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Polypropylene synthesis methods

A nylon-clay hybrid (nanocomposite NCH) was originally developed by the authors and was the first polymer nanocomposite to be used practically. Since 1990, when it was first used, various studies and analyses of it have been reported. An excellent review was published in 2003 [1]. In the present review, which focuses on the authors studies, details on the NCH that we reported initially and further developments in polypropylene and polyethylene will be described. In Sect. 2, comprehensive classifications of the production methods developed previously will be described, according to the synthesis method employed. Thereafter, nylon will be discussed in Sect. 3, polyolefin in Sect. 4, and renewable polymer (green polymer) will be discussed in Sect. 5. [Pg.137]

In the late 1980s, Frank and coworkers developed a method for parallel solid phase synthesis where the molecules were linked to a membrane rather than to conventional polystyrene beads [26,27]. Libraries were prepared by adding the different reagents at each of the spots on the membrane. This SPOT-synthesis method can be carried out on cellulose and polypropylene sheets (loading lOO-lOOOOnM/cm or lO-lOOnM/cm, respectively) and requires no specialized infrastructure to obtain libraries. The mean spot size... [Pg.316]

Practical methods for synthesis and elucidation of the optimum physical forms were developed at Du Pont (13). The violets fill the void in the color gamut when the inorganics are inadequate. The quinacridones may be used in most resins except polymers such as nylon-6,6, polystyrene, and ABS. They are stable up to 275°C and show excellent weatherabiUty. One use is to shade phthalocyanines to match Indanthrone Blue. In carpeting, the quinacridones are recommended for polypropylene, acrylonitrile, polyester, and nylon-6 filaments. Predispersions in plastici2ers ate used in thermoset polyesters, urethanes, and epoxy resins (14). [Pg.462]

Recently, Murray and Gellman demonstrated that parallel synthesis in inexpensive 96-well polypropylene filter plates with microwave irradiation in a multimode reactor is a simple and effective method for the rapid preparation of j8-peptide hbraries on sohd support in acceptable purities [156]. [Pg.93]

Microwave-assisted reactions allow rapid product generation in high yield under uniform conditions. Therefore, they should be ideally suited for parallel synthesis applications. The first example of parallel reactions carried out under microwave irradiation conditions involved the nucleophilic substitution of an alkyl iodide with 60 diverse piperidine or piperazine derivatives (Scheme 4.22) [76]. Reactions were carried out in a multimode microwave reactor in individual sealed polypropylene vials using acetonitrile as solvent. Screening of the resulting 2-aminothiazole library in a herpes simplex virus-1 (HSV-1) assay led to three confirmed hits, demonstrating the potential of this method for rapid lead optimization. [Pg.74]

In 1993 we have published a method which met most of these requirements and for the first time allowed for the large-scale synthesis of dendrimers [2], Since that time, each of the steps have been optimized in the reaction scheme. In this chapter, we present state-of-the-art procedures for the large-scale production of the polypropylene imine) dendrimers. [Pg.606]

A line of research that has aroused much interest in recent years is the study of head-to-head, tail-to-tail polymers (96-98). Their direct synthesis has little likelihood of being successffil as head-to-tail sequences usually predominate in vinyl polymerization. One possibility for their preparation is through the chemical modification of suitable preformed polymers. In the case of the head-to-head, tail-to-tail polypropylene, different stereoisomeric forms have been isolated, depending on the method of preparation. In the general scheme, the precursor is an unsaturated polymer obtained by polymerization of the disubsti-tuted butadiene (2,3-dimethylbutadiene or 2,4-hexadiene) then, by chemical or catalytic reduction, this polymer is converted into the desired polypropylene, whose stmcture can then be examined by NMR spectra. Head-to-head, tail-to-... [Pg.17]

In the 1980s, a synthetic method to produce AB block copolymers of propylene and tetrahydrofurane (THF) was proposed [29]. Polypropylene-fi/ock-poly(THF) was prepared by a combination of living polymerization of propylene with a V(acac)3 catalyst and the living polymerization of THF. Its synthesis was based on the transformation of living polypropylene chain ends to cationic ones, which initiated the living polymerization of THF. [Pg.85]

