Nickel electrical resistivity

In some deposits, notably those of nickel, electrical resistance follows current density at low temperamres in the sense that films deposited at low current density (say, lOniA/cm ) show lower resistance than do those deposited at higher density. Although this is so in the low-temperature range 4 to 40 K, this difference in resistance disappears closer to room temperature. 

Nonferrous alloys account for only about 2 wt % of the total chromium used ia the United States. Nonetheless, some of these appHcations are unique and constitute a vital role for chromium. Eor example, ia high temperature materials, chromium ia amounts of 15—30 wt % confers corrosion and oxidation resistance on the nickel-base and cobalt-base superaHoys used ia jet engines the familiar electrical resistance heating elements are made of Ni-Cr alloy and a variety of Ee-Ni and Ni-based alloys used ia a diverse array of appHcations, especially for nuclear reactors, depend on chromium for oxidation and corrosion resistance. Evaporated, amorphous, thin-film resistors based on Ni-Cr with A1 additions have the advantageous property of a near-2ero temperature coefficient of resistance (58). 

Resistance thermometers are made of a pure metal, such as platinum, nickel, or copper. The electrical resistance of such a material is almost linearly dependent on temperature. Resistance thermometers are stable, having a small drift. A widely used and the best-known resistance probe is the IW-100 probe, which is platinum, having a resistance of 100 ohms at the temperature of 0 °C. Other resistance values for PT probes are available. The resistance versus temperature values as well as tolerances for platinum probes are standardized. The shape and size of a resistance probe can vary considerably, resulting in changes in probe dynamics. 

The non-ferrous alloys include the misleadingly named nickel silver (or German silver) which contains 10-30% Ni, 55-65% Cu and the rest Zn when electroplated with silver (electroplated nickel silver) it is familiar as EPNS tableware. Monel (68% Ni, 32% Cu, traces of Mn and Fe) is used in apparatus for handling corrosive materials such as F2 cupro-nickels (up to 80% Cu) are used for silver coinage Nichrome (60% Ni, 40% Cr), which has a very small temperature coefficient of electrical resistance, and Invar, which has a very small coefficient of expansion are other well-known Ni alloys. Electroplated nickel is an ideal undercoat for electroplated chromium, and smaller amounts of nickel are used as catalysts in the hydrogenation of unsaturated vegetable oils and in storage batteries such as the Ni/Fe batteries. 

Nickel. Ni, at wt 58.71, at no 28, valences +2 +3, five stable isotopes, 7 radioactive isotopes. Malleable, silvery metal readily fabricated by hot and cold working takes high polish excellent resistance to corrosion. Mp 1455° bp 2900° d 8.9Q8g/cc electrical resistivity (20°) 6.844 microhm-cm Moh s hardness 3.8 spec heat (100°) 0.1123 latent heat of fusion 73cal/g. 

Fig. 2. Typical curves of the relative changes of the electrical resistance of nickel films as a function of time (a) adsorption of one dose of hydrogen on the surface, partially covered by preadsorbed oxygen (b) adsorption of one dose of oxygen on the surface, covered by preadsorbed hydrogen (both at 300°K).

Ni-P adhesion, 9 705. See also Nickel phosphorus entries Ni-P alloys, solderability, 9 707, 708 NIPAm hydrogels, 13 738 Ni-P density, 9 705 Ni-P electrical resistivity, 9 706 Ni-P ferromagnetic properties, 9 706 Nipkow disk, 16 484 Ni-P mechanical properties, 9 706 Niranium N/N, base-metal dental alloy, 8 309t... 

Electric detonators are also used for detonation of high explosive charges. They are similar in design to other types of detonators except for the presence of an electric fusehead consisting of a bridgewire made of chromium and nickel. The bridgewire is covered by a heat-sensitive pyrotechnic mixture protected by varnish insulation. Standard fuseheads have electrical resistance of 1.2 to 1.4 ohms and... 

