Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Precision qualitative applications using

The physical properties determined using the ECD are important to different areas of chemistry. Analytical chemistry deals with how much and what are involved in a chemical reaction. Expressed differently, it establishes what we refer to as the QQQ quantitation, qualitative identification, and the quality of the results. The determination of the electron affinities of the chlorinated biphenyls, dioxins, and phenols and the prediction of the response of the ECD and NIMS are important to qualitative and quantitative analyses of environmental pollutants [21]. Polarographic reduction in solutions likewise gives accurate and precise qualitative and quantitative results. The quality of the analyses is expressed by the random and systematic uncertainties in the reported values. These are obtained from the same principle of weighted least squares used to obtain information from ECD data. Wentworth has described the application of the general least-squares procedure to chemical problems [22, 23]. [Pg.3]

Molecular symmetry and ways of specifying it with mathematical precision are important for several reasons. The most basic reason is that all molecular wave functions—those governing electron distribution as well as those for vibrations, nmr spectra, etc.—must conform, rigorously, to certain requirements based on the symmetry of the equilibrium nuclear framework of the molecule. When the symmetry is high these restrictions can be very severe. Thus, from a knowledge of symmetry alone it is often possible to reach useful qualitative conclusions about molecular electronic structure and to draw inferences from spectra as to molecular structures. The qualitative application of symmetry restrictions is most impressively illustrated by the crystal-field and ligand-field theories of the electronic structures of transition-metal complexes, as described in Chapter 20, and by numerous examples of the use of infrared and Raman spectra to deduce molecular symmetry. Illustrations of the latter occur throughout the book, but particularly with respect to some metal carbonyl compounds in Chapter 22. [Pg.3]

Near-infrared (NIR) spectroscopy has been found to be a useful technique to characterize raw materials and finished textile products, and NIR methods and techniques continue to find increasingly diverse and wide-ranging quantitative and qualitative applications in the textile industry. Quantitative analyses determine the amount (or quantity) of the property/species of interest in a substance or material. Qualitative analyses can be used to either identify a specific species or subsfance present in a material (i.e., coating on a fiber), the type of material itself (i.e., cotton, nylon, or polyester), or the quality of the material. NIR quantitative and qualitative methods allow the user to rapidly, accurately, and precisely monitor key chemical, physical, and morphological properties of textile fibers, yarns, fabrics, and chemical textile auxiliaries. Chemical properties are specific chemical species or groups present in the material (i.e., CH, OH, NH) that result in NIR spectral absorbencies at distinctive... [Pg.485]

The use of a model of human error allows a systematic approach to be adopted to the prediction of human failures in CPI operations. Although there are difficulties associated with predicting the precise forms of mistakes, as opposed to slips, the cognitive approach provides a framework which can be used as part of a comprehensive qualitative assessment of failure modes. This can be used during design to eliminate potential error inducing conditions. It also has applications in the context of CPQRA methods, where a comprehensive qualitative analysis is an essential precursor of quantification. The links between these approaches and CPQRA will be discussed in Chapter 5. [Pg.85]

The main uses of TLC include (1) qualitative analysis (the identification of the presence or absence of a particular substance in the mixture), (2) quantitative analysis (precise and accurate determination of a particular substance in a sample mixture), and (3) preparative analysis (purification and isolation of a particular substance for subsequent use). All these analytical and preparative applications of TLC require the common procedures of sample apphcation, chromatographic separation, and... [Pg.348]

Before performing a validation method for a certain application, the scope of the method and its validation criteria should be defined first. The parameters to be investigated include compounds, matrices, types of formation, qualitative or quantitative method, detection or quantitation limit, linear range, precision and accuracy, types of equipment that will be used, and the location of the system. These steps of the validation method are illustrated in Fig. 1, which has been modified from Ref. [11],... [Pg.245]

Potentially applicable to a wide range of organic materials. Most use has been made in the analysis of polymers and oils. Essentially a qualitative technique with poor precision for quantitative measurements. [Pg.496]

Analytical biochemistry involves the use of laboratory methods to determine the composition of biological samples and it has applications in many widely differing areas of biological science. The information gained from an analysis is usually presented as a laboratory report, which may simply say what substances are present (a qualitative report) or may specify the precise amount of a substance in the sample (a quantitative report). [Pg.1]

