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Of organometallic compounds

Hard carbon nucleophiles of organometallic compounds react with 7r-allyl-palladium complexes. A steroidal side-chain is introduced regio- and stereo-selectively by the reaction of the steroidal 7T-allylpalladium complex 319 with the alkenylzirconium compound 320[283]. [Pg.64]

In addition, a catalytic version of Tt-allylpalladium chemistry has been devel-oped[6,7]. Formation of the Tr-allylpalladium complexes by the oxidative addition of various allylic compounds to Pd(0) and subsequent reaction of the complex with soft carbon nucleophiles are the basis of catalytic allylation. After the reaction, Pd(0) is reformed, and undergoes oxidative addition to the allylic compounds again, making the reaction catalytic.-In addition to the soft carbon nucleophiles, hard carbon nucleophiles of organometallic compounds of main group metals are allylated with 7r-allylpalladium complexes. The reaction proceeds via transmetallation. These catalytic reactions are treated in this chapter. [Pg.290]

The stereochemistry of the Pd-catalyzed allylation of nucleophiles has been studied extensively[5,l8-20]. In the first step, 7r-allylpalladium complex formation by the attack of Pd(0) on an allylic part proceeds by inversion (anti attack). Then subsequent reaction of soft carbon nucleophiles, N- and 0-nucleophiles proceeds by inversion to give 1. Thus overall retention is observed. On the other hand, the reaction of hard carbon nucleophiles of organometallic compounds proceeds via transmetallation, which affords 2 by retention, and reductive elimination affords the final product 3. Thus the overall inversion is observed in this case[21,22]. [Pg.292]

The properties of organometallic compounds are much different from those of the other classes we have studied to this point Most important many organometallic com pounds are powerful sources of nucleophilic carbon something that makes them espe cially valuable to the synthetic organic chemist For example the preparation of alkynes by the reaction of sodium acetylide with alkyl halides (Section 9 6) depends on the presence of a negatively charged nucleophilic carbon m acetylide ion... [Pg.587]

A large number of organometallic compounds are based on transition metals Examples include organic derivatives of iron nickel chromium platinum and rhodium Many important industrial processes are catalyzed by transition metals or their complexes Before we look at these processes a few words about the structures of transition metal complexes are m order... [Pg.608]

Chapman and Hall Chemical Database Chapman and Hall, Ltd. Dialog Dictiona of Organic Compounds (5th ed.), Dictiona of Organometallic Compounds, Carbohydrates, Mmino Mcids, Peptides, Dictionay of Antibiotics and Eelated Compounds, and Dictionay of Organophosphorus Compounds... [Pg.120]

T. G. Brihnka and V. A. Shushunov, Reactions of Organometallic Compounds with Ouygen and Peroxide, CRC Press, Inc., Cleveland, Ohio, 1969, pp. 184-185. [Pg.360]

F. E. Btinckman and G. Gordon, Proceedings of the International Symposium on Decomposition of Organometallic Compounds to Eefractoy Ceramics, Metals, and Metal Alloys, Dayton, Ohio, 1967. [Pg.481]

Reaction of organometallic compounds with enamine salts have been successfully used for the synthesis of some natural products (256). Thus reaction of the immonium salt of 0-alkylated enamino ketone 122 with isobutyllithium affords the compound 169. [Pg.290]

In the case of organometallic compounds the most satisfactory way of classifying the ligands... [Pg.907]

Another such effect is the intervention of cyclic transition states in reactions of organometallic compounds (Section II, B, 5) with azines or in intramolecular nucleophilic substitutions (Section II, F). [Pg.269]

Furan is typically tiVC) coordinated in a series of organometallic compounds. However, it is its ti (C=C) coordination that opened a perspective toward a broad series of derivatized furans. It can be a bridging ligand forming (C=C)... [Pg.50]

Nomenclature of organometallic compounds of the transition elements (lUPAC recommendations) 99PAC1557. [Pg.204]

