Sulfur content values

It is noteworthy, however, that traces of sulfur can have beneficial effects on the anti-wear resistance of fuel injection pumps. It is thus undesirable to reduce the sulfur content to extremely low values unless additives having lubricating qualities are added. Independently from total sulfur content, the presence of mercaptans that are particularly aggressive towards certain metal or synthetic parts is strictly controlled. The mercaptan content is thereby limited to 0.002% (20 ppm) maximum. The analysis is performed chemically in accordance to the NF M 07-022 or ASTM D 3227 procedures. 

Od condensed from the released volatdes from the second stage is filtered and catalyticady hydrotreated at high pressure to produce a synthetic cmde od. Medium heat-content gas produced after the removal of H2S and CO2 is suitable as clean fuel. The pyrolysis gas produced, however, is insufficient to provide the fuel requirement for the total plant. Residual char, 50—60% of the feed coal, has a heating value and sulfur content about the same as feed coal, and its utilisation may thus largely dictate process utdity. 

Properties. A high volatile western Kentucky bituminous coal, the tar yield of which by Fischer assay was ca 16%, gave a tar yield of ca 26% at a pyrolysis temperature of 537°C (146—148). Tar yield peaked at ca 35% at 577°C and dropped off to 22% at 617°C. The char heating value is essentially equal to that of the starting coal, and the tar has a lower hydrogen content than other pyrolysis tars. The product char is not suitable for direct combustion because of its 2.6% sulfur content. 

The volatiles contents of product chars decreased from ca 25—16% with temperature. Char (lower) heating values, on the other hand, increased from ca 26.75 MJ /kg (11,500 Btu/lb) to 29.5 MJ /kg (12,700 Btu/lb) with temperature. Chars in this range of heating values are suitable for boiler fuel apphcation and the low sulfur content (about equal to that of the starting coal) permits direct combustion. These char products, however, are pyrophoric and require special handling in storage and transportation systems. 

Economic Aspects and Uses. Almost all ammonium sulfate is used as a fertilizer for this purpose it is valued both for its nitrogen content and for its readily available sulfur content. In 1986/1987 United States consumption of ammonium sulfate was 0.57 million metric tons (34) world consumption during the same period was estimated at 13.3 million metric tons. In North America ammonium sulfate is largely recovered from caprolactam production. 

Trinidad asphalt has a relatively uniform composition of 29% water and gas, 39% bitumen soluble in carbon disulfide, 27% mineral matter on ignition, and 5% bitumen that remains adsorbed on the mineral matter. Refining is essentially a process of dehydration by heating the cmde asphalt to ca 165°C. The refined product averages 36% mineral ash with a penetration at 25°C of about 2 (0.2 mm), a softening point (ring and ball method) of 99°C, a flash point (Cleveland open cup) of 254°C, a sulfur content of 3.3%, and a saponification value of 45 mg KOH/g. The mineral matter typically contains... 

Exhaust emissions of CO, unbumed hydrocarbons, and nitrogen oxides reflect combustion conditions rather than fuel properties. The only fuel component that degrades exhaust is sulfur the SO2 concentrations ia emissions are directly proportional to the content of bound sulfur ia the fuel. Sulfur concentrations ia fuel are determined by cmde type and desulfurization processes. Specifications for aircraft fuels impose limits of 3000 —4000 ppm total sulfur but the average is half of these values. Sulfur content ia heavier fuels is determined by legal limits on stack emissions. 

Properties Involving Utilization. Coal rank is the most important single property for appHcation of coal. Rank sets limits on many properties such as volatile matter, calorific value, and swelling and coking characteristics. Other properties of significance include grindabHity, ash content and composition, and sulfur content. 

Heating value of the product (SRC) is ca 37 MJ/kg (16,000 Btu/lb). Sulfur contents have been reduced from 2—7% initially to 0.9% and possibly less. Ash contents have been reduced from 8—20% to 0.17% (102). These properties permit compliance with EPA requirements for SO2 and particulate emissions. The SRC is primarily intended to be used as a boiler fuel in either a soHd or molten form (heated to ca 315°C). The soHd has a Hardgrove index of 150 (103). Boiler tests have been successfully carried out using a utiHty boiler. 

The sulfur content of crudes, however, is important and is usually considered when determining commercial values. 

