Adequate ventilation

The element and its compounds are toxic and should be handled carefully. Contact of the metal with skin is dangerous, and when melting the metal adequate ventilation should be provided. Exposure to thallium (soluble compounds) - skin, as Tl, should not exceed 0.1 mg/ms (8-hour time-weighted average - 40-hour work week). Thallium is suspected of carcinogenic potential for... 

Air contaminants are emitted to the indoor air from a wide variety of activities and consumer products, some of which are summarized in Table 11. Most indoor activities produce some types of pollutants. When using volatile products or engaging in the activities Hsted, care should be exercised to minimize exposure through proper use of the product and by providing adequate ventilation. 

Chemical safety data sheets for individual compounds should be consulted for detailed information. Precautions for the higher aldehydes are essentially those for most other reactive organic compounds, and should include adequate ventilation in areas where high exposures are expected fire and explosion precautions and proper instmction of employees in use of respiratory, eye, and skin protection. 

Safe practices employed for handling PTEE and EEP resins are adequate for Teflon PEA (37) adequate ventilation is required for processing above 330—355°C. In rotoprocessing, a vacuum (250—750 Pa or 1.8—5.6 mm Hg) in the oven ensures exhaust to the outside (36). Removal of end caps or opening of sealed parts in a weU-ventilated area ensures ventilation of decomposition fumes. During rotoprocessing, molds should be vented. 

The TLV is set at 0.1 ppm (hydraziae) 0.2 ppm (MMH) and 0.5 ppm (UDMH). The TLV is weU below the olfactory limit of 3—5 ppm (hydraziae). The latter does aot provide adequate warning when exposure exceeds the TLV therefore, monitoring the working environment by suitable means and providing adequate ventilation is necessary. 

This hydrolysis reaction is accelerated by acids or heat and, in some instances, by catalysts. Because the flammable gas hydrogen is formed, a potential fire hazard may result unless adequate ventilation is provided. Ingestion of hydrides must be avoided because hydrolysis to form hydrogen could result in gas embolism. 

Two compounds associated with particular industrial risks are iron(III) oxide, Fe202, and iron pentacarbonyl, Fe(CO). Chronic inhalation of iron(III) oxide leads to siderosis. Adequate ventilation and mechanical filter respirators should be provided to those exposed to the oxide. Iron pentacarbonyl is volatile and highly toxic. 

The speed of the pickle reaction is also dependent on the concentration and temperature of the pickle, the degree of agitation of either the metal part or the pickle solution, the alloy being pickled, and the acid used. Pickling solutions may be appHed by either spray or immersion techniques. However, because of the noxious fumes emitted, there must be adequate ventilation. Sometimes, particularly when spraying techniques are used, an enclosure to contain the fumes and mist is employed. 

Appropriate protective clothing and equipment should be worn to minimize exposure to methacrylate liquids and vapors. Chemically resistant clothes and gloves and splash-proof safety goggles ate recommended. The working area should be adequately ventilated to limit vapors. Should chemical exposure occur, contaminated clothing should be removed and the affected area washed with copious amounts of water. Medical attention should be sought if symptoms appear. Eurther information about methyl methacrylate and other methacrylates is available (141). 

Oxahc acid is not flammable but its decomposition products, both formic acid and carbon monoxide, are toxic and flammable. Its dust and mist are irritating, especially under prolonged contact. Personnel who handle oxahc acid should wear mbber gloves, aprons, protection masks or goggles, etc, to avoid skin contact and inhalation. Adequate ventilation also should be provided in areas in which oxahc acid dust fumes are present. 

Health and Safety. Remover formulas that are nonflammable may be used in any area that provides adequate ventilation. Most manufacturers recommend a use environment of 50—100 parts per million (ppm) time weighted average (TWA). The environment can be monitored with passive detection badges or by active air sampling and charcoal absorption tube analysis. The vapor of methylene chloride produces hydrogen chloride and phosgene gas when burned. Methylene chloride-type removers should not be used in the presence of an open flame or other heat sources such as kerosene heaters (8). 

Health and Safety. Petroleum and oxygenate formulas are either flammable or combustible. Flammables must be used in facUities that meet requirements for ha2ardous locations. Soak tanks and other equipment used in the removing process must meet Occupational Safety and Health Administration (OSHA) standards for use with flammable Hquids. Adequate ventilation that meets the exposure level for the major ingredient must be attained. The work environment can be monitored by active air sampling and analysis of charcoal tubes. 

