Removal of Organics

Drying refers to the removal of water from a substance through a whole range of processes, including distillation, evaporation, and even physical separations such as with centrifuges. Here, consideration is restricted to the removal of moisture from solids and liquids into a gas stream (usually air) by heat, namely, thermal drying. Some of the types of equipment for removal of water also can be used for removal of organic liquids from solids. [Pg.89]

For many years fluorine has been deterrnined by the Willard-Winters method in which finely ground ore, after removal of organic matter, is distilled with 72% perchloric acid in glass apparatus. The distillate, a dilute solution of fluorosiUcic acid, is made alkaline to release fluoride ion, adjusted with monochloroacetic acid at pH 3.4, and titrated with thorium nitrate, using sodium a1i2arine sulfonate as indicator. [Pg.174]

Thiophene [110-02-17, C H S, and dibenzothiophene [132-65-OJ C22HgS, are models for the organic sulfur compounds found in coal, as well as in petroleum and oil shale. Cobalt—molybdenum and nickel—molybdenum catalysts ate used to promote the removal of organic sulfur (see Coal CONVERSION... [Pg.416]

The chemical yield of hydrogen peroxide and the anthraquinone per process cycle is very high, but other secondary reactions necessitate regeneration of the working solution and hydrogenation catalyst, and the removal of organic material from the extracted hydrogen peroxide. [Pg.474]

Supercritical CO2 has also beea tested as a solveat for the removal of organic contaminants from sod. At 60°C and 41.4 MPa (6,000 psi), more than 95% of contaminants, such as diesel fuel and polychlotinated biphenyls (PCBs), may be removed from sod samples (77). Supercritical CO2 can also extract from sod the foUowiag hydrocarbons, polyaromatic hydrocarbons, chlotinated hydrocarbons, phenols, chlotinated phenols, and many pesticides (qv) and herbicides (qv). Sometimes a cosolvent is required for extracting the more polar contaminants (78). [Pg.226]

Carbon Adsorption. Carbon adsorption is a well estabflshed and widely used technology for the removal of organics from wastewaters and gaseous streams. Carbon adsorption is a proven technology for potable water treatment and capable of reducing organic concentrations to very low or nondetectable levels. [Pg.160]

Removal of organic bases by washing with dilute hydrochloric or sulfuric acids. [Pg.6]

Adsorption — An important physico-chemical phenomenon used in treatment of hazardous wastes or in predicting the behavior of hazardous materials in natural systems is adsorption. Adsorption is the concentration or accumulation of substances at a surface or interface between media. Hazardous materials are often removed from water or air by adsorption onto activated carbon. Adsorption of organic hazardous materials onto soils or sediments is an important factor affecting their mobility in the environment. Adsorption may be predicted by use of a number of equations most commonly relating the concentration of a chemical at the surface or interface to the concentration in air or in solution, at equilibrium. These equations may be solved graphically using laboratory data to plot "isotherms." The most common application of adsorption is for the removal of organic compounds from water by activated carbon. [Pg.163]

The effectiveness of activated carbon for the removal of organic compounds from fluids by adsorption is enhanced by its large surface area, a critical factor in the adsorption process. The surface area of activated carbon typically can range from 450 to 1,800 m /g, with some carbons observed to have a surface area up to 2,500 m /g. Some examples are given in Table 6. [Pg.139]

Prechlorination (before the clarifier) significantly improves the removal of organics as well as reducing the coagulant demand. [Pg.311]

Swimming pools Ozone injection for removal of organic contaminants Removal of residual ozone and control of chloramine levels... [Pg.416]

Tubular reactors are used for reactions involving a gas and a liquid. In this arrangement, the gas phase is dispersed as bubbles at the bottom of a tubular vessel. The bubbles then rise through the continuous liquid phase that flows downwards as shown in Figure 4-14. An example of this process is the removal of organic pollutants from water by noncatalytic oxidation with pure oxygen. [Pg.239]

The removal of organic compounds such as toxic compounds... [Pg.1259]

The main types of cleaners used for the removal of organic contaminants are solvent cleaners, neutral cleaners, acid cleaners and alkali cleaners. [Pg.280]

Removal of organisms may follow the following exponential format of equation... [Pg.320]

Clean-in-place (CIP) units for periodic membrane washing and removal of organic deposits, inorganic scales, and biofouling... [Pg.366]

The removal of organics by industrial detergent cleaners. These products employ several mechanisms, depending on the formulation, but tend to include dissolution (using nonaqueous solvents such as kerosene, petroleum spirits, and naphtha, saponification, by caustic, or emulsification by nonionic detergents. [Pg.637]

The main mechanism for removal of organic carbon from the ocean is burial in sediments. This flux is equal to the average global sedimentation rate for marine sediments times their weight percent organic carbon. The total sink... [Pg.253]

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