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Anodic protection against acids has been used in a number of processes in the chemical industry, as well as during storage and transport. It is also successful in geometrically complicated containers and tubings [12], Carbon steel can be protected from nitric and sulfuric acids. In the latter case, temperature and concentration set application limits [17]. At temperatures of up to 120°C, efficient protection can only be achieved with concentrations over 90% [ 18]. At concentrations between 67 and 90%, anodic protection can be used at up to 140°C with CrNi steels [19]. [Pg.478]

Polymer- based Applicable Applicable impeded setfingh Applicable imp ed setting Applicable Not applicable Applicable... [Pg.179]

Cement- based Applicable Applicable impeded setting Applicable Applicable (contaminant is neutralized by the basic cement) Applicable Applicable if an additive used to prevent spalling... [Pg.179]

Basis Set [Applicable Atoms] Description Basis Fimctions 1st row hydrogen atoms atoms Default Function Types ... [Pg.102]

A planar molecule of point group 03b is shown in Fig. 5. The sigma orbitals i, <72 and (73 represented there will be taken as the basis set Application of the method developed in Section 8.9 yields the characters of the reducible representation given in Table 14. With the use of the magic formula (Eq. (37)] the structure of the reduced representation is of the form Ta — A, ... [Pg.319]

Dahle, P., Helgaker, T., Jonsson, D., Taylor, RR. Accurate quantum-chemical calculations using Gaussian-type geminal and Gaussian-type orbital basis sets applications to atoms and diatomics. Phys. Chem. Chem. Phys. 2007, 9, 3112-26. [Pg.147]

We can use the same approach to expand the design and obtain a data set applicable for polynomials of third order. The respective full factorial design is constructed by combining all of the factors at five levels, giving a total of N = 5", or N = 25 for n = 2, N = 125 for n = 3, N = 625 for n = 4, etc. It is apparent that the number of the experiments grows geometrically with the number of factors, and there are not many applications where the performance of 625 experiments to explore four factors is reasonable. [Pg.293]

In cold-set applications, the cost of resorcinol as a commercial commodity has led to its well-known grafting onto phenol-formaldehyde resols to provide... [Pg.219]

Casein adhesives experienced similar problems. Once the industry recognized that they were not waterproof, as was originally believed, they were rapidly replaced by resorcinols in most structural, cold-set applications where pressure was easily applied. Crosslinking polyvinyl acetates became preferable in some nonstructural, cold-set applications. Cheaper PF resins took over those exterior applications that allowed the use of heat and pressure. UF resins took over many interior applications on the basis of superior costs and mold resistance. Although the basic raw material cost is not a complete picture of the costs of its adhesive derivatives, it is a fairly good index. Table III shows how casein and blood compare with their competition at the present time. Although the exact prices of these materials fluctuate considerably, the approximate order of their costs has not changed much in the last 15 years. The materials are listed in order of cost. [Pg.445]

P Stilbs, K Paulsen, PC Griffiths. Global least squares analysis of large, correlated spectra data sets. Application to component-resolved FT-PSGE NMR spectroscopy. J Chem Phys 100 8180-8189, 1996. [Pg.110]

This significant m variability is reduced but does not disappear if we switch to the real spherical harmonics, which are arguably more important chemically, particularly in minimal-basis-set applications. In the context of chemistry we almost never use the complex spherical harmonics but rather their real and imaginary parts. The real spherical harmonics each have / nodal circles... [Pg.299]

Full ab initio optimizations of molecular geometries of enamines (and of any other kind of molecules) depend strongly on the kind of applied basis sets application of STO-3G 2 3, 3-21G 3-2lG 4-3lG 6-3lG 6-31G " and 6-31G basis sets leads to optimizations for the coplanar framework of all atoms of vinylamine, but it was not stated in these references whether coplanarity was assumed by input constraint or not. Contrary to that, the use of a double-zeta basis set with heavy atom polarization functions as well as 6-31 - -G ° based optimization yielded a non-planar amino group for 115. [Pg.25]