Carbene transfer reactions with participation of organometallic compounds bearing heterocyclic substituents 99CSR315. [Pg.208]

Grignard reagents are a very important class of organometallic compounds. For their preparation an alkyl halide or aryl halide 5 is reacted with magnesium metal. The formation of the organometallic species takes place at the metal surface by transfer of an electron from magnesium to a halide molecule, an alkyl or aryl radical species 6 respectively is formed. Whether the intermediate radical species stays adsorbed at the metal surface (the A-modelf, or desorbs into solution (the D-model), still is in debate ... [Pg.142]

Many metals occur in crude oils. Some of the more abundant are sodium, calcium, magnesium, aluminium, iron, vanadium, and nickel. They are present either as inorganic salts, such as sodium and magnesium chlorides, or in the form of organometallic compounds, such as those of nickel and vanadium (as in porphyrins). Calcium and magnesium can form salts or soaps with carboxylic acids. These compounds act as emulsifiers, and their presence is undesirable. [Pg.19]

Many other kinds of organometallic compounds can be prepared in a manner similar to that of Grignard reagents. For instance, alkyllithium reagents, RLi, can be prepared by the reaction of an alkyl halide with lithium metal. Alkyllithiums are both nucleophiles and strong bases, and their chemistry is similar in many respects to that of alkylmagnesium halides. [Pg.346]

Additions of organometallic compounds to 2-azelidinones such as 1 or 4 bearing a leaving group in the 4-position preferentially or exclusively afford tram-3,4-substituted /(-lactams 3 or 6. Therefore, the participation of an A -acylinline intermediate such as 2 or 5 which is attacked from the less hindered side is probable14-16. This has been exploited for the synthesis of carbapenem antibiotics, e.g., thienamycin (7)16. [Pg.702]

Addition of Organometallic Compounds to a,/MJnsaturated Carbonyl Compounds... [Pg.891]


See other pages where Of organometallic compounds is mentioned: [Pg.289]    [Pg.100]    [Pg.5]    [Pg.79]    [Pg.79]    [Pg.81]    [Pg.83]    [Pg.85]    [Pg.282]    [Pg.282]    [Pg.360]    [Pg.189]    [Pg.69]    [Pg.416]    [Pg.592]    [Pg.924]    [Pg.924]    [Pg.51]    [Pg.118]    [Pg.209]    [Pg.705]    [Pg.891]    [Pg.893]    [Pg.897]    [Pg.901]   
See also in sourсe #XX -- [ Pg.794 , Pg.798 ]




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13C NMR Chemical Shifts and Coupling Constants of Organometallic Compounds

Acidolysis of organometallic compounds

Acylation of organometallic compounds

Addition Reactions of Organometallic Compounds

Addition of Organometallic Reagents to Carbonyl Compounds

Addition of organometallic compounds

Aryl Migrations in Organometallic Compounds of the Alkali Metals

Boranes, alkoxyreaction with organometallic compounds formation of aldehydes

Boranes, vinylreactions with organometallic compounds via hydroboration of 1-alkynes

CHARACTERIZATION OF ORGANOMETALLIC COMPOUNDS

Carbonyl compounds addition of organometallic

Chapter 7. Organometallic Compounds of the Group I, II, and III Metals

Character of Organometallic Compounds

Characteristics of Cyclometalation Reactions for Organometallic Intramolecular-Coordination Five-Membered Ring Compounds

Classification of organometallic compounds by bond type

Coupling of alkyl halides with organometallic compounds

Cross-coupling of haloalkynes with organometallic compounds

Crotyl organometallic compounds dependence of product type on metal

David J., Organometallic Compounds of the Heavier Alkali Metals

Decomposition reactions of organometallic compounds

Dictionary of Organometallic Compounds

Electrochemical synthesis of organometallic compounds

Electrosynthesis of organometallic compounds

Fast Exchange Reactions of Group I, II, and III Organometallic Compounds

Formation of metal-carbon bonds (organometallic compounds)

