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Products reduction

HSCH -CHNHj-COjH. Cysteine is a reduction product of cystine. It is the first step in the breakdown of cystine in the body, one molecule of cystine splitting to give two molecules of cysteine. Cysteine is soluble in water but the solution is unstable, and is reoxidized to cystine. [Pg.124]

The reduction product formed by adding 2H across the starred double bond is called ftava-none. [Pg.176]

Again, nitric acid readily dissolves lead but is unable to oxidise lead beyond the oxidation state -P 2. The reduction products of the nitric acid vary with the concentration of acid used, and a number of nitrogen oxides are usually obtained. Warm dilute nitric acid gives mainly nitrogen oxide, NO. [Pg.170]

Reduction products vary depending on the reducing agent, for example dinitrogen oxide is obtained with sulphurous acid, nitrogen is obtained when the gas is passed over heated metals (e.g. copper and iron) and ammonia is produced when the gas reacts with aqueous chromiumfll) salts. [Pg.231]

Concentrated sulphuric acid is an oxidising agent, particularly when hot, but the oxidising power of sulphuric acid decreases rapidly with dilution. The hot concentrated acid will oxidise non-metals, for example carbon, sulphur and phosphorous to give, respectively, carbon dioxide, sulphur dioxide and phosphoric(V) acid. It also oxidises many metals to give their sulphates cast iron, however, is not affected. The mechanisms of these reactions are complex and the acid gives a number of reduction products. [Pg.301]

Give characteristic reduction products depending upon reagent used. [Pg.371]

Only the mono-amines are described here. The diamines are more frequently encountered as reduction products of dinitrobenzenes and nitro-anilines, and the chief reactions of the phenylenediamines are therefore given in Section 23, pp. 384-388. [Pg.372]

Acetone is reduced by amalgamated magnesium largely to a bimolecu lar reduction product, tetramethylethylene glycol or plnacol (CHjjjClOHjClOHjiCHj), some isopropyl alcohol is also formed ... [Pg.349]

Some of the functional groups which are reduced by lithium aluminium hydride, the reduction product together with the theoretical mols of reducing agent required (in parenthesis) are listed below —... [Pg.878]

Nitroso, azo, hy-drazo, and other intermediate reduction products of nitro com-pounds... [Pg.1052]

The imides, primaiy and secondary nitro compounds, oximes and sulphon amides of Solubility Group III are weakly acidic nitrogen compounds they cannot be titrated satisfactorily with a standard alkaU nor do they exhibit the reactions characteristic of phenols. The neutral nitrogen compounds of Solubility Group VII include tertiary nitro compounds amides (simple and substituted) derivatives of aldehydes and ketones (hydrazones, semlcarb-azones, ete.) nitriles nitroso, azo, hydrazo and other Intermediate reduction products of aromatic nitro compounds. All the above nitrogen compounds, and also the sulphonamides of Solubility Group VII, respond, with few exceptions, to the same classification reactions (reduction and hydrolysis) and hence will be considered together. [Pg.1074]

Nitro compounds and their reduction products. Tertiary nitro compounds (these are generally aromatic) are reduced by zinc and ammonium chloride solution to the corresponding hydroxylamines, which may be detected by their reducing action upon an ammoniacal solution of silver nitrate or Tollen s reagent ... [Pg.1074]

The fermentative fixing of CO2 and water to acetic acid by a species of acetobacterium has been patented acetyl coen2yme A is the primary reduction product (62). Different species of clostridia have also been used. Pseudomonads (63) have been patented for the fermentation of certain compounds and their derivatives, eg, methyl formate. These methods have been reviewed (64). The manufacture of acetic acid from CO2 and its dewatering and refining to glacial acid has been discussed (65,66). [Pg.69]

