Rechargeability, solid-state lithium

The same concept can be applied to interfaces between the components of rechargeable solid-state lithium ion batteries, thereby improving the performance and reducing the resistivities of dc batteries [102],... 

Some successful development of rechargeable solid state systems was achieved by using lithium intercalation cathodes, such as TiS2, which operate in exactly the same manner as in the lithium-organic cells described in Chapter 7. One example of this type of cell is provided by the battery system developed in the 1970s by P. R. Mallory and Co. (now Duracell) based on the following scheme ... 

The use of polyaniline as a possible electrode in a rechargeable solid-state battery appears promising and was first investigated by DeSurville et al. [178]. Both aqueous [179,180] and nonaqueous cells have been extensively investigated [181-183]. A lithium/polyaniline rechargeable battery is now commercially available from Bridgestone and Seiko Electronics in Japan. 

Iwamoto K, Aotani N, Takada K, Kondo S (1994) Rechargeable solid state battery with lithium... 

Quartarone E, Mustarelli P (2011) Electrolytes for solid-state lithium rechargeable batteries recent advances and perspectives. Chem Soc Rev 40 2525-2540... 

Path A, Path V, Shin DW, Choi JW, Paik DS, Yoon SJ (2008) Issue and challenges facing rechargeable thin film lithium batteries. Mater Res Bull 43 1913-1942 Jones SD, Akridge JR (1996) A microfabricated solid-state secondary Li battery. Solid State Ionics 86-88 1291-1294... 

Kepler K. D., Vaughey J. T., Thackeray M. M., LixCu6Sn5 (0 < x < 13) An intermetallic insertion electrode for rechargeable lithium batteries, Electrochem. and Solid State Lett.,... 

Dr. Martin Winter is currently University Professor for Applied Inorganic Chemistry and Electrochemistry at the Institute for Chemistry and Technology of Inorganic Materials, Graz University of Technology (Austria). His fields of specialization are applied electrochemistry, chemical technology and solid state electrochemistry with special emphasis on the development and characterization of novel materials for rechargeable lithium batteries. 

Li H, Huang X, Chen L, Wu Z, Liang Y. A high capacity nano-Si composite anode material for lithium rechargeable batteries. Electrochem Solid-State Lett 1999 2 547-549. 

LiVMoOe was successfully synthesized using the conventional solid-state reaction method, and its chemical and physical properties were examined by several analytical methods. We have shown that LiVMoOe does not possess good structural characteristics for a lithium half cell (Li/LiVMoOe) as a cathode in non-aqueous electrolyte environment. Furthermore, we suggest that LiVMoOe may instead be considered as an anode material of choice for developing rechargeable lithium-ion battery technology. 

Ozawa, K., Lithium-ion rechargeable batteries with LiCo02 and carbon electrodes the LiCoOj/C system. Solid State Ionics, 69, 212, 1994. 

Chang, C.-C., Scarr, N., and Kumta, P.N., Synthesis and electrochemical characterization of LiMOj (M = Ni, Nio 75Coo,25) for rechargeable lithium-ion batteries. Solid State Ionics, 112, 329, 1998. 

Chiang, Y.-M., Sadoway, D.R., Jang, Y.-J., Huang, B., and Wang, H., High capacity, temperature-stable lithium aluminum manganese oxide cathodes for rechargeable batteries, Electrochem. Solid State Lett., 2, 107, 1999. 

Polythiophene (from bithiophene) was also proposed as the positive electrode in a rechargeable lithium battery [505, 506]. All solid-state batteries were assembled with PEO/LiC104. Poly(3-methylthiophene) was used in Li/S02 rechargeable cells [507]. 

If GO is used as a host lattice for Li+ in aprotic electrolytes, reversibility is improved [577]. The potential level is distinctly more positive than with donor GIC, at about —1 V vs. SHE. An all-solid-state Li/GO battery with PE0/LiC104 as solid electrolyte was reported by Mermoux and Touzain [578], but rechargeability is poor. Recently, the structure of graphite oxide was studied by its fluorination at 50-2()0 °C [579]. C-OH bonds were transformed into C-F bonds. The examples, in conjunction with Section 2, show that the formation or cleavage of covalent C-O (C-F) bonds makes the whole electrochemical process irreversible. Application was attempted in lithium primary batteries, which have a voltage of 2-2.5 V. Really reversible electrodes are only possible, however, with graphite intercalation compounds, which are characterized by weak polar bonds. 

Guo, G.H., Tao, Y.T., Song, Z.P., and Zhang, K.L. 2007. Zinc tetrathiomolybdate as novel anodes for rechargeable lithium batteries. Journal of Solid State EJectmchemistry 11, 90-92. 

Yamazoe, N., and Miura, N. 1996. Dynamically compacted rechargeable ceramic lithium batteries. Solid State Ionics 86-88, 897-902. 

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