Radioactive decay gases

ORIGIN OF NAME Originally named "niton" after the Latin word for "shining," it was given the name "radon" in 1923 because it is the radioactive decay gas of the element radium. 

While studying radium, Friedrich Ernst Dorn (1848—1916) found that it gave off a radioactive gas that, when studied in more detail, proved to be the sixth noble gas. Dorn was given credit for its discovery in 1900. He called it radon, a variation of the word radium. Sir Wdham Ramsay and R. W. Whytlaw-Gray, who also investigated the properties of radon, called it niton from the Latin word nitens, which means shining. Several other scientists who worked with radon named it thoron because of the transmutation of radon-220 from the decay of thorium. However, since 1923, the gas has been known as radon because it is the radioactive decay gas of the element radium. The name is derived from the Latin word radius, which means ray. ... 

From the radioactive decay constants and measurement of the amount of argon in a rock sample, the length of time since formation of the rock can be estimated. Essentially, the dating method requires fusion of a rock sample under high vacuum to release the argon gas that has collected through radioactive decay of potassium. The amount of argon is determined mass spectrometrically,... 

Radon-222 [14859-67-7] Rn, is a naturally occuriing, iaert, radioactive gas formed from the decay of radium-226 [13982-63-3] Ra. Because Ra is a ubiquitous, water-soluble component of the earth s cmst, its daughter product, Rn, is found everywhere. A major health concern is radon s radioactive decay products. Radon has a half-life of 4 days, decayiag to polonium-218 [15422-74-9] Po, with the emission of an a particle. It is Po, an a-emitter having a half-life of 3 min, and polonium-214 [15735-67-8] Po, an a-emitter having a half-life of 1.6 x lO " s, that are of most concern. Polonium-218 decays to lead-214 [15067-28A] a p-emitter haviag = 27 min, which decays to bismuth-214 [14733-03-0], a p-emitter haviag... 

Mass Spectrometer. The mass spectrometer is the principal analytical tool of direct process control for the estimation of tritium. Gas samples are taken from several process points and analy2ed rapidly and continually to ensure proper operation of the system. Mass spectrometry is particularly useful in the detection of diatomic hydrogen species such as HD, HT, and DT. Mass spectrometric detection of helium-3 formed by radioactive decay of tritium is still another way to detect low levels of tritium (65). Accelerator mass spectroscopy (ams) has also been used for the detection of tritium and carbon-14 at extremely low levels. The principal appHcation of ams as of this writing has been in archeology and the geosciences, but this technique is expected to faciUtate the use of tritium in biomedical research, various clinical appHcations, and in environmental investigations (66). 

Loss of radon in the ocean occurs typically through radioactive decay (producing four short-lived daughters before decaying to °Pb) or loss to the atmosphere at the air-sea interface. Loss of radon owing to turbulence or diffusion at the air-sea interface leads to a depletion of radon with respect to "Ra, allowing for studies on gas exchange at this interface. ... 

Radon gas is formed in the process of radioactive decay of uranium. The distribution of naturally occurring radon follows the distribution of uranium in geological formations. Elevated levels have been observed in certain granite-type minerals. Residences built in these areas have the potential for elevated indoor concentrations of radon from radon gas entering through cracks and crevices and from outgassing from well water. 

Graham s, 159, 722 Hess s, 244 Hooke s, 92 ideal gas, 147 integrated rate, 540 Kirchhoff s, 256 Newton s second, 10 of mass action, 360 of radioactive decay, 712 periodic, 38 Raoult s, 330 rate, 535, 537 second, 267 Stefan-Boltzmann, 9 third, 276 Wien s, 9 LCAO-MO, 117 Le Chatelier, H., 377 Le Chatelier s principle, 377, 468... 

Radon gas is the result of the radioactive decay of radium-226, an element that can be found in varying concentrations throughout many soils and bedrock. Figure 31.1 shows the series of elements that begins with uranium-238, and, after undergoing a series of radioactive decays, leads eventually to lead-210. At the time radium decays to become radon gas, energy is released.9 Of all the elements... 

Each liter of air normally contains a few atoms each of 218Po, 211+Pb, 211+Bi and 211+Po, which are the short-lived decay products of the radioactive noble gas radon. When inhaled, these atoms can be deposited on the lining of the respiratory tract, causing irradiation of the tissue due to further radioactive decay. This irradiation accounts for about one half of the average persons dose... 

Radon-222, a decay product of the naturally occuring radioactive element uranium-238, emanates from soil and masonry materials and is released from coal-fired power plants. Even though Rn-222 is an inert gas, its decay products are chemically active. Rn-222 has a a half-life of 3.825 days and undergoes four succesive alpha and/or beta decays to Po-218 (RaA), Pb-214 (RaB), Bi-214 (RaC), and Po-214 (RaC ). These four decay products have short half-lifes and thus decay to 22.3 year Pb-210 (RaD). The radioactive decays products of Rn-222 have a tendency to attach to ambient aerosol particles. The size of the resulting radioactive particle depends on the available aerosol. The attachment of these radionuclides to small, respirable particles is an important mechanism for the retention of activity in air and the transport to people. 

