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Diatomic hydrogen

Raman Spectroscopy. Raman spectroscopy is an excellent method for the analysis of deuterium containing mixtures, particularly for any of the diatomic H—D—T molecules. For these, it is possible to predict absolute light scattering intensities for the rotational Raman lines. Hence, absolute analyses are possible, at least in principle. The scattering intensities for the diatomic hydrogen isotope species is comparable to that of dinitrogen, N2, and thus easily observed. [Pg.9]

Mass Spectrometer. The mass spectrometer is the principal analytical tool of direct process control for the estimation of tritium. Gas samples are taken from several process points and analy2ed rapidly and continually to ensure proper operation of the system. Mass spectrometry is particularly useful in the detection of diatomic hydrogen species such as HD, HT, and DT. Mass spectrometric detection of helium-3 formed by radioactive decay of tritium is still another way to detect low levels of tritium (65). Accelerator mass spectroscopy (ams) has also been used for the detection of tritium and carbon-14 at extremely low levels. The principal appHcation of ams as of this writing has been in archeology and the geosciences, but this technique is expected to faciUtate the use of tritium in biomedical research, various clinical appHcations, and in environmental investigations (66). [Pg.15]

The simplest molecules contain just two atoms. For example, a molecule of hydrogen is made up of two hydrogen atoms. A molecule that contains two atoms is classified as a diatomic molecule. Figure FA represents a diatomic hydrogen molecule as two spheres connected together. [Pg.12]

He assumed that a pair of electrons is shared between two atoms in diatomic hydrogen and in other molecules, like methane. The electrons were modeled as a girdle of electrons rotating in a circle at a right angle to the axis connecting two atoms. [Pg.154]

KIE s on the Simplest Chemical Reaction (Hydrogen Atom + Diatomic Hydrogen)... [Pg.313]

For every molecule of hydrogen (H2) that reacts within a fuel cell, two electrons are liberated at the fuel cell anode. This is most easily seen in the PAFC and PEFC because of the simplicity of the anode (fuel) reaction, although the rule of two electrons per diatomic hydrogen molecule (H2) holds true for all fuel cell types. The solution also requires knowledge of the definition of an ampere (A) and an equivalence of electrons. [Pg.284]

Heitler-London covalence theory phys chem A calculation of the binding energy and the distance between the atoms of a diatomic hydrogen molecule, which assumes... [Pg.175]

Another type of bond is the covalent bond, in which one, two, or more pairs of electrons are shared by two or more atoms. Unlike ionic bonds, covalent bonds involve the sharing of electrons by atoms. The simplest example of covalent bonding occurs when two atoms of hydrogen bond to form a diatomic hydrogen molecule (H + H yield H H, or H ). [Pg.19]

After reading through several posts, it appears as if there is a problem regarding the current method of gas production coupled with its delivery into the combustion chamber. First and foremost is the "backfire" issue. Obviously it doesn t take much to cause diatomic hydrogen and oxygen to combine it s a rather unstable combination to begin with and not something to utilise carelessly. [Pg.38]

Diatomic hydrogen, H2, also exhibits a rich and remarkable complex soUd phase diagram. At low temperatures, when a H2-based solid is formed, electrons are confined in the H2 molecules and the soUd is thus a large-gap insulator. E. Wigner and H. B. Huntington predicted in 1935 the possibiUty of preparing... [Pg.5]

The values for the energy states of gaseous diatomic hydrogen are from Richardson3-4> 5 and Richardson and Das.1,2 See also Sandeman,1 Dieke and Hopfield,1 Hori,3 Schaafsma and Dieke,1 Richardson and Davidson,1 2> 3 5 Finkelnburg and Mecke,1,2 Mulliken,6 Jevons,1 and Burrau.1... [Pg.98]

How many molecules of hydrogen chloride, HC1, form when ten molecules of diatomic hydrogen, H2, react with ten molecules of diatomic chlorine, Cl2 If ten molecules represent one volume, how many volumes of hydrogen chloride form ... [Pg.84]

Diatomic hydrogen compounds have been studied extensively because of their simplicity in respect of the experimental and theoretical viewpoints. [Pg.5]

In a sense, when considering equivalence between atoms in a molecule, diatomic hydrogen is the simplest situation. However, in reality, just the opposite is found to be true. [Pg.12]

The reader will note that we avoided mention of the n 0 species and the difference of their enthalpies of formation and those with n = 1. For the gas phase Me2N(CH=CH) CHO series, the difference is 87.7 kJ mol-1 while for the H(CH=CH) H series it is 52.5 kJ mol-1. For the liquid phase Me2N(CH=CH) CHO series, the difference is 64.3 kJ mol-1, while for the solid phase Ph(CH=CH) Ph and PhN=CH(CH=CH) NHPh series, they are now 8 and 37.5 kJ mol-1. A pattern is not particularly obvious—then again we have included real amides and amidines, biphenyl that wants to be twisted and diatomic hydrogen. Perhaps we have taken chemical homology and analogy too far. [Pg.274]

A A sigma bond is a single bond that is formed from the overlap of s orbitals. A diatomic hydrogen molecule falls under this category. [Pg.29]

Notice that the ratio 1 16 is the smallest integer (whole number) ratio. It is obtained by dividing both numbers in the ratio by the smaller number, and then rounding the larger number to remove the digits after the decimal. The ratio of the molar masses is one to sixteen. In other words, the ratio indicates that the molar mass of diatomic hydrogen gas is sixteen times smaller than the molar mass of diatomic oxygen gas. [Pg.908]

In this case, the simplified fraction is calculated by dividing both the numerator (top of the fraction) and the denominator (bottom of the fraction) by 2.00. This fraction yields the same information as the ratio. That is, diatomic hydrogen gas has one-sixteenth the mass of diatomic oxygen gas. [Pg.908]

Thus, diatomic hydrogen gas has 6.25% of the mass of diatomic oxygen gas. [Pg.909]

Before we attempt to balance an equation, all substances must be represented by formulas that describe them as they exist. For instance, we must write H2 to represent diatomic hydrogen molecules—not H, which represents hydrogen atoms. Once the correct formulas are written, the subscripts in the formulas may not be changed. Different subscripts in formulas specify different compounds, so changing the formulas would mean that the equation would no longer describe the same reaction. [Pg.91]

In diatomic hydrogen each atom has one electron to share. [Pg.24]

The nature of vibrationally and rotationally predissociating states of atom-diatom Van der Waals molecules and the fundamental considerations governing their predissociation are discussed. Particular attention is focussed on the influence of the potential energy surface and the information about it which might be extracted from accurate measurements of predissociation lifetimes. Most of the results discussed pertain to the molecular hydrogen-inert gas systems, and details of previously unpublished three-dimensional potential energy surfaces for diatomic hydrogen with krypton and xenon are presented. [Pg.231]


See other pages where Diatomic hydrogen is mentioned: [Pg.16]    [Pg.141]    [Pg.146]    [Pg.67]    [Pg.495]    [Pg.154]    [Pg.38]    [Pg.38]    [Pg.16]    [Pg.50]    [Pg.340]    [Pg.414]    [Pg.98]    [Pg.802]    [Pg.174]    [Pg.126]    [Pg.131]    [Pg.2]    [Pg.280]    [Pg.91]    [Pg.146]    [Pg.164]    [Pg.340]    [Pg.33]   
See also in sourсe #XX -- [ Pg.22 ]

See also in sourсe #XX -- [ Pg.136 ]




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