Electrodes insertion

The most important rechargeable lithium batteries are those using a soHd positive electrode within which the lithium ion is capable of intercalating. These intercalation, or insertion, electrodes function by allowing the interstitial introduction of the LE ion into a host lattice (16,17). The general reaction can be represented by the equation ... 

The Structural Stability of Transition Metal Oxide Insertion Electrodes for Lithium Batteries... 

Insertion electrodes can, in principle, tolerate minor and subtle phase changes... 

Unfortunately, Fe304, Co304, and Mn304 are unattractive insertion electrodes because the large and bulky transition metal ions in the interstitial space of... 

Although LiJMn2]04 appears to have the ideal structure for an insertion electrode in 4V lithium cells, the cells lose capacity slowly when operated over the high voltage range. Several reasons have... 

Although Li[Ti2]04 and Li4Ti,Ol2 have low theoretical capacities (161 and 175 mAhg-1, respectively), they have excellent structural properties for an insertion electrode. The spinel structures are excep-... 

According to our analytical results on the solid-state redox reaction of LiNi02 based on the phenomenological expression for solid-state redox potentials of insertion electrodes [23], the reaction consists of three redox systems characterized by potentials of 4.23, 3.93, and 3.63V with re-... 

Beginning in the early 1980s [20, 21] metallic lithium was replaced by lithium insertion materials having a lower standard redox potential than the positive insertion electrode this resulted in a "Li-ion" or "rocking-chair" cell with both negative and positive electrodes capable of reversible lithium insertion (see recommended papers and review papers [7, 10, 22-28]). Various insertion materials have been proposed for the anode of rechargeable lithium batteries,... 

Zhu Junjie Lu, Zhonghua AST, Doron A, Aharon G (2000) Sonochemical synthesis of Sn02 nanoparticles and their preliminary study as Li insertion electrodes. Chem Mater 12 2557-2566... 

Kepler K. D., Vaughey J. T., Thackeray M. M., LixCu6Sn5 (0 < x < 13) An intermetallic insertion electrode for rechargeable lithium batteries, Electrochem. and Solid State Lett.,... 

Vest X., Jacobsen T., Atiung S. Modeling of Porous Insertion Electrodes with Liquid Electrolite. J. Electrochem. Soc. 1982 129 1480-85. 

Insertion electrodes I Atomic and electronic structure of the hosts and their insertion compounds... 

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