Stearate, stearates

Primary amides for slip/antiblock agents in LDPE, LLDPE, PP films. Lubricants can tie up catalyst residues, usually calcium stearate stearates and ethylene bis-stearamide waxes are sometimes used in processing of fine powdered polyolefins erucamides preferred for films and mouldings fluoropolymer alloys give better use of machinery methacrylate-reactive silicones... 

It seems probable that in stabilization systems based on combinations of organolins and calcium stearate, a complex of the two additives displaces labile chloride with a ligand from tin, either carboxylate or mercaptide, at carbon 3, with chloride from carbon 1 going to calcium. This may be a concerted reaction, (i.e., occur simultaneously), or the tin stabilizer may function as a phase transfer catalyst for transfer of chloride to calcium stearate, stearate replacing the tin ligand that has been lost, as in Reaction (20) ... 

Liquid or solid films which reduce or prevent adhesion between surfaces solid-solid, solid-paste, solid-liquid. Waxes, metallic soaps, glycerides (particularly stearates), polyvinyl alcohol, polyethene, silicones, and fluorocarbons are all used as abherents in metal, rubber, food, polymer, paper and glass processing. 

Results can sometimes be unexpected. The first study of this type made use of labeled Aerosol OTN [111], an anionic surfactant, also known as di-n-octylsodium sulfosuccinate. The measured F was twice that in Eq. III-93 and it was realized that hydrolysis had occurred, that is, X + H2O = HX + OH , and that it was the undissociated acid HX that was surface-active. Since pH was essentially constant, the activity of HX was just proportional to C. A similar behavior was found for aqueous sodium stearate [112]. 

Photopolymerization reactions of monolayers have become of interest (note Chapter XV). Lando and co-workers have studied the UV polymerization of 16-heptadecenoic acid [311] and vinyl stearate [312] monolayers. Particularly interesting is the UV polymerization of long-chain diacetylenes. As illustrated in Fig. IV-30, a zipperlike process can occur if the molecular orientation in the film is just right (e.g., polymerization does not occur readily in the neat liquid) (see Refs. 313-315). 

Rothberg L, Higashi G S, Allara D L and Garoff S 1987 Thermal disordering of Langmuir-Blodgett-films of cadmium stearate on sapphire Chem. Phys. Lett. 133 67-72... 

Cemel A, Fort T and Lando J B 1972 Polymerization of vinyl stearate multilayers J. Poiymer Soi. A-1 10 2061-83... 

Detergents are made by, for example, treating petroleum hydrocarbons with sulphuric acid, yielding sulphonated products which are water soluble. These can also solubilise fats and oils since, like the stearate ion, they have an oil-miscible hydrocarbon chain and a water-soluble ionic end. The calcium salts of these substances, however, are soiu u-ic in water and, therefore, remove hardness without scum formation. 

Successful results have been obtained (Renfrew and Chaney, 1946) with ethyl formate methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec.-butyl and iso-amyl acetat ethyleneglycol diacetate ethyl monochloro- and trichloro-acetates methyl, n-propyl, n-octyl and n-dodecyl propionates ethyl butyrate n-butyl and n-amyl valerates ethyl laurate ethyl lactate ethyl acetoacetate diethyl carbonate dimethyl and diethyl oxalates diethyl malonate diethyl adipate di-n-butyl tartrate ethyl phenylacetate methyl and ethyl benzoates methyl and ethyl salicylates diethyl and di-n-butyl phthalates. The method fails for vinyl acetate, ieri.-butyl acetate, n-octadecyl propionate, ethyl and >i-butyl stearate, phenyl, benzyl- and guaicol-acetate, methyl and ethyl cinnamate, diethyl sulphate and ethyl p-aminobenzoate. 

Polymerization takes place, in the following manner in the presence of suitable peroxide catalyst these compounds polymerize with themselves (homopolymerizatiOn) in aqueous emulsion. When the reaction is complete, the emulsified polymer may be used directly or the emulsion coagulated to yield the solid polymer (312). A typical polymerization mixture is total monomer (2-vinylthiazole), 100 sodium stearate, 5 potassium persulfate, 0.3 laurylmercaptan, 0.4 to 0.7 and water, 200 parts. 

The solubility behavior of salts of carboxylic acids having 12—18 carbons is unusual and can be illustrated by considering sodium stearate (sodium octadecanoate) As seen by the structural formula of its sodium salt... 

FIGURE 19 5 Electrostatic potential map of sodium stearate Most of the molecule is comprised of a nonpolar hydrocarbon chain (green) One end is very polar as indicated by the red and blue associated with the carboxylate and sodium ions respectively... 

Compare the electro r-static potential maps of sodium lauryl sul 5 fate and sodium stearate on Learning By Modeling... 

Carboxylate groups are hydrophilic ( water loving ) and tend to confer water sol ubility on species that contain them Long hydrocarbon chains are lipophilic ( fat loving ) and tend to associate with other hydrocarbon chains Sodium stearate is an example of an amphiphilic substance both hydrophilic and lipophilic groups occur within the same molecule... 

The formation of micelles and their properties are responsible for the cleansing action of soaps Water that contains sodium stearate removes grease by enclosing it m the hydrocarbon like interior of the micelles The grease is washed away with the water not because it dissolves m the water but because it dissolves m the micelles that are dis persed m the water Sodium stearate is an example of a soap sodium and potassium salts of other C12-C1S unbranched carboxylic acids possess similar properties... 

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