General Safety Precautions

Procedures First aid, risk assessment, safety precautions generally (at school and outside school) and specifically for different activities, e.g. swimming, emergency, handling apparatus, jewellery, clothing, etc. 

Cross-country gas pipelines generally must odorize the normally odorless, colorless, and tasteless gas ia urban and suburban areas, as is required of gas distribution companies. Organosulfur compounds, such as mercaptans, are usually used for this purpose, and code requires that the odor must be strong enough for someone with a normal sense of smell to detect a gas leak iato air at one-fifth the lower explosive limit of gas—air mixtures. The latter is about 5%, so the odorant concentration should be about 1%, but most companies odorize more heavily than this as a safety precaution. 

The Shoe grouting system is considered nonhazardous and nonpolluting. Sodium silicate is essentially nontoxic. Formamide is toxic and corrosive, but does not present a serious hazard if normal safety precautions are followed. Shoe chemical grout materials are two to five times more expensive than Portland cement, depending on the sodium silicate to formamide concentration ratios. Installed costs are generally more similar to those for cement grouts. 

Organo-metallic compounds, on the other hand, behave very much like organic compounds, e.g. they can be redistilled and may be soluble in organic solvents. A note of caution should be made about handling organo-metallic compounds, e.g. arsines, because of their potential toxicities, particularly when they are volatile. Generally the suppliers of such compounds provide details about their safe manipulation. These should be read carefully and adhered to closely. If in any doubt always assume that the materials are lethal and treat them with utmost care. The same safety precautions about the handling of substances as stated in Chapter 4 should be followed here (see Chapter 1). 

Table 5.52 General safety precautions with trichloroethylene and tetrachloroethylene Do not...

People often lack respect for the power in compressed air because air is so common, and it is viewed as harmless. At sufficient pressures, compressed air can cause damage if an accident occurred. To minimize the hazards of working with compressed air, all safety precautions should be followed closely. Reasons for general precautions follow. 

The hazards and safety precautions for selected common compressed gases are discussed below to illustrate the general approach. More details should be sought from suppliers. Some methods for their preparation in situ are noted full experimental details must be obtained from the literature. 

The presence of radiation in the workplace - which is an inevitable consequence of the radioactivity of uranium - requires that additional safety precautions be taken over and above those observed in other similar workplaces. There are generally three sources from which radiation exposure may occur (i) radiation emitted from uranium ore in-situ and/or during handling (ii) airborne radiation resulting from the decay of radon gas released from the ore and uranium dust and (iii) contamination by ore dust or concentrate. Radiation levels around uranium mining and milling facilities are quite low - for the most part only a few times the natural background levels - and they decrease rapidly as the distance from... 

In view of insufficient safety precautions for chemical operations, these systems are generally not recommended for microwave-assisted digestions of polymeric material. 

Step 5 Off-line method or analyzer development and validation This step is simply standard analytical chemistry method development. For an analyzer that is to be used off-line, the method development work is generally done in an R D or analytical lab and then the analyzer is moved to where it will be used (QA/ QC lab, at-line manufacturing lab, etc.). For an analyzer that is to be used on-line, it may be possible to calibrate the analyzer off-line in a lab, or in situ in a lab reactor or a semiworks unit, and then move the analyzer to its on-line process location. Often, however, the on-line analyzer will need to be calibrated (or recalibrated) once it is in place (see Step 7). Off-line method development and validation generally includes method development and optimization, identification of appropriate check samples, method validation, and written documentation. Again, the form of the documentation (often called the method or the procedure ) is company-specific, but it typically includes principles behind the method, equipment needed, safety precautions, procedure steps, and validation results (method accuracy, precision, etc.). It is also useful to document here which approaches did not work, for the benefit of future workers. 

General Safety Precautions. The preparation and handling of the items covered by this specification, and the subassemblies thereof, involve hazardous operations and therefore require explosives safety precautions. Use of this specification will not be construed as to relieve the contractor or manufacturer of responsibility for the safety of his operations. Listed below are certain minimum provisions which a contractor or manufacturer (who prepares the item covered) should observe in order to fulfill his responsibility for safety. At Bureau of Naval Weapons, Navy Department, and other government plants, these provisions are mandatory. Such other warnings and precautions, pertinent to the operational effectiveness or safety during preparation of the specified items, are included in detailed technical requirements of the specification... 

All these reactions are best carried out (a) under an atmosphere of nitrogen and (b) with mechanical stirring. General safety precautions should be maintained, namely, the use of eye protection in the laboratory, proper gloves to avoid skin contact with chemicals, and provision of a hood or dry box with adequate ventilation for all chemical manipulations. 

Perchloryl fluoride generally reacts with electron-rich alkencs or with various carbanionie substrates (Scheme 1), where salts are usually prepared in situ and further react at low temperature or in some cases at room temperature temperature control must be taken into account. However. it has been pointed out several times that serious explosions may occur and for this reason the reactions are potentially hazardous and safety precautions must be taken when working with this reagent. Over the last twenty years fluorination reactions with perchloryl fluoride have been partially discussed in several monographs6 8 and review papers.9 12... 

Trifluoromethyl hypofluorite is generally used at low temperatures with reactants dissolved in an inert solvent, but to increase the solubility of reactants a cosolvent (MeOH, acetone, THF) is often used however, it must be used with extra caution and appropriate safety precautions against explosions and fires, since trifluoromethyl hypofluorite is a powerful oxidizing agent. The toxicity of trifluoromethyl hypofluorite is expected to be high (as with fluorine). Fluori-nation reactions with trifluoromethyl hypofluorite have been discussed in the last twenty years in review papers6 11,65 and several monographs.12" 14... 

Should the platinum become poisoned, that is, rendered inactive by contamination with impurities which have escaped the initial purification process, it can generally be revivified by heating in a current of a reducing gas such as hydrogen. Safety precautions for the operators are desirable during the process.5... 

In general, solid solutes should be weighed on weighing paper or plastic weighing boats, using an analytical or top-loading balance. Liquids are more conveniently dispensed by volumetric techniques however, this assumes that the density is known. If a small amount of a liquid is to be weighed, it should be added to a tared flask by means of a disposable Pasteur pipet with a latex bulb. The hazardous properties of all materials should be known before use and the proper safety precautions obeyed. 

CHEMICAL MANUFACTURERS ASSOCIATION (CMA). Founded in 1863, this nonprofit trade association of chemical manufacture represents more than 90% of the chemical industry of the U S. and Canada. It is located at 2501 M St., N. W., Washington, DC 20037. It is particularly active in the fields of packaging, transportation, and safe handling of hazardous chemicals and wording of precautionary labels, as well as in general chemical education and all aspects of pollution control. It has instituted an emergency telephone information service called ChemTrec to provide instant information for safety precautions in accidents involving chemicals. 

NOTE Observe adequate safety precautions for all cooling tower maintenance workers to protect them against not only the general occupational health and safety risks but also the special risks from Legionella. 

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