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Processing material formation

Steps such as the substitution of low sulfur fuels or nonvolatile solvents, change of taw materials, lowering of operation temperatures to reduce NO formation or vo1ati1i2ation of process material, and instaHion of weU-designed hoods (31—37) at emission points to effectively reduce the air quantity needed for pollutant capture are illustrations of the above principles. [Pg.385]

Another method of purifying niobium is by distillation of the anhydrous mixed chlorides (29). Niobium and tantalum pentachlorides boil within about 15°C of one another which makes control of the process difficult. Additionally, process materials must withstand the corrosion effects of the chloride. The system must be kept meticulously anhydrous and air-free to avoid plugging resulting from the formation of niobium oxide trichloride, NbOQ. Distillation has been used commercially in the past. [Pg.23]

Another purpose of inerting is to control oxygen concentrations where process materials are subject to peroxide formation or oxidation to form unstable compounds (acetylides, etc.) or where materials in the process are degraded by atmospheric oxygen. An inert gas supply of sufficient capacity must be ensured. The supply pressure must be monitored continuously. [Pg.38]

The second slop is to obtain all the information about the process that will be needed for a Ihorongh evaluation including but not limited to the process materials used and their physical properties, the chemistry and tlicnnodynamics of the process, a plant layout, and a description of all the equipment used including controls and instrumentation. The last part of the information gathering step nitty be viewed as the preliminary formation of the What If questions. [Pg.443]

The Phillips Cr/silica catalyst is prepared by impregnating a chromium compound (commonly chromic acid) onto a support material, most commonly a wide-pore silica, and then calcining in oxygen at 923 K. In the industrial process, the formation of the propagation centers takes place by reductive interaction of Cr(VI) with the monomer (ethylene) at about 423 K [4]. This feature makes the Phillips catalyst unique among all the olefin polymerization catalysts, but also the most controversial one [17]. [Pg.8]

The fabrication and characterization of atomic metal contacts have been based mainly on electro-deposition/dissolution [182] and break junction techniques (see review [134] and literatures cited therein). In particular, gold nanocontacts have been studied in great detail, due to the chemical inertness of the material, the malleability and ductility of gold. The processes of formation, evolution, and breaking of gold atomic contacts leads to step-like features in the current-distance curves [188, 189]. The abrupt changes in the current (conductance) response were... [Pg.134]

In summary, the extinct radioactivities which have a limited time of existence in the solar system, constrain the time interval between the late stages of stellar nucleosynthesis and the formation of the solar system. Some production may also occur within the solar system during active periods of the young Sun. There have been numerous studies about how this matter was added into the solar system as a late spike of about 10 solar masses of freshly stellar processed material or from constant production in the galaxy (Wasserburg et al. 1996 Goswami and Vanhala 2000 Russell et al. 2001). These models are refined constantly with the input of new data and will probably continue to evolve in the future. [Pg.54]

The first device was a circular-shape microhotplate, which essentially consisted of CMOS-process materials (Sect. 4.1). The fabrication of this microhotplate required a minimum of post-CMOS processing steps. The electrochemical etching process used for the membrane release and the formation of the circular-shape Si island was optimized and can now be routinely apphed on wafer-level. [Pg.108]

Crystallization is the process by which particles are produced by precipitation of the material in a suitable solvent. The level of control over this process determines the physical nature and size of the finished particles. Most pharmaceutical bulk material is produced through crystallization as the final stage of the manufacturing process. The formation of a pime, crystalline material is normally the target of this final step. [Pg.100]

Attempts to prepare a bicyclobutane by reductive cydization of cyclobutane-1,3-diones have been unsuccessful [114]. a,o)-Dibenzoylalkanes are reduced at a mercury cathode to cycloalkanediols only when a ring size of 5 or 6 results. These reactions have been achieved using either aqueous ethanolic sodium hydroxide [115] or acetonitrile containing tetramethylammonium tetrafluoroborate [113] as electrolyte. Attempts to extend the process to formation of 7-membered rings lead only to oligomeric materials. [Pg.351]