In 1985 Houghton introduced his tea bag method for the rapid solid phase multiple peptide synthesis. In this technique the beads are contained within a porous polypropylene bag. All the reactions, including deprotections, are... [Pg.117]

The usual methods of synthesis of polypropylene oxide) lead to low molecular weight compounds which can be hydroxyl-ended [111]. Poly(-oxypropylene) polyols are used in the synthesis of rubbery polyurethanes [112,113]. [Pg.718]

A peptide library can be synthesized using the SPOT synthesis technique to form a low-density peptide spot array (e.g., 25 spots/cm ). In this method, different peptides are synthesized in situ as low-density arrays on cellulose membrane or paper (8). The volume of Fmoc-amino acids and coupling reagents dispensed creates a specific SPOT size that determines both the scale of reaction and the absolute number of peptides that can be arranged on an area of a membrane. Cotton (another form of cellulose) and polystyrene-grafted polyethylene film segments also have been used as solid supports. Recently, polymeric membranes that are chemically, mechanically, and thermally more stable have been developed, which include hydroxy-functionalized PEG acrylate polypropylene membranes and an amino-functionalized ester-free PEG... [Pg.1429]

Most synthetic methods for the generation of peptide libraries have been derived from various multiple parallel peptide synthesis techniques developed since 1984.bs-i l Consequently, the sohd supports used for hbrary synthesis are essentially the same as those used for multiple peptide synthesis. Standard divinylbenzene cross-linked polystyrene resins are typically used for hbraries that are cleaved from the resin and screened in solution.P Polyoxyethylene-grafted polystyrene resins,f l or acrylamide-polyoxyethylene copolymers, P on the other hand, are the sohd supports of choice for the synthesis of resin-bound peptide hbraries screened in sohd-phase binding assays.P Such resins are compatible with both organic solvents used for peptide synthesis, as well as aqueous buffers used in the bioassays. Various segmental supports previously employed for multiple peptide syntheses have also been utilized for the synthesis of peptide libraries, including polypropylene pins, PI cotton,t cellulose membrane,and glass shdes.P ... [Pg.845]

A different way to produce chemical microarrays in situ is spot synthesis of combinatorial libraries on cellulose sheets [56]. Spot synthesis is configured as an open system to be operated at room temperature. Despite attempts to replace cellulose with polypropylene as a synthesis support [57], cellulose is still the support of choice for spot synthesis, and reaction conditions have to be compatible with the restricted chemical stability of cellulose. Due to the acid labihty of such membranes, the diversity content of these arrays was initially restricted to the synthesis of peptides. Recently, a method was described that could widen the scope of spot synthesis arrays. Germeroth and coworkers [57] succeeded in the assembly of a library of 8000 cellulose-bound 1,3,5-triazines under mild reaction conditions. They employed a strategy that took advantage of a temperature-dependent, successive displacement of cyanuric chlorides by different nucleophiles in a first report of the synthesis of smaU organic compounds on ceUulose sheets. [Pg.224]

In the so-called tea-bag method, originated in 1984 by Houghten et al. [14] for multiple peptide synthesis, the split-pool protocol occurs batchwise on 15 x 22 mm polypropylene mesh packets with pm-sized pores known as tea bags, sealed with resin beads for solid-phase synthesis. This method offers the advantage that a greater quantity of each compound of the library is available at once (up to 500 pmol), which is sufficient for a complete biological and structural characterization. Furthermore, the structural identity of... [Pg.6]

Figure 9.18 Schematic of the method of synthesis of a bridge-anchored ansa-metallocene. (The indenyl rings are shown in pseudo-racemic orientation as the high isotacticity of polypropylene produced with the catalyst suggests a structural analogy to rac-Et(Ind)2ZrCl2-(Soga et al., 1994.)... Figure 9.18 Schematic of the method of synthesis of a bridge-anchored ansa-metallocene. (The indenyl rings are shown in pseudo-racemic orientation as the high isotacticity of polypropylene produced with the catalyst suggests a structural analogy to rac-Et(Ind)2ZrCl2-(Soga et al., 1994.)...

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