Platinum electrical resistivity

Heating and Cooling. Heat must be appHed to form the molten zones, and this heat much be removed from the adjacent sohd material (4,70). In principle, any heat source can be used, including direct flames. However, the most common method is to place electrical resistance heaters around the container. In air, nichrome wine is useflil to ca 1000°C, Kanthal to ca 1300°C, and platinum-rhodium alloys to ca 1700°C. In an inert atmosphere or vacuum, molybdenum, tungsten, and graphite can be used to well over 2000°C. 

The bot-wire anemometer consists essentially of an electrically heated fine wire (generally platinum) exposed to the gas stream whose velocity is being measured. An increase in fluid velocity, other things being equal, increases the rate of heat flow from the wire to the gas, thereby tending to cool the wire and alter its electrical resistance. In a constant-current anemometer, gas velocity is determined by measuring the resulting wire resistance in the constant-resistance type, gas velocity is determined from the current required to maintain the wire temperature, and thus the resistance, constant. The difference in the two types is primarily in the electric circmts and instruments employed. 

Temperature The level of the temperature measurement (4 K, 20 K, 77 K, or higher) is the first issue to be considered. The second issue is the range needed (e.g., a few degrees around 90 K or 1 to 400 K). If the temperature level is that of air separation or liquefact-ing of natural gas (LNG), then the favorite choice is the platinum resistance thermometer (PRT). Platinum, as with all pure metals, has an electrical resistance that goes to zero as the absolute temperature decreases to zero. Accordingly, the lower useful limit of platinum is about 20 K, or liquid hydrogen temperatures. Below 20 K, semiconductor thermometers (germanium-, carbon-, or silicon-based) are preferred. Semiconductors have just the opposite resistance-temperature dependence of metals—their resistance increases as the temperature is lowered, as fewer valence electrons can be promoted into the conduction band at lower temperatures. Thus, semiconductors are usually chosen for temperatures from about 1 to 20 K. 

Resistance thermometers are made of a pure metal, such as platinum, nickel, or copper. The electrical resistance of such a material is almost linearly dependent on temperature. Resistance thermometers are stable, having a small drift. A widely used and the best-known resistance probe is the IW-100 probe, which is platinum, having a resistance of 100 ohms at the temperature of 0 °C. Other resistance values for PT probes are available. The resistance versus temperature values as well as tolerances for platinum probes are standardized. The shape and size of a resistance probe can vary considerably, resulting in changes in probe dynamics. 

The principal applications of the outstanding stability of platinum and its alloys at high temperatures lie in their use as materials of construction for equipment to handle molten glass and as electrical resistance windings for high-temperature furnaces. 

Rhodium-platinum alloys containing up to 40% Rh are used in the form of wire or ribbon in electrical resistance windings for furnaces to operate continuously at temperatures up to 1 750°C. Such windings are usually completely embedded in a layer of high-grade alumina cement or flame-sprayed alumina to prevent volatilisation losses from the metal due to the free circulation of air over its surface. Furnaces of this type are widely employed for steel analysis, ash fusions and other high-temperature analytical procedures. 

It is a valve metal and when made anodic in a chloride-containing solution it forms an anodic oxide film of TiOj (rutile form), that thickens with an increase in voltage up to 8-12 V, when localised film breakdown occurs with subsequent pitting. The TiOj film has a high electrical resistivity, and this coupled with the fact that breakdown can occur at the e.m.f. s produced by the transformer rectifiers used in cathodic protection makes it unsuitable for use as an anode material. Nevertheless, it forms a most valuable substrate for platinum, which may be applied to titanium in the form of a thin coating. The composite anode is characterised by the fact that the titanium exposed at discontinuities is protected by the anodically formed dielectric Ti02 film. Platinised titanium therefore provides an economical method of utilising the inertness and electronic conductivity of platinum on a relatively inexpensive, yet inert substrate. 

Electrical resistance thermometers, the most widely used of which is Callendar s platinum resistance thermometer. This is probably the most convenient and accurate apparatus for measuring temperatures between the boiling-point of liquid air (—190° C.) and the melting-point of platinum (1,500° C.). Lead has recently been applied at very low temperatures. 

