Neoprene rubber phenolic

Adhesives used to bond acetal homopolymer to itself and to other materials, such as aluminum, steel, natural rubber, neoprene rubber, and Buna rubber, include polyester with isocyanate curing agent, rubber-based adhesives, phenolics, epoxies, modified epoxies, and vinyls. Solvent cementing... 

Cellulose acetate natural rubber (latex), polyisobutylene rubber, neoprene rubber, polyvinyl acetate, ethylene vinyl acetate, polyacrylate (carboxylic), cyanoacrylate, polyamide (versamid), phenoxy, polyester + isocyanate, nitrile-phenolic, polyurethane, and resorcinol-formaldehyde. 

Phenylene oxide-based resins (Noryl ) epoxy, polyisocyanate, polyvinyl butyral, nitrile rubber, neoprene rubber, polyurethane rubber, polyvinyUdene chloride, and acrylic. Polyethylene-nitrile rubber, polyisobutylene rubber, flexible epoxy, nitrile-phenolic, and water-based (emulsion) adhesives. Polystyrene for these foams (expanded polystyrene (EPS)), aromatic solvent adhesives (e.g., toluol) can cause collapse of the foam cell walls. For this reason, it is advisable to use either 100% solids adhesives or water-based adhesives based on SBR or polyvinyl acetate. Specific adhesives recommended include urea-formaldehyde, epoxy, polyester-isocyanate, polyvinyl acetate, vinyl chloride-vinyl acetate copolymer, and reclaim rubber. Polystyrene foam can be bonded satisfactorily with any of the following general adhesive types ... 

PVC epoxy, polyester-isocyanate, unsaturated polyester, vinyl chloride-acetate copolymer, polyvinyl acetate, polyvinyl alkyl ether, ethylene-vinyl acetate, nitrile rubber-phenolic, neoprene rubber, polyisobutylene rubber, polyurethane rubber, and polysulfide rubber. See discussion in Section 6.3.28 concerning migration of plasticizers in PVC. 

Types within group Cellulose acetate, cellulose acetate butyrate, cellulose nitrate, polyvinyl acetate, vinyl vinylidene, polyvinyl acetals, polyvinyl alcohol, polyamide, acrylic, phenoxy Cyanoacrylate, polyester, urea formaldehyde, melamine formaldehyde, resorcinol and phenol-resorcinol formaldehyde, epoxy, polyimide, polybenzimidazole, acrylic, acrylate acid diester Natural rubber, reclaimed rubber, bulyl, polyisobutylene, nitrile, styrene-butadiene, polyurethane, polysulfide, silicone, neoprene Epoxy-phenolic, epoxypolysulfide, epoxy-nylon, nitrile-phenolic, neoprene-phenolic, vinyl-phenolic... 

Neoprene-phenolic adhesives are formulated for room temperature cure and they are used for bonding metal, wood, and many plastics. A combination of neoprene rubber and a / ara-substituted phenolic resin was first described by Thomson. ... 

Adhesives. Contact adhesives are