Underground states

Occurrence. Iodine [7553-56-2] is widely distributed in the Hthosphere at low concentrations (about 0.3 ppm) (32). It is present in seawater at a concentration of 0.05 ppm (33). Certain marine plants concentrate iodine to higher levels than occur in the sea brine these plants have been used for their iodine content. A significant source of iodine is caUche deposits of the Atacama Desert, Chile. About 40% of the free world s iodine was produced in Japan from natural gas wells (34), but production from Atacama Desert caUche deposits is relatively inexpensive and on the increase. By 1992, Chile was the primary world producer. In the United States, underground brine is the sole commercial source of iodine (35). Such brine can be found in the northern Oklahoma oil fields originating in the Mississippian geological system (see Iodine and iodine compounds). 

American Petroleum Institute, State Relations Department, 1984, Special Report State Underground Petroleum Products Storage Mandates, American Petroleum Institute, Washington, D.C., September 21. 

EPA. 1984. State underground injection control programs. U.S. Environmental Protection Agency. Code of Federal Regulations. 40 CFR 147. 

CFR 147, 1991, State Underground Injection Control Programs," Code of Federal Regulations, as amended. 

The Institute has many-year experience of investigations and developments in the field of NDT. These are, mainly, developments which allowed creation of a series of eddy current flaw detectors for various applications. The Institute has traditionally studied the physico-mechanical properties of materials, their stressed-strained state, fracture mechanics and developed on this basis the procedures and instruments which measure the properties and predict the behaviour of materials. Quite important are also developments of technologies and equipment for control of thickness and adhesion of thin protective coatings on various bases, corrosion control of underground pipelines by indirect method, acoustic emission control of hydrogen and corrosion cracking in structural materials, etc. 

By utilizing the improvements stated above in any combination preferable to the chemist, convenience will be enhanced and yield will jump from around 20% to that of 50%. Not bad, but there is one more oddball form of the Leuckart reaction that was devised specifically for X production and produces a yield of 70% This little procedure [32] has been around for 40 years and has, until recently, failed to be reported as a superior Leuckart conversion method by underground sources. This sort of thing really frustrates Strike. 

Synthetic Processes. Traditional Solvay plants produce large volumes of aqueous, chloride-containing waste which must be discharged. This fact, in addition to a noncompetitive cost position, is largely responsible for the demise of U.S. synthetic plants. In countries other than the United States, waste is sent to the ocean, rivers, or deep underground wells. The AC and NA coproduct processes produce less aqueous waste than the traditional Solvay and NA mono processes. Related environmental concerns are added whenever a plant complex includes lime quarries and ammonia-producing equipment. 

Natural gas production and transmission systems are complemented by underground storage systems. These systems provide the capabdity to respond to short-term gas demands which exceed the immediate production levels or transmission capabdities. They also provide an opportunity to sustain some production by refilling the storage areas when seasonal temperature variations lead to periods of reduced gas demand. In the United States in 1990, there were 397 storage pools having a combined capacity of 2.2 x 10 (1). 

Nuclear wastes are classified according to the level of radioactivity. Low level wastes (LLW) from reactors arise primarily from the cooling water, either because of leakage from fuel or activation of impurities by neutron absorption. Most LLW will be disposed of in near-surface faciHties at various locations around the United States. Mixed wastes are those having both a ha2ardous and a radioactive component. Transuranic (TRU) waste containing plutonium comes from chemical processes related to nuclear weapons production. These are to be placed in underground salt deposits in New Mexico (see... 

In the United States, Hquid HLW from the reprocessing of defense program fuels was concentrated, neutralized with NaOH, and stored in underground, mild steel tanks pending soHdification and geologic disposal (see Tanks AND PRESSURE VESSELS). These wastes are a complex and chemically active slurry. Suspended in the supernatant Hquid are dissolver soHds which never went into solution, insoluble reaction products which formed in the tank, and salts which have exceeded their solubiHty limit. The kinetics of many of the reactions taking place are slow (years) so that the results of characterization... 

United States. In 1980, Unocal began constmcting the Parachute Creek Project, designed to produce 1600 m (10,000 bbl) of upgraded shale oil per day. The project included a conventional underground room-and-pikar mine, the Unishale B (see Table 7) retort, and a special Unocal upgrading facihty. Plant startup occurred in 1986, and daily shale oil production reached 1100 m /d (7000 bbl/d). By 1991, total production exceeded 0.6 x 10 m (four million barrels). However, the Parachute Creek Project was shut down in mid-1991 for economic reasons. 

Open-pit zinc mining is not common, since most mines ate below the surface. The Kidd Creek Mine in Ontario, Canada, is a combination open-pit—underground mine. It is one of the richest deposits in the world with an estimated 62.5 x 10 t grading 7.08% zinc, 1.33% copper, and 151 g silver (14). Underground mining methods include room-and-pdlar, shrinkage, cut-and-fill, and square set. In the United States, ca 20 mines account for more than 98% of zinc production. 

In the United States the primary route for making calcium chloride is by the evaporation of underground brines (see Chemicals frombrines). Additional commercial material is available by the action of hydrochloric acid on limestone. Typically the hydrochloric acid is a by-product of some other commercial process and the conversion to calcium chloride is motivated by waste avoidance (see Hydrogen chloride). 

Occurrence. The brines of Seades Lake, California are the sole brine source of sodium carbonate [497-19-8] (soda ash) production in the United States. There is a large underground deposit of sodium carbonate brine in the Sua Pan area of Botswana, Afdca (66). Another potential source is Owens Lake, California. Owens Lake brines were used to produce soda ash but were discontinued in 1967. 

If yourfacility has a permit to inject a waste containing the toxic chemical into Class 1 deep wells, enter the 12-digit Underground Injection Well Code (UlC) identification number assigned by EPA or by the State under the authority of the Sate Drinking Water Act. If your facility does not hold such a p>ermit(s), enter not applicable, NA, in Section 3.1 la. You are only required to provide the UlC number for wells that receive the toxic chemical being reported. 

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