Catalyst Poisons. It is well known that sulfur, chlorine, etc. are strong poisons for nickel catalyst. Chlorine was not detectable in the synthesis gas downstream of the Rectisol in the SASOL plant. The total sulfur content of this gas—in the form of H2S, COS, and organic sulfur components—averaged 0.08 mg/m3 with maximum values of 0.2 mg total sulfur/m3. 

Active matter (anionic surfactant) in AOS consists of alkene- and hydroxy-alkanemonosulfonates, as well as small amounts of disulfonates. Active matter (AM) content is usually expressed as milliequivalents per 100 grams, or as weight percent. Three methods are available for the determination of AM in AOS calculation by difference, the two-phase titration such as methylene blue-active substances (MBAS) and by potentiometric titration with cationic. The calculation method has a number of inherent error factors. The two-phase titration methods may not be completely quantitative and can yield values differing by several percent from those obtained from the total sulfur content. These methods employ trichloromethane, the effects from which the analyst must be protected. The best method for routine use is probably the potentiometric titration method but this requires the availability of more expensive equipment. 

However, since the authors assumed that no hexasulfide and negligible amounts of tri- and disulfide ions were present in their solutions at pH values of 11-12, these data can be only approximately correct. In any case, it is obvious that the acidity of aqueous sulfanes increases with increasing sulfur content, as it does in the gas phase. 

Figure 1.167. Sulfur content vs. value for Quaternary volcanic rocks of Japan. Field bounded by solid lines show two volcanoes (AK and HK), two volcanic zones (NA and CH) in Northeast Japan, three volcanic belts (IM, SW and RY), alkaline rocks (AL) and volcanic rocks of unusually high values (HI) in Ryukyu belt. Symbols surrounded by small circles show S S values of Satsuma-Iwojima volcanic rocks in West Japan (Ueda and Sakai, 1984).

Quality of RDF can be roughly evaluated by calorific value, ash content, water content, and chlorine and sulfur content. Table 5 presents the quality of RDF depending on several kinds of waste. The table shows that RDF from industrial waste has lower water content and higher heating value than from household or commercial waste. This is because of the low percentage of organic fraction. 

RDF source Calorific value (MJ/kg) Ash residue (wt.%) Chlorine content (wt.%) Sulfur content (wt.%) Water content (wt.%)... 

The lower explosive limit and minimum explosive concentrations of flax, wool, cotton, jute, hemp and sisal fibres are of the same order of magnitude as those of highly explosive dusts [15], The explosibility of pyrites dusts with sulfur contents above 20% was evaluated experimentally. Dusts of 30% sulfur content gave explosion pressures of 3 bar at pressure rise rates of 16 bar/sec. Mixtures of 60% pyrites and 40% powdered limestone still showed significant pressure effects, and the proportion of limestone actually needed to suppress explosions was considerably above the values currently accepted by mining industries [16], Effects of mixtures of particle sizes in combustible dusts upon minimum ignition temperature (T ") and upon presence or absence of explosion were studied. Presence of 30% of fines in a coarse dust lowers Tf significantly [17], Experimental explosions of polyethylene,... 

Coal Char Coal char is, generically, the nonagglomerated, non-fusible residue from the thermal treatment of coal however, it is more specifically the solid residue from low- or medium-temperature carbonization processes. Char is used as a fuel or a carbon source. Chars have compositions intermediate between those of coal and coke the volatile matter, sulfur content, and heating values of the chars are lower, and the ash content is higher, than those of the original coal. 

Among the classes of feedstock processed in the hydrocracker the most highly aromatics feed are light cycle oils produced in the FCC unit Once formed by cyclization and the hydrogen transfer mechanism discussed above, they accumulate in the product due to the absence of a metal function in the FCC catalyst and adequate hydrogen in the process environment. They are typically sold as low-value fuel oil, or hydrotreated to reduce sulfur content and improve their quality as diesel blend stocks. Another approach to upgrade their value even further... 

Data for the thiophenic sulfur content determined by XANES and XPS for all samples studied are plotted in Figure 3. The solid line in the figure represents the parity situation. Most of the data lie off the parity line in the figure, but in a non-random fashion. The apparent systematic nature of the disparities implies that the differences in the values derived from XANES and XPS arise from the underlying assumptions used in each technique since the experimental precision for both methods is better than differences between the data from XPS and XANES. 

Figure 3. Comparison of XPS and XANES Values for Thiophenic Sulfur Content of Samples Studied.

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