An elegant four-enzyme cascade process was described by Nakajima et al. [28] for the deracemization of an a-amino acid (Scheme 6.13). It involved amine oxidase-catalyzed, (i )-selective oxidation of the amino acid to afford the ammonium salt of the a-keto acid and the unreacted (S)-enantiomer of the substrate. The keto acid then undergoes reductive amination, catalyzed by leucine dehydrogenase, to afford the (S)-amino acid. NADH cofactor regeneration is achieved with formate/FDH. The overall process affords the (S)-enantiomer in 95% yield and 99% e.e. from racemic starting material, formate and molecular oxygen, and the help of three enzymes in concert. A fourth enzyme, catalase, is added to decompose the hydrogen peroxide formed in the first step which otherwise would have a detrimental effect on the enzymes. [Pg.119]

As in all large-scale industrial processes, the formation of the cellulose esters involves recovery of materials. Acetic anhydride is generally employed. After reaction, acetic acid and solvent are recovered. The recovered acetic acid is employed in the production of additional acetic anhydride. The recovered solvent is also reintroduced after treatment. [Pg.270]

Bulk material formation from leached particles by SPS process... [Pg.163]

The results of the Hg2 reaction experiments using particle-size-mediated synthesized metal sulfides are shown in Table 5. The powder XRD pattern of the resulting solids reveals amorphous material formation. Previous studies using Cu,S revealed the removal of Hg by a process other than dissolved sulfide precipitation [10], Other researchers have shown that MoS2 removes Fig2 from aqueous solutions via an intercalation mechanism [11]. [Pg.771]

Through the choice of the appropriate combination of solvent and operating conditions for a particular compound, PGSS can eliminate some of the disadvantages of traditional methods of particle-size redistribution in material processing. Solids formation by PGSS therefore shows potential for the production of crystalline and amorphous powders with a narrow and controllable size-distribution, thin films, and mixtures of amorphous materials. [Pg.609]

COAL. Containing more than 50% (weight) and 70% (volume) of carbonaceous material, including Inherent moisture, coal is a readily combustible rock. Coal was formed from the compaction and induration of variously altered plant remains similar lo those found in peal. Coal was formed during earlier geological periods, the process of formation acting slowly over extremely long periods of lime. Coal is not a uniform substance, but reflects the conditions of its formation. These include ... [Pg.389]

Packaging formats and materials will all play then part in appealing to die consumer. It is important to consider whether the product is to be in a multiserve or single-serve pack, purchased in a supermarket as part of a weekly shop or as an impulse purchase in a fast-food outlet, garage forecourt or corner 24-7 shop. This may affect the pack size, material format and hence the product processing conditions available to the drink development technologists. [Pg.200]

Growth Pattern Bacteria reproduce predominantly by a process known as binary fission as illustrated in Figure 5.3. This process involves several steps cell elongation, invagination of the cell wall, distribution of nuclear material, formation of the transverse cell wall, distribution of cellular material into two cells, and separation into two new cells. This is an asexual reproductive process. [Pg.95]

The environmentally benign, nontoxic, and nonflammable fluids water and carbon dioxide (C02) are the two most abundant and inexpensive solvents on Earth. Water-in-C02 (w/c) or C02-in-water (c/w) dispersions in the form of microemulsions and emulsions offer new possibilities in waste minimization for the replacement of organic solvents in separations, reactions, and materials formation processes. Whereas the solvent strength of C02 is limited, these dispersions have the ability to function as a universal solvent medium by solubilizing high concentrations of polar, ionic, and nonpolar molecules within their dispersed and continuous phases. These emulsions may be phase-separated easily for product recovery (unlike the case for conventional emulsions) simply by depressurization. [Pg.135]


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See also in sourсe #XX -- [ Pg.344 ]




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