Flammable atmospheres can be assessed using portable gas chromatographs or, for selected compounds, by colour indicator tubes. More commonly, use is made of explos-imeters fitted with Pellistors (e.g. platinum wire encased in beads of refractory material). The beads are arranged in a Wheatstone bridge circuit. The flammable gas is oxidized on the heated catalytic element, causing the electrical resistance to alter relative to the reference. Instruments are calibrated for specific compounds in terms of 0—100% of their lower flammable limit. Recalibration or application of correction factors is required for different gases. Points to consider are listed in Table 9.10. 

The electric resistance of metals decreases as temperature is lowered down to about 20 K. The most used metal as thermometric material is platinum. Platinum is chemically resistant and can be produced with high purity (minimizing the temperature-independent... 

Platinum sensors exploit the fact the electrical resistance of platimum metal is temperature dependent. This behaviour can be described by a polynomial of the form... 

A second, popular, standard is the platinum-resistance thermometer. Here, the electrical resistance R of a long wire of platinum increases with increased temperature, again with an essentially linear relationship. 

The conductance of a solution is the inverse of its resistance, and conductance has units of ohms 1 or mohs. The higher the conductance of a solution, the lower is its electrical resistance. A conductivity meter and conductivity cell are used to determine the effective resistance of a solution. The conductivity cell consists of a pair of platinized platinum electrodes with an area of approximately 1.0 cm2 with spacers designed to hold the electrodes rigidly parallel and at a fixed distance from each other. The cell can be standardized with solutions of known conductivity to obtain the cell constant, k so that the instrument response R... 

Figure 11.1 (a) Scheme of an isoperibol titration calorimetry apparatus A Dewar vessel B lid C stirrer D electrical resistance E thermistor F titrant delivery tube G O-ring seal, (b) Vessel for isothermal operation A stainless-steel, platinum, or tantalum cup B water-tight stainless steel container C heater D Peltier thermoelectric cooler E O-ring seal F heater and cooler leads. Adapted from [211],... 

Tsrical electric resistance between two points at a distance of 1 cm on the platinum surface (circle with 1.3 cm in diameter) was 5 Q. 

On the other hand, some of Suhrmann s electrical resistance measurements on nickel and platinum films and Eischens observations, of the effect of Hj on the infrared spectrum of chemisorbed CO on platinum, referred to earlier, suggest electron-transfer from hydrogen to the metal, i.e., adsorption of positive ions. 

Dilatometer. Reliable kinetic data on gamma-induced emulsion polymerization can be obtained only when the polymerization rate is measured continuously (7). The recording dilatometer used in our previous work had some disadvantages. A mercury meniscus traveled down a precision capillary, releasing a thin platinum wire within the capillary. The electrical resistance of this assembly was used as a measure for the... 

The lone electrons of the 0 atom in the H2O molecule can also become part of the electron gas in the metal surface and reduce its work function. So Schaaff (75) observed an increase of the photoelectric emission of platinum in the presence of water vapor. On the other hand an adsorbed layer of H2O molecules on the surface of a thin nickel film decreases the electric resistance of the film (18). 

A cross-section schematic drawing of the newly-developed thick film oxygen sensor is shown in Figure 2. The platinum film heater is embedded in the alumina substrate. Electrical resistance of the heater is about 6 ohms at room temperature. 

Fig. 1.21.1. Schematic drawing of an instrument to measure the electrical resistance (ER) of a sample during cooling and rewarming (Figure 1 from [1.27]). 1 = Platinum electrodes 2 = temperature sensor in the product ...

The method determines the partial pressure of methane in the gas phase above the solution (Henry s law). Methane catalytically oxidizes on a heated platinum filament, that is part of a Wheatstone bridge. The heat generated increases the electrical resistance of the filament which is measured and compared against calibrated standards. 

The hot-wire anemometer, principally used in gas flow measurement, consists of an electrically heated, fine platinum wire which is immersed into the flow. As the fluid velocity increases, the rate of heat flow from the heated wire to the flow stream increases. Thus, a cooling effect on the wire electrode occurs, causing its electrical resistance to change. In a constant-current anemometer, the fluid velocity is determined from a measurement of the resulting change in wire resistance. In a constant-resistance anemometer, fluid velocity is determined from the current needed to maintain a constant wire temperature and, thus, the resistance constant. 

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