of Surface Acoustic Wave (SAW) resonator for hydrogen sensing (adapted from D Amico et al., 1982/83)...

Mercury binding leads to an increase of mass of the gold layer which can be detected by electro-acoustic transducers based on quartz microbalance (QMB the abbreviation QCM = quartz crystal microbalance is also widely used), surface acoustic waves (SAW)—devices [20] or microcantilevers [21,22], Adsorption of mercury vapour increases resonance frequency of shear vibrations of piezoelectric quartz crystals (Fig. 12.2). This process can be described by Sauerbrey equation [23]. For typical AT-cut quartz, this equation is... 

The transducers most commonly employed in biosensors are (a) Electrochemical amperometric, potentiometric and impedimetric (b) Optical vibrational (IR, Raman), luminescence (fluorescence, chemiluminescence) (c) Integrated optics (surface plasmon resonance (SPR), interferometery) and (d) Mechanical surface acoustic wave (SAW) and quartz crystal microbalance (QCM) [4,12]. 

The piezo-electric effect of deformations of quartz under alternating current (at a frequency in the order of 10 MHz) is used by coating the crystal with a selectively binding substance, e. g. an antibody. When exposed to the antigen, an antibody-antigen complex will be formed on the surface and shift the resonance frequency of the crystal proportionally to the mass increment which is, in turn, proportional to the antigen concentration. A similar approach is used with surface acoustic wave detectors [142] or with the surface plasmon resonance technology (BIAcore, Pharmacia). 

Devices based on piezoelectric crystals, which allow transduction between electrical and acoustic energies, have been constructed in a number of conrigurations for sensor applications and materials characterization. This cluqtter examines those devices most commonly utilized for sensing a( licatithickness-shear mode (TSM) resonator, the surface acoustic wave (SAW) device, the acoustic plate mode (APM) device, and the flexural plate wave (FPW) device. Each of these devices, shown schematically in Figure 3.1, uses a unique acoustic mode. 

Figure 3.1 Schematic sketches of the four types of acoustic sensors, (a) Thickness-Shear Mode (TSM) resonator (b) Surface-Acoustic-Wave (SAW) sensor, (c) Shear-Horizontal Acoustic-Plate-Mode (SH APM) sensor, and (d) Flexural-Plate-Wave (FPW) sensor.

The discovery by R. M. White of the University of California at Berkeley that surface acoustic waves could be excited and detected by lithographically patterned interdigital electrodes on the surface of piezoelectric crystals [42] has led to widespread use of SAW devices in a number of signal-processing applications. These include frequency filters, resonators, delay lines, convolvers, and correlators [43,44]. 

ZnO is a wide band gap semiconductor, which is used for various applications. Based on textured ZnO films one can build highly effective piezo field emitters. On the other hand ZnO is a very effective electron-excited phosphor. ZnO films easily withstand electron fluence more than 1 W/cm. ZnO films doped with Al, Ga, or In have a low resistivity of about 10 " Qcm and a high transparency of about 90%. This is sufficient for applications as a front contact in solar cells, liquid crystal displays etc. Dielectric ZnO films have a high electromechanical coupling factor that allow using ZnO in various surface acoustic wave (SAW) devices such as delay lines, delay-line filters, resonators, transducers and SAW convolvers. 

Another state-of-the-art detection system contains a surface acoustic wave (SAW) device, which is based on a piezoelectric crystal whose resonant frequency is sensitive to tiny changes in its mass—it can sense a change of 10-1° g/cm2. In one use of this device as a detector it was coated with a thin film of zeolite, a silicate mineral. Zeolite has intricate passages of a very uniform size. Thus it can act as a molecular sieve, allowing only molecules of a certain size to pass through onto the detector, where their accumulation changes the mass and therefore alters the detector frequency. This sensor has been used to detect amounts of methyl alcohol (CH3OH) as low as 10 9 g. 

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