The areas for the reactors and storage tanks should be separated by fire walls, and must be adequately ventilated. Storage tanks should be blanketed by inert gas. A slight positive pressure of inert gas should be maintained in the reactor or storage tanks during the discharging of the resin or resin solution to prevent air from being sucked into the vessel to form an explosive mixture with the solvent vapor. 

In view of the above, aniline should be handled in areas with adequate ventilation and skin exposure should be avoided by wearing the proper safety equipment. Recommended personal protective equipment includes hard hat with brim, chemical safety goggles, hiU length face shield, mbber gaundet gloves, mbber apron, and mbber safety shoes or mbber boots worn over leather shoes. 

Because of the high vapor pressure of the simple quinones and their penetrating odor, adequate ventilation must be provided in areas where these quinones are handled or stored. Quinone vapor can harm the eyes, and a limit of 0.1 ppm of 1,4-benzoquinone in air has been recommended. Quinone in either sohd or solution form can cause severe local damage to the skin and mucous membranes. Swallowing benzoquinones may be fatal the LD q in rat is 130 mg/kg orally and 0.25 mg/kg intravenously. There is insufficient data concerning quinones and cancer. The higher quinones are less of a problem because of their decreased volatihty (118—120). 

Protective measures iavolve prompt detection and adequate ventilation. Continuous monitoring is recommended to signal an evacuation alarm if the workplace concentration exceeds 70 mg/m (50 ppm) and a warning alert if it is present at 15—70 mg/m (10—50 ppm). 

Health and Safety Factors. MSC has a vapor toxicity on mice of LD q 4.7 mg/L. It is a lachrymator and in order to prevent contact with eyes, goggles should be worn. It is also corrosive to skin and therefore chemically resistant gloves and protective clothing should be worn to prevent contact with skin. Containers should only be opened where there is adequate ventilation. 

Because routine inhalation of dust of any kind should be avoided, reduction of exposure to poly(vinyl chloride) dust may be accompHshed through the utilization of care when dumping bags, sweeping, mixing, or performing other tasks that can create dust. The use of an approved dust respirator is recommended where adequate ventilation may be unavailable. 

The melting pot is heated either electrically or by gas to 427—524°C. The pot capacity is typically over 100 kg of lead alloy, and periodically the top of the molten metal must be skimmed to remove the dross. The pot fumes must be removed by adequate ventilation (forced suction). When the molten metal has reached the proper temperature and flow characteristics, it is transported by pump to the grid mold. 

Butylenes are not toxic. The effect of long-term exposure is not known, hence, they should be handled with care. Reference 96 Hsts air and water pollution factors and biological effects. They are volatile and asphyxiants. Care should be taken to avoid spills because they are extremely flammable. Physical handling requires adequate ventilation to prevent high concentrations of butylenes in the air. Explosive limits in air are 1.6 to 9.7% of butylenes. Their flash points range from —80 to —73° C. Their autoignition is around 324 to 465°C (Table 2). Water and carbon dioxide extinguishers can be used in case of fire. 

A deterrnination that carbon monoxide might be a metaboUte of methylene chloride in humans (33) suggests that unacceptable levels of carboxyhemoglobin would exist in the blood of persons exposed to methylene chloride vapors at concentrations greater than 500 ppm for extended periods of time. These conditions are rarely encountered in most industrial appHcations. However, as with any organic solvent, adequate ventilation should be provided to ensure compliance with all industrial and governmental regulations. 

Coal piles are carefully constmcted to exclude air or to allow adequate ventilation. The latter requites larger sizes, graded as 4 cm+ without fines, for a voiding heating by ventilation. For exclusion of air, mixed sizes provide fines to fill the gaps between larger pieces. Pockets of large sizes must not be allowed because these provide access for air. The coal should be compacted to maximize the bulk density of the coal pile. 

Cyanohydrins are highly toxic by inhalation or ingestion, and moderately toxic through skin absorption (21). AH a-hydroxy nitriles are potential sources of hydrogen cyanide or cyanides and must be handled with considerable caution. Contact with the skin and inhalation should be rigorously avoided. Special protective clothing should be worn and any exposure should be avoided (18,20). The area should be adequately ventilated. Immediate medical attention is essential in case of cyanohydrin poisoning. 

Caution should be taken when using glutaraldehyde. Gloves and aprons should be worn and adequate ventilation provided. It has been reported to produce contact dermatitis, eye irritation, nausea, headache, rashes, and asthmatic reaction (125). 

Sohd metal soaps, when finely divided, may present an explosion ha2ard and are capable of spontaneous combustion. Inhalation of the dust can cause eye and/or respiratory irritation, so they require adequate ventilation. 

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