Energy losses in soft magnetic materials arise due to both hysteresis and eddy currents, as described in the previous section. Eddy current losses can be reduced by increasing the electrical resistivity of the magnetic material. This is one reason why solid-solution iron-silicon alloys ( 4% Si) are used at power frequencies of around 60 Hz and why iron-nickel alloys are used at audio frequencies. Some magnetically soft ferrites (see Section 6.2.2.1) are very nearly electrical insulators and are thus immune to eddy current losses. Some common soft magnetic materials and their properties are listed in Table 6.19. Soft magnetic alloys are described further in Section 6.2.1.6. 

Fio. 10. Changes in electrical resistance during the chemisorption of hydrogen on nickel films. [Suhrmann, R., in Chemisorption (W. E. Garner, ed.), p. 106. Academic Press, New York, 1967.]... 

On the other hand, some of Suhrmann s electrical resistance measurements on nickel and platinum films and Eischens observations, of the effect of Hj on the infrared spectrum of chemisorbed CO on platinum, referred to earlier, suggest electron-transfer from hydrogen to the metal, i.e., adsorption of positive ions. 

A large fraction of the iron and steel produced today is recycled scrap. Since scrap does not require reduction, it can be melted down directly in an electric arc furnace, in which the charge is heated through its own electrical resistance to arcs struck from graphite electrodes above it. The main problem with this process is the presence of tramps (i.e., copper from electrical wiring, chromium, nickel, and various other metals) that accompany scrap steel such as crushed automobile bodies and that lead to brittleness in the product. Tin in combination with sulfur is the most troublesome tramp. Only the highest quality recycled steel—specifically, steel with no more than 0.13% tramps—can be used for new automobile bodies, and usually reprocessed scrap has to be mixed with new steel to meet these requirements. 

In carbon monoxide the bond between the atoms depends, as in the N2O molecule, on an asymmetrical electron shift, electrons of the 0 atom moving toward the C atom, and the CO molecule having a dipole character. In this case, too, metal electrons are displaced toward the adsorbed molecule and taken from the electron gas, as shown by the change of the electrical resistance of thin nickel films on carbon monoxide adsorption (18). 

The lone electrons of the 0 atom in the H2O molecule can also become part of the electron gas in the metal surface and reduce its work function. So Schaaff (75) observed an increase of the photoelectric emission of platinum in the presence of water vapor. On the other hand an adsorbed layer of H2O molecules on the surface of a thin nickel film decreases the electric resistance of the film (18). 

A heliarc-welded, all-nickel can of 850-mL volume was filled with an intimate mixture of NiF, (290 g, 3 mol) and anhyd KF (52 g, 9 mol). The can was valved to a tank of F2 gas and a vacuum pump and was heated by an electric-resistance furnace. The can was heated slowly to 500 C under 10 atm of F2 and then cooled to 250 C, while still under several atm of F2. Several such cycles were carried out before using the device for the regeneration of F2. For the regeneration of F2, the salt was fluorinated at 250 C until no more F2 was taken up. The can was then cooled to 225 C and evacuated to remove the excess F2 and any volatile impurities. The temperature was then raised until the desired F, pressure (at 400 C, 25 atm) was achieved. 

It is well known that many important alloy combinations have properties that are not easy to predict, simply on the basis of knowledge of the constituent metals. For example, copper and nickel, both having good electrical conductivity, form solid-solution type alloys having very low conductivity, or high resistivity, making them useful as electrical resistance... 

In addilion to ferrous ulluys, chromium also is added to cupper, vanadium, zirconium, and other metals to form several hundred chromium-bearing alloys. Nickel-chromium-iron alloys have high electrical resistance and are used widely as electrical heating elements. Niclirttme and ChromeI are examples. 

Mixtures of powders of poly(vinyl chloride) (FVC) and various metals were compacted at a pressure of 10,000 psig at 120-130°C. The compacts appear to be strong, and density measurements show the porosity to be <1.5%, Electrical resistivity is reduced, from a value for unloaded FVC of about JO25 Clem, to < JO"1 Clem by a fractional volume loading of nickel or copper as low as 0.06. Microscopic examination of polished sections of the compacts show the metallic particles to be segregated around zones of unpenetrated polymer which correspond in size to the initial particles of FVC. The pattern of segregation favors the formation of continuous chains of metallic particles at unusually low volume loadings. 

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