The Zambon synthesis of the non-steroidal anti-inflammatory agent (5)-2-(6-methoxy-2-naphthyl)propanoic acid (naproxen) is a landmark-setting application of the chiral auxiliary approach in the industrial stereoselective synthesis of an enantiomerically pure drug [51]. The chiral auxiliary employed, a (2f ,Jf )-dialkyltartrate, is a paradigmatic representative of this class of stereocontroller, being cheap, readily available, easily introduced on the substrate and removed from the product, and eventually recycled (although as its parent acid). [Pg.118]

Thus PCA may be used to filter out the most relevant information in a data set. Applications of variations of PCA, such as correspondence factorial analysis and non-linear mapping may have small advantages with particular data sets, but require expert support. [Pg.364]

Gleeson, based on work of Bruneau, used an independent test set to define the relationship between the distance of test set compounds from the training set applicability domain and error in prediction. They investigated a number of different distance measures, including Euclidean and Mahalanobis... [Pg.258]

Let us consider the subdomain (0, X) first. We replace the set applicable to this domain (Eq. 12.85) into the first order subproblem Eqs. 12.84, and obtain... [Pg.566]

V. P. Guinn, in L Analyte par Radioactivation et Set Applications aux Sciences Biologiques, Presses Universitaires de France, 1964, pp. 69-82. [Pg.414]

One particular such function that has been found convenient in level set applications [1, 2] is the so-called signed distance function (SDE) which is simply the minimum distance (or the negative thereof) from any point in space to the interface, usually taken with a positive sign in the region outside a closed surface and negative inside. For a circle of radius a in 2D, the SDF would be given by (f>(x, y) = r — a where r = (x + y y. This conical surface is plotted... [Pg.1419]

The package implementation provides the graph types BDD, FDD, OKFDD, MTBDD, EVBDD, BMD, BMD, p BMD, HDD, K BMD and ZDD in order to represent boolean and integer functions as well as sets. Applications of the presented method exist virtually in any approach based on decision diagrams. The paper investigates manipulation of bit-level and word-level functions as well as bit selection from arithmetic expressions. [Pg.185]

In order to determine the symmetry coordinates for the three stretching vibrations, we must apply the projection operator to one of the three basis functions in the Fg i basis set. Application of the projection operator for the A/ IRR on the fj basis function yields the SALC shown in Table 9.10. This SALC is shown in Figure 9.13(b). If the A projection operator had been applied to the r-i or basis function instead, the exact same SALC would have resulted. This will always be true for a nondegenerate IRR. The choice of the basis function in these cases is entirely irrelevant. [Pg.246]

It is essential that any element of each set of operations can be obtained by a combination of other elements from the same set. Application of the subsequent symmetry operations is called multiplication. For a water molecule we can write the corresponding multiplication table. Table 2.1. For instance, the multiplication of operations C2 from the first row and the first column corresponds to the identity operation, C2 C2 = E, shown in the table. Further, C2CT = a and aC2 = o, so these operations commute in our particular case. Generally they may not commute and the order of operations is important (by convention, multiplication operation C2C7 means that first we apply operation a and then C2). [Pg.10]

D.J. Crockford, E. Holmes, J.C. Lindon, R.S. Plumb, S. Zirah, S.J. Bruce, et al.. Statistical heterospectroscopy, an approach to the integrated analysis of NMR and UPLC-MS data sets application in metabonomic toxicology studies. Anal. Chem. 78 (2006) 363. [Pg.344]

Mating surfaces are heated against a hot surface, allowed to soften sufficiently to produce a good bond, then clamped together while bond sets. Applicable to rigid thermoplastics. [Pg.738]

Customers are looking for products with a more natural look, according to Hanna. Trend-setting applications now include white stone and earthenware (terracotta) effects, created for indoor and outdoor products, as well as wooden chairs and tables. Building on its experience with fibres, beads, pearlescent, and fluorescent effects, the company has developed a range of natural effects. [Pg.70]


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See also in sourсe #XX -- [ Pg.392 ]




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