Natural decay, radioactivity

Tritium [15086-10-9] the name given to the hydrogen isotope of mass 3, has symbol or more commonly T. Its isotopic mass is 3.0160497 (1). Moletecular tritium [10028-17-8], is analogous to the other hydrogen isotopes. The tritium nucleus is energetically unstable and decays radioactively by the emission of a low-energy P particle. The half-life is relatively short (- 12 yr), and therefore tritium occurs in nature only in equiUbrium with amounts produced by cosmic rays or man-made nuclear devices. 

Analyses of this type are correct only if all of the product nuclide comes from radioactive decay. This is not known with certainty, but when age estimates using different pairs of nuclides give the same age and samples from different locations also agree, the age estimate is likely to be accurate. Note also that 3.8 X 10 years agrees with the qualitative limits derived from naturally occurring radioactive nuclides. 

The picture shows one of the three natural decay series according to which heavy, radioactive nuclei eventually decay to stable lead atoms. 

Radon-222, a decay product of the naturally occuring radioactive element uranium-238, emanates from soil and masonry materials and is released from coal-fired power plants. Even though Rn-222 is an inert gas, its decay products are chemically active. Rn-222 has a a half-life of 3.825 days and undergoes four succesive alpha and/or beta decays to Po-218 (RaA), Pb-214 (RaB), Bi-214 (RaC), and Po-214 (RaC ). These four decay products have short half-lifes and thus decay to 22.3 year Pb-210 (RaD). The radioactive decays products of Rn-222 have a tendency to attach to ambient aerosol particles. The size of the resulting radioactive particle depends on the available aerosol. The attachment of these radionuclides to small, respirable particles is an important mechanism for the retention of activity in air and the transport to people. 

This very long half-life (1.25x1(r years) isotope comprises 0.0117 percent of all potassium. Thus, this isotope is present in all of us and has always been so. In addition, the materials around us, including the soil and the building materials, contain both potassium and the heavy naturally occurring radioactive elements thorium and uranium that contribute to a level of radiation to which we are all continuously exposed. Thus, there is always radiation exposure to the general public and we must understand the exposure due to radon in this context. The amount of radioactivity is described in units of activity. The activity is the number of decay events per unit time and is calculated as follows... 

This results in the transmutation of parent element X into daughter Y, which has an atomic number two less than X. The particular isotope of element Y which is formed is that with an atomic mass of four less than the original isotope of X. Note that, as in chemical reactions, these nuclear reactions must be numerically balanced on either side of the arrow. Many of the heavy elements in the three naturally occurring radioactive decay chains (see below) decay by a-emission. 

Radon is a radioactive gas that seeps into our homes, schools, and offices. It is produced by the natural decay of radium in the ground. Radon gas is thought to be a cause of some cancers, particularly lung cancer, as it seeps into the ground levels of buildings. Kits are available for testing the levels of radon that may exist in your home—particularly the basement or ground-level areas. 

Most of the known chemistry of polonium is based on the naturally occurring radioactive isotope polonium-210, which is a natural radioactive decay by-product of the uranium decay series. Its melting point is 254°C, its boiling point is 962°C, and its density is 9.32g/cm. ... 

Plutonium exists in trace amounts in nature. Most of it isotopes are radioactive and manmade or produced by the natural decay of uranium. Plutonium-239 is produced in nuclear reactors by bombarding uranium-238 with deuterons (nuclei of deuterium, or heavy hydrogen). The transmutation process is as follows + deuterons—> 2 nuclei + Np + p— ... 

Table 11.2 Naturally occurring radioactive substances, a = years, d = days. Radionuclide Decay Process Half-Life Isotopic Abundance (%) Stable End-Product...

Radon is a naturally occurring radioactive decay product of uranium. A great deal of attention 222 228 centers around radon, which is the first decay product of radium. Radon and radon... 

Radioactive decay usually does not immediately lead to a stable end product, but to other unstable nuclei that form a decay series (Kiefer 1990). The most important examples of unstable nuclei are started by very heavy, naturally occurring nuclei. Because the mass number changes only with a decay, all members of a series can be classified according to their mass numbers (see the uranium-238 decay series in Figure 32.2). A total of three natural decay series — formed at the birth of our planet — are named after their parent isotope Th, and (Figure 32.3). Several shorter decay series also exist. For example, Sr decays with a Tb 1/2 of 28 years by [3 emission to °Y, which in turn disintegrates (P emission) with a Tb 1/2 of 64 h to the stable °Zr (Kiefer 1990). Other examples of known radionuclides since the Earth s origin include " °K and Rb. In hazard assessments, all members of a decay series must be considered. 

Like most natural events, radioactive decay is not a uniform function. Consequently, the term half-life is meant to describe the value that would result if an infinite number of half-life measurements were made and the average calculated. Individual decays, however, follow a Poisson distribution, i.e.. the standard deviation is equal lu the square root of the number of observed decay events. This fact enables the experimenter to calculate the probable accuracy of his result, assuming no instrumentation inaccuracy. 

In any use of radioactive dating or age determining processes, a basic assumption is. in general, that the concentration of the radioactive element is changed during the life of the sample only by its natural decay process, and that the accuracy of the determination depends primarily, therefore, upon the accuracy with which the half-life of that radionuclide is known. 

All naturally occurring radioactive nuclei have extremely small partial widths. Did you notice that 64Cu can decay into 64Zn and 64Ni This is unusual but can occur for certain odd-odd nuclei (see Chapter 2). 

Viewed in the context of the actinide lifespan, the nuclear fuel cycle involves the diversion of actinides from their natural decay sequence into an accelerated fission decay sequence. The radioactive by-products of this energy producing process will themselves ultimately decay but along quite different pathways. Coordination chemistry plays a role at various stages in this diversionary process, the most prominent being in the extraction of actinides from ore concentrate and the reprocessing of irradiated fuel. However, before considering these topics in detail it is appropriate to consider briefly the vital role played by coordination chemistry in the formation of uranium ore deposits. 

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