Radon in indoor air arises primarily from radium in the soil. The radon in the soil gas flows under a pressure gradient from the soil into the building. In some cases building practices can lead to high radon levels in the living areas of the house. Radon is chemically quite inert and does not pose a significant radiation health hazard in itself because the retained fraction in the body is so low (Mays et al., 1958). It is, however, an excellent vehicle for the dispersion of its short-lived radioactive decay products. 

He is found in natural gas deposits principally because alpha particles are produced during natural radioactive decay processes. These alpha particles are 4 He nuclei they obtain two electrons from the surrounding material to become helium atoms. This gaseous helium then accumulates with the natural gas trapped beneath the earth. Although other noble gases are produced by radioactive decay—notably 40 Ar—they are not produced in the large quantities that helium is. 

Neon is believed to be produced by radioactive decay deep in the Earth. As it rises to the surface, it escapes into the atmosphere and is soon dissipated. Some neon is found mixed with natural gas and several minerals... 

Physical Form. Radon is a chemically inert, colorless, odorless, tasteless radioactive gas that is formed from the normal radioactive decay of uranium-238. 

German physicist Friedrich Ernst Dorn Heavy, radioactive noble gas widely present results from uranium decay even present in soil highly toxic but valuable as a cancer treatment. 

In the environment, thorium and its compounds do not degrade or mineralize like many organic compounds, but instead speciate into different chemical compounds and form radioactive decay products. Analytical methods for the quantification of radioactive decay products, such as radium, radon, polonium and lead are available. However, the decay products of thorium are rarely analyzed in environmental samples. Since radon-220 (thoron, a decay product of thorium-232) is a gas, determination of thoron decay products in some environmental samples may be simpler, and their concentrations may be used as an indirect measure of the parent compound in the environment if a secular equilibrium is reached between thorium-232 and all its decay products. There are few analytical methods that will allow quantification of the speciation products formed as a result of environmental interactions of thorium (e.g., formation of complex). A knowledge of the environmental transformation processes of thorium and the compounds formed as a result is important in the understanding of their transport in environmental media. For example, in aquatic media, formation of soluble complexes will increase thorium mobility, whereas formation of insoluble species will enhance its incorporation into the sediment and limit its mobility. 

The opportunistic measurement techniques generally used are absorption and Rn disequilibrium (Asher and Wanninkhofi 1998). First, there is an estimate of a long-term ( 1,000 years) global gas transfer coefficient of = 6 x 10 m/s, developed by assuming steady state between pre-1950 radioactive decay in the oceans and absorption from the atmosphere (Broecker and Peng, 1982). In addition, nuclear testing since 1950 has increased concentration in the atmosphere. Thanks... 

By contrast, the gas transfer estimates utilizing Rn measurements assumes steady state between Rn production from radioactive decay of nonvolatile Rd and gas transfer with the atmosphere. This assumption is possible because Rn has a half-life of only 3.8 days, so accumulation and lateral ocean fluxes of Rn is assumed to be minimal. Again, a potential problem is the active, versus inactive layer of the ocean in this case, the mixed layer depth that may change during an experiment. 

Radon (222Rn) is formed by the radioactive decay of uranium, BKU (Fig. 15.1a). As a result, the highest concentrations tend to be associated with soils derived from rocks with a high uranium content (Nazaroff and Nero, 1988 Boyle, 1988 Nero, 1989 Mose and Mushrush, 1997). Because radon is a gas that diffuses out of the soil, it can enter homes through cracks in the foundation, around loose-fitting pipes and wall joints, and through floor drains (e.g., Nero, 1989). The concentrations found in a home depend on the type of soil (including the moisture content) on which it sits and the extent of Rn penetration into the house. They also depend on the house ventilation rate and the particular location in the house in which the measurement is... 

In 1900 Rutherford and the English chemist Frederick Soddy, working at McGill University in Montreal, showed that radioactive thorium emits atoms of the noble gas radon. Where did this inert element come from Rutherford and Soddy concluded that thorium was turning into a different element by undergoing radioactive decay. 

In INAA, a rock or mineral sample is irradiated in the reactor. The irradiated sample is removed from the reactor, and the dangerous radioactivities are allowed to decay. Then the sample is placed into a counter and the y-rays emitted by each element in the sample are counted. A variety of counters are used, including scintillation counters, gas ionization counters, or semi-conductor counters. For the most precise results, background counts in the detectors produced by electronic noise, cosmic rays, and other radioactive decays must be eliminated. The technique is very sensitive, and samples as small as a few tens of milligrams can be measured. 

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