The application of atomic spectroscopic instruments as element-specific detectors in chromatography has been reviewed by van Loon More recently, Krull has extensively reviewed their use in high pressure liquid chromatography (HPLC). Atomic spectrometry has found wide acceptance in the field of liquid chromatography because, in most cases, the fractions can be directly analysed after elution from the column. However, it is possible to use the technique for the analysis of solid samples without first dissolving the matrix. This is particularly useful after electrophoresis, where the fractions are fixed either in a gel or on paper. Kamel et al. have shown that it is possible to cut the appropriate sections and insert them into the carbon furnace for analysis. The disadvantage of this approach is that the precision is usually poorer (about 10%) and it is difficult to calibrate the instrument. Nevertheless, this approach is very useful if it is used for qualitative speciation. [Pg.164]

Mathematica, Interactive Physics, Spartan, and Odyssey are all available with protocols and content (sometimes from third parties) for subject-specific topics. The learning objectives, however, go beyond those of specific content. Being very different from memorization aids, method-based learning environments have at least the potential to familiarize students with the process and the principles of science. It is precisely the use of a multi-purpose tool that makes students invoke the generic reasoning skills, both qualitatively and quantitatively, that are the hallmark of a scientifically literate mind. Sometimes there is value in using fewer applications for more purposes ... [Pg.209]

Tire performance of an analytical method and its inherent reliability are characterized by a set of quality parameters that determine its applicability and its usefulness, b or a quantitative method, the most notable parameters are its precision, accuracy, and limit of detection. For a qualitative method, the most important characteristic is its reliability in the identification of the analyte. Since there may be found in the literature an enormous set of different methods for analyzing a particular analyte in a particular matrix, it must be decided which method is the most appropriate for the analysis. [Pg.772]

An important issue of the application of electronic structure theory to polyatomic systems is the selection of the appropriate basis set. As usual in quantum chemistry, a compromise between precision and computational cost has to be achieved. It is generally accepted that in order to obtain qualitatively correct theoretical results for valence excited states of polyatomic systems, a Gaussian basis set of at least double-zeta quality with polarization functions on all atoms (or at least on the heavy atoms) is necessary. For a correct description of Rydberg-type excited states, the basis set has to be augmented with additional diffuse Gaussian functions. Such basis sets were used in the calculations discussed below. [Pg.417]

The preparation of a derivative of a sample compound prior to GC is a significant potential source of both qualitative and, in particular, quantitative errors. Almost all reactions that are used for derivatization are organic syntheses adapted to the micro-scale. This approach makes full use of an advantageous property of GC, namely the need to take only very small amounts of the sample for the analysis, but on the other hand, it makes heavy demands on the quality of the materials used and the precision of the operating procedures. As GC has especially been used in analyses of complex mixtures with large contents of various components, such as biological samples, the operations necessary for the preliminary separation of the compounds of interest from the sample, e.g., extraction or TLC, are often involved in the entire procedure, and make it even more complicated. With some reactions, the necessity for an anhydrous medium requires the application of drying (lyophilization) in the treatment of the sample. [Pg.9]

The importance of linear chromatography comes from the fact that almost all analytical applications of chromatography are carried out xmder such experimental conditions that the sample size is small, the mobile phase concentrations low, and thus, the equilibrixim isotherm linear. The development in the late 1960s and early 1970s of highly sensitive, on-line detectors, with detection limits in the low ppb range or lower, permits the use of very small samples in most analyses. In such cases the concentrations of the sample components are very low, the equilibrium isotherms are practically linear, the band profiles are symmetrical (phenomena other than nonlinear equilibrium behavior may take place see Section 6.6), and the bands of the different sample components are independent of each other. Qualitative and quantitative analyses are based on this linear model. We must note, however, that the assumption of a linear isotherm is nearly always approximate. It may often be a reasonable approximation, but the cases in which the isotherm is truly linear remain exceptional. Most often, when the sample size is small, the effects of a nonlinear isotherm (e.g., the dependence of the retention time on the sample size, the peak asymmetry) are only smaller than what the precision of the experiments permits us to detect, or simply smaller than what we are ready to tolerate in order to benefit from entertaining a simple model. [Pg.282]


See other pages where Precision qualitative applications using is mentioned: [Pg.360]    [Pg.30]    [Pg.509]    [Pg.373]    [Pg.217]    [Pg.335]    [Pg.268]    [Pg.260]    [Pg.1176]    [Pg.791]    [Pg.289]    [Pg.221]    [Pg.5]    [Pg.158]    [Pg.324]    [Pg.416]    [Pg.93]    [Pg.179]    [Pg.560]    [Pg.52]    [Pg.225]    [Pg.293]    [Pg.336]    [Pg.259]    [Pg.6083]    [Pg.102]    [Pg.5]    [Pg.321]    [Pg.3373]    [Pg.119]    [Pg.217]    [Pg.118]    [Pg.60]    [Pg.57]    [Pg.68]   
See also in sourсe #XX -- [ Pg.575 ]




SEARCH



Applications qualitative

© 2024 chempedia.info