Spiral wound membrane application

Microfiltration and UF membranes are available in tubular, spiral wound, and hollow fiber membrane module configurations. Tubular and spiral MF and UF modules are similar to RO tubular and spiral wound membrane modules described in Chapters 4.3.2 and 4.3.3. However, while the thickest feed spacer in a spiral RO module is 34-mil, UF and MF modules nominally have up to a 45-mil spacer due to the relatively high concentration of suspended solids these membranes are called upon to treat (TriSep Corporation offers a special 65-mil spacer for dairy applications). 

Membrane processes are used to filter liquids. Instead of conventional filter materials (e.g. filter cloth, filter candles,) microporous membranes are employed with molecular size pores. First the industry had to learn how to manufacture membranes with controlled pore sizes. To optimise the filtration capacities specific filter structures had to be designed in which the liquid followed well defined flow patterns on one side of the membrane. Many different systems were developed for the varied applications, all having their advantages and also disadvantages, i.e. plate modules, tubular modules, spiral wound membranes, etc. Research and development in this field is far from being exhausted. Today membrane systems are available which are sufficiently resistant to chemical, mechanical and thermal stress. They are produced from plastic... 

Pleated ultrafiltration module. The axial filter is convenient for experiments, in that volumes small relative to ordinary ultrafiltration systems can be studied and in that pumping of viscous solutions is limited to that necessary to replace filtrate or concentrate bled from the chamber, rather than that necessary to maintain desired cross flow velocities. There is no obvious reason it could not be scaled up to moderate sizes for practical separations, but so far as we know, no large-volume axial filters are available. For the operations of interest, any of the commercial ultrafiltration systems would be candidates. We have tested one module, recently developed by Gelman, which incorporates a pleated membrane (Figure 5), with somewhat more open feed passages than those of spiral-wound membranes, and which allows backwashing. Other applications of the module were discussed at this symposium by A. Korin in a paper coauthored by G. B. Tanny, and a written account is presumably in these proceedings. 

Spiral Wound The spiral-wound membrane geometry in MF and UF is not widely used in surface water treatment because spiral-wound membranes cannot be backwashed, and extensive pretreatment is therefore required to keep the membrane from clogging. However, there are some applications in groundwater treatment where surface water UF membranes are applied to remove color (Nystrom et al., 1999). In the spiral-wound configuration, two flat sheets of membrane are separated with a permeate collector channel material to form a leaf. This assembly is sealed on three sides, with the fourth side left open for permeate to exit. A feed/brine spacer material sheet is also included in the leaf assembly. A number of these assemblies or leaves are wound around a central plastic permeate tube. This tube is perforated to collect the permeate from the multiple leaf assemblies (Hydranautics, 2001). Most commercial lengths are 1 or 1.5 m and 20 cm in diameter (Fig. 6.7). 

Spirally wound membrane modules can generally meet most process application requirements. They are particularly suitable for sanitary applications in the pharmaceuticals, biotechnology, dairy, food and beverage industries. They are also widely used in the industrial sector for environmental protection, metal coating, chemical and paint apphcations. 

RO membrane performance in the utility industry is a function of two major factors the membrane material and the configuration of the membrane module. Most utility applications use either spiral-wound or hollow-fiber elements. Hollow-fiber elements are particularly prone to fouling and, once fouled, are hard to clean. Thus, applications that employ these fibers require a great deal of pretreatment to remove all suspended and colloidal material in the feed stream. Spiral-wound modules (refer to Figure 50), due to their relative resistance to fouling, have a broader range of applications. A major advantage of the hollow-fiber modules, however, is the fact that they can pack 5000 ft of surface area in a 1 ft volume, while a spiral wound module can only contain 300 ftVff. 

Major problems inherent in general applications of RO systems have to do with (1) the presence of particulate and colloidal matter in feed water, (2) precipitation of soluble salts, and (3) physical and chemical makeup of the feed water. All RO membranes can become clogged, some more readily than others. This problem is most severe for spiral-wound and hollow-fiber modules, especially when submicron and colloidal particles enter the unit (larger particulate matter can be easily removed by standard filtration methods). A similar problem is the occurrence of concentration-polarization, previously discussed for ED processes. Concentration-polarization is caused by an accumulation of solute on or near the membrane surface and results in lower flux and reduced salt rejection. 

Gas separation Hollow-fibre for high-volume applications with low-flux, low-selectivity membranes in which concentration polarisation is easily controlled (nitrogen from air) Spiral-wound when fluxes are higher, feed gases more contaminated, and concentration polarisation a problem (natural gas separations, vapour permeation). 

Modules and Housings Modern gas membranes are packaged either as hollow-fiber bundles or as spiral-wound modules. The former uses extruded hollow fibers. Tube-side feed is preferable, but it is limited to about 1.5 MPa. Higher-pressure applications are usually fed on the shell side. A large industrial permeator contains fibers 400 pm by 200 pm i.d. in a 6-inch shell 10 feet long. Flat-sheet membrane is wound into spirals, with an 8- by 36-inch permeator containing 25 of membrane. Both types of module are similar to those illustrated in Background and Definitions. Spiral modules are useful when feed... 

Membrane gas-separation systems have found their first applications in the recovery of organics from process vents and effluent air [5]. More than a hundred systems have been installed in the past few years. The technique itself therefore has a solid commercial background. Membranes are assembled typically in spiral-wound modules, as shown in Fig. 7.3. Sheets of membrane interlayered with spacers are wound around a perforated central pipe. The gas mixture to be processed is fed into the annulus between the module housing and the pipe, which becomes a collector for the permeate. The spacers serve to create channels for the gas flow. The membranes separate the feed side from the permeate side. 

In 1968 we started investigations of RO applications for desalting brackish water. In the course of the investigations, we have found the spirally wound module of asymmetric cellulose acetate RO membrane shows excellent durabilities against fouling materials and free chlorine. 

Figure 3.42 Exploded view and cross-section drawings of a spiral-wound module. Feed solution passes across the membrane surface. A portion passes through the membrane and enters the membrane envelope where it spirals inward to the central perforated collection pipe. One solution enters the module (the feed) and two solutions leave (the residue and the permeate). Spiral-wound modules are the most common module design for reverse osmosis and ultrafiltration as well as for high-pressure gas separation applications in the natural gas industry...

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