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Support-sensitive

The addition of nickel to ruthenium has a less pronounced effect on the methanation activity. This is hardly surprising since nickel is also intrinsically active for methanation. However, dilution of ruthenium with nickel does result in a marked increase in catalyst stability. A catalyst of composition 0.5% Ru, 2% NiY was more stable than those prepared from the pure metals. This improved stability was attributed to an improved balance between the rates of dissociation of CO and hydrogenation of surface carbon, thereby preventing the formation of excess surface carbon. The data presented indicated that a similar improvement in stability was obtained for 0.5% Ru, 2% Ni on A1203, which demonstrates that this effect is not support sensitive. [Pg.54]

It is apparent from the support sensitivity of these low lying electronic transitions that guest-host interactions play a significant role for Ag3 ° and Ag3° in rare gas... [Pg.432]

Recycling of the PEG-bound porphyrin 5 was also studied. The catalyst was reused a second time in the photooxidation of the bisdialine to give the product 7 in 97% yield and 80/20 diastereoisomeric ratio after a 1-h reaction. The recovered PEG-TPP was recycled a third time without showing any decrease in the catalytic activity the PEG-supported sensitizer was recycled six times with no appreciable loss of chemical or stereochemical efficiency. [Pg.304]

The 02/ 02 isotopic equilibration on metals is support-sensitive, particularly with reducible supports which can lead to SMSI effects. Shpiro et showed that the rate of equilibration at 20°C over Rh/Ti02 and... [Pg.158]

Whether or not to include trials with no cardiovascular events in a meta-analysis has been a highly debated topic. If a trial had a sufficiently long period of follow-up and no cardiovascular events were reported, these data would appear to support the hypothesis of noninferiority however, no formal statistical method exists for estimating the cardiovascular risk from such data, and they are typically excluded from the analysis. Tian and colleagues (2009) discussed a method of obtaining an exact confidence interval for the difference in event rates at a fixed time point that permits combining data from trials that have zero events with data from other trials. This method could be utilized as a supportive sensitivity analysis. [Pg.261]

SHx - relationship stability, family support sensitively check - any domestic violence ... [Pg.310]

Enzyme Act Direct Solid Support Sensitivity (pmol/tube) cv (%) Volume of Serum Required (ml) Samples/h (only flow systems) Reference... [Pg.74]

The primary support sensitivity studies show that, high thermal stresses in the hot piping cannot be avoided solely through the use of a higher coefficient of thermal expansion (CTE) primary structure material and/or a higher primary support structure temperature. [Pg.462]

Special configurations to reduce probe wobble and sensitivity to geometry changes and to allow inspection nearby both sides of a support plate in one pass... [Pg.323]

As the safety and quality of industrial components, equipments and constructions is correlated with the inspection sensitivity and this is influenced in radiography by the film system class, a continuous supervision of the film systems on the market seems to be urgently necessary. To support the confidence of the film users in the film properties specified by the film manufacturers such a system for quality assurance for industrial x-ray films is proposed by some manufacturers and BAM. This system will be open to all manufacturers, distributers and users of x-ray films. It will deal with all film systems inclusive those which are not specified by a manufacturer as for instance mixed systems. The system for quality assurance will be based... [Pg.552]

Surfactants have also been of interest for their ability to support reactions in normally inhospitable environments. Reactions such as hydrolysis, aminolysis, solvolysis, and, in inorganic chemistry, of aquation of complex ions, may be retarded, accelerated, or differently sensitive to catalysts relative to the behavior in ordinary solutions (see Refs. 205 and 206 for reviews). The acid-base chemistry in micellar solutions has been investigated by Drummond and co-workers [207]. A useful model has been the pseudophase model [206-209] in which reactants are either in solution or solubilized in micelles and partition between the two as though two distinct phases were involved. In inverse micelles in nonpolar media, water is concentrated in the micellar core and reactions in the micelle may be greatly accelerated [206, 210]. The confining environment of a solubilized reactant may lead to stereochemical consequences as in photodimerization reactions in micelles [211] or vesicles [212] or in the generation of radical pairs [213]. [Pg.484]

The use of sensitizing dyes in photography has been the subject of many studies and constitutes. still now. one of the most studied areas in specialized periodic publications (125, 126) or in textbooks (88. 127). It can be ascertained that one hundred years after Vogel s discovery of spectral sensitization, the basic mechanisms of action of dyes on their silver halide support still remain not fully understood. However, the theoretical reasons explaining why among many other dye families practically only cyanine methine dyes appear to be spectral sensitizers (128) are better known. [Pg.78]

The plaque assay is desirable because it is very sensitive and only detects infectious viral particles. However, there are viral agents which cannot be supported by cell lines. In these cases other methods must be used. The polymerase chain reaction (PGR), which amplifies DNA or RNA from viral agents, can be used to detect the presence and quantity of viral agents. The amount of RNA or DNA target in the initial sample can be determined by competitive PGR where the quantity of amplified product is compared to a control PGR product where the initial amount of target is known. Quantification is also possible by an end-point dilution method similar to that used to determine a tissue culture infections dose. PGR methods can be very sensitive however. [Pg.143]

Friction due to lack of vertical positioning of the tube is a source of error, as is sensitivity to the surface condition of the test piece. Samples of small mass cannot be tested except when supported on a heavy anvil. [Pg.467]

Immobilization. The fixing property of PEIs has previously been discussed. Another appHcation of this property is enzyme immobilization (419). Enzymes can be bound by reactive compounds, eg, isothiocyanate (420) to the PEI skeleton, or immobilized on soHd supports, eg, cotton by adhesion with the aid of PEIs. In every case, fixing considerably simplifies the performance of enzyme-catalyzed reactions, thus faciHtating preparative work. This technique has been appHed to glutaraldehyde-sensitive enzymes (421), a-glucose transferase (422), and pectin lyase, pectin esterase, and endopolygalacturonase (423). [Pg.13]

Uses. In architectural and industrial appHcations vibrational isolators are used to reduce transmission of vibration into building stmctures from rotating or reciprocating machinery, such as ventilating fans, pumps, chillers, industrial machinery, and the piping and ductwork coimected to this equipment (6). Vibration isolators also can be used to isolate vibration-sensitive equipment or noise-sensitive areas from sources of vibration. Examples are special pneumatic isolators to protect electron microscopes, and isolators used to support floating concrete floors in recording studios. [Pg.319]


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See also in sourсe #XX -- [ Pg.158 ]




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