Formylation of Organometallic Compounds

Hydrolysis of organometallic compounds

In synthesis of organometallic compounds

Ketone syntheses by means of organometallic compounds

Manganese Organometallics for the Chemoselective Synthesis of Polyfunctional Compounds

Mass Spectra of Organometallic Compounds

Metal Atom Synthesis of Organometallic Compounds

New Methods for the Synthesis of Trifluoromethyl Organometallic Compounds

Nomenclature of organometallic compounds

Nuclear Magnetic Resonance Spectra of Organometallic Compounds

Ordering of central atoms in polynuclear organometallic compounds

Organometallic Complexes as Catalysts in Oxidation of C—H Compounds

Organometallic Compounds of Gold

Organometallic Compounds of Group IA Metals

Organometallic Compounds of Group IIIA Metals

Organometallic Compounds of Group IVA Metals

Organometallic Compounds of Group VA Elements

Organometallic Compounds of Palladium and Platinum

Organometallic Compounds of Pyrrole

Organometallic Compounds of Silver

Organometallic Compounds of Thiophene

Organometallic Compounds of Transition Metals

Organometallic Compounds of Zn, Cd, and Hg

Organometallic Compounds of the Group I, II, and III Metals

Organometallic Compounds of the Main Group Elements

Organometallic Nitrogen Compounds of Germanium, Tin, and Lead

Organometallic compounds effect of bulky substituents on stability

Organometallic compounds meaning of term

Organometallic compounds mode of action

Organometallic compounds of Ga, In and

Organometallic compounds of Ga, In and Tl

Organometallic compounds of Main Group elements

Organometallic compounds of aluminum

Organometallic compounds of chromium

Organometallic compounds of copper

Organometallic compounds of d-block elements

Organometallic compounds of furan

Organometallic compounds of furan thiophene and their benzannulated

Organometallic compounds of group

Organometallic compounds of iron (

Organometallic compounds of lanthanoids

Organometallic compounds of lithium

Organometallic compounds of magnesium, zinc, and cadmium

Organometallic compounds of p-block elements

Organometallic compounds of rare-earth elements

Organometallic compounds of s- and p-block elements

Organometallic compounds of the actinides

Organometallic compounds of tin

Organometallic compounds of transition elements

Organometallic compounds of zinc

Organometallic compounds, of transition

Photoelimination of CO and CO2 from Organometallic Compounds

Preparation and Reactions of Organometallic Compounds

Preparation of Organometallic Compounds

Preparation of metal carbonyls and organometallic compounds

Pyrolysis of organometallic compounds

Radiochemistry of organometallic compounds

Reaction of Organometallic Reagents with Other Compounds

Reactions of organometallic compounds

Reactions of organometallic compounds with metal halides

Reactivity and Reaction Pathways of Organometallic Compounds

Reactivity of Organometallic Compounds with Metallic Surfaces

Redistribution Equilibria of Organometallic Compounds

Schumann and W. Genthe, Organometallic compounds of the rare earths

Simple Addition Reactions of Organometallic Compounds

Spectroscopic Properties of Inorganic and Organometallic Compounds, Volume

Structures of Main Group Organometallic Compounds Containing Electron-Deficient

Structures of Main Group Organometallic Compounds Containing Electron-Deficient Bridge

Structures of Main Group Organometallic Compounds Containing Electron-Deficient Bridge Bonds

Structures of some 7r-organometallic compounds containing allyl groups as ligands

Studies of Organometallic Compounds

The Photochemistry of Transition-metal Organometallic Compounds

The interaction of carbonyl-containing compounds with organometallic reagents

The stability of organometallic compounds

Thermal decomposition of hydrides and organometallic compounds

Thermochemistry and Kinetics of Organometallic Tin Compounds in the

Thioureas in synthesis of heterocycles Transition organometallic compounds

Transmetallation of organometallic compounds

Use of transition organometallic compounds

Use of transition organometallic compounds heterocyclic synthesis

Use of transition organometallic compounds in heterocyclic synthesis

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