The reduction of the nitro group to yield aniline is the most commercially important reaction of nitrobenzene. Usually the reaction is carried out by the catalytic hydrogenation of nitrobenzene, either in the gas phase or in solution, or by using iron borings and dilute hydrochloric acid (the Bechamp process). Depending on the conditions, the reduction of nitrobenzene can lead to a variety of products. The series of reduction products is shown in Figure 1 (see Amines byreduction). Nitrosobenzene, /V-pbenylbydroxylamine, and aniline are primary reduction products. Azoxybenzene is formed by the condensation of nitrosobenzene and /V-pbenylbydroxylamine in alkaline solutions, and azoxybenzene can be reduced to form azobenzene and hydrazobenzene. The reduction products of nitrobenzene under various conditions ate given in Table 2. [Pg.63]

Fig. 1. Reduction products of nitrobenzene (1) nitrosobenzene [98-95-3] (2) /V-pbenylbydroxyl amine [100-65-2] (3) aniline [62-53-3] (4) azoxybenzene... Fig. 1. Reduction products of nitrobenzene (1) nitrosobenzene [98-95-3] (2) /V-pbenylbydroxyl amine [100-65-2] (3) aniline [62-53-3] (4) azoxybenzene...
Reduction Products. Glyoxyhc acid [298-12 ], HOOCCHO, mol wt 74.04, is produced as aqueous solution by the electrolytic reduction of oxahc acid. It is used for the manufacture of vanillin. [Pg.463]

In the reduction of nitro compounds to amines, several of the iatermediate species are stable and under the right conditions, it is possible to stop the reduction at these iatermediate stages and isolate the products (see Figure 1, where R = CgH ). Nitrosoben2ene [586-96-9] C H NO, can be obtained by electrochemical reduction of nitrobenzene [98-95-3]. Phenylhydroxylamine, C H NHOH, is obtained when nitrobenzene reacts with ziac dust and calcium chloride ia an alcohoHc solution. When a similar reaction is carried out with iron or ziac ia an acidic solution, aniline is the reduction product. Hydrazobenzene [122-66-7] formed when nitrobenzene reacts with ziac dust ia an alkaline solution. Azoxybenzene [495-48-7], C22H2QN2O, is... [Pg.264]

Only the reduction products involving the keto groups are of any academic or industrial importance. Complete reduction of the keto groups by ammonia and zinc (von Perger method) gives rise to anthracene in good yields and quaUty (10). This method is of importance since substituted anthracenes can be prepared from the corresponding anthraquinones. Industrially, an important dyestuff intermediate, 3-chloroanthracene-2-carboxyhc acid, (2) is prepared by this method (11) from 3-chloroanthraquinone-2-carboxyhc acid [84-32-2]... [Pg.420]

Ivermectin is the catalytic reduction product of avermectin, a macroHde containing a spiroketal ring system. Two other related antibiotics having significantly different stmctural features and biological properties, moxidectin and milbemycin oxime, were more recentiy introduced into the market. Although these compounds have no antimicrobial activity, they are sometimes referred to as antibiotics because they are derived from fermentation products and have very selective toxicities. They have potent activity against worms or helminths and certain ectoparasites such as mites and ticks. [Pg.476]

The close electrochemical relationship of the simple quinones, (2) and (3), with hydroquinone (1,4-benzenediol) (4) and catechol (1,2-benzenediol) (5), respectively, has proven useful in ways extending beyond their offering an attractive synthetic route. Photographic developers and dye syntheses often involve (4) or its derivatives (10). Biochemists have found much interest in the interaction of mercaptans and amino acids with various compounds related to (3). The reversible redox couple formed in many such examples and the frequendy observed quinonoid chemistry make it difficult to avoid a discussion of the aromatic reduction products of quinones (see Hydroquinone, resorcinol, and catechol). [Pg.403]

Dihydropyrazines, although the initial reduction product under electrochemical conditions, appear to be unstable, as might be predicted from the fact that they contain eight... [Pg.177]

The final reduction product of pyrazine, piperazine (89), is a stable compound which behaves as a typical diamine. It has found extensive use in medicinal chemistry as a linking agent and as a medicine in its own right for the treatment of helminths both in human and veterinary medicine. [Pg.178]

Apart from the nuclear bromination observed (Section 2.15.13.1) in the attempted radical bromination of a side-chain methyl group leading to (396), which may or may not have involved radical intermediates, the only other reaction of interest in this section is a light-induced reduction of certain hydroxypyrido[3,4-f)]pyrazines or their 0x0 tautomers analogous to that well-known in the pteridine field (63JCS5156). Related one-electron reduction products of laser photolysis experiments with 1 -deazaflavins have been described (79MI21502). [Pg.254]

The first 1,2-benzisoxazole, 3-phenyl-l,2-benzisoxazole, was obtained from the treatment of o-bromobenzophenone oxime with alkali in 1892 (1892CB1498,1892CB3291). 2,1-Benzisoxazole has been known since 1882, being obtained as a reduction product of o-nitrobenzaldehyde with tin and hydrochloric acid (1882CB2105). In general, benzisoxazoles behave much like substituted isoxazoles. Numerous structural ambiguities occur in the early literature of these two systems, and these have been discussed in the above reviews. [Pg.3]


See other pages where Products reduction is mentioned: [Pg.215]    [Pg.428]    [Pg.116]    [Pg.240]    [Pg.243]    [Pg.301]    [Pg.510]    [Pg.878]    [Pg.882]    [Pg.156]    [Pg.167]    [Pg.370]    [Pg.317]    [Pg.490]    [Pg.64]    [Pg.274]    [Pg.303]    [Pg.304]    [Pg.108]    [Pg.209]    [Pg.21]    [Pg.177]    [Pg.530]    [Pg.494]    [Pg.237]    [Pg.249]    [Pg.220]   
See also in sourсe #XX -- [ Pg.526 ]




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1-Electron reduction product

2-propanol reduction product

Aromatic Amines and Other Reduction Products of Nitro Compounds

Aromatic ketone reduction products

Benzothiadiazines and Their Reduction Products

By-products in Birch reductions

Carbon dioxide reduction product distribution

Chiral compound stereoselective synthesis reduction products

Cholesterol reduction products

Cleaner production waste elimination/reduction

Conjugate reduction natural products synthesis

Dithionite reductive activation products

End products of sulfate reduction

Fission products oxidation-reduction potentials

Flavoprotein reduction product

Formates reduction products

Formation of reduction product

Intermediate products in the reduction of nitro compounds

Lead reduction, initiatives electronic products

Molecular weight reduction degradation products

NTERMEDIATE PRODUCTS IN THE REDUCTION OF NITRO COMPOUNDS

Natural product reduction

Natural product synthesis reduction

Nicotine reduction products

Niobium complexes reduction products

Nitric oxide production reduction

Nitric oxide reduction— products

Nitro compounds intermediate products in reduction

Nitro, acids Reduction products

Nitrogen selenide, as explosive product in reduction of strontium

Nitrogen selenide, as explosive product in reduction of strontium selenite with ammonia

One-electron reduction product

Oxygen partial reduction products

Primary alcohol aldehyde reduction product

Product development cost reduction

Product isolation reduction with complex hydrides

Product of reductive

Production cost reduction

Products of Birch reduction

Products of Dithionite Reductive Activation

Reduction and Oxidation Products

Reduction and hydrogenation products

Reduction furnaces, copper production

Reduction of Infrared Emission from Combustion Products

Reduction of Residual Monomer in Latex Products Using High-Pressure Carbon Dioxide

Reduction of production costs

Reduction products from addition reactions

Reduction syngas production

Secondary alcohol ketone reduction product

Selectivity in the Reduction of Natural Products

Stereoisomeric products, asymmetric reduction

The Possible Reduction Product

VANILLIN PRODUCTION reduction

Virus reduction product

Waste reduction product redesign

Wolff-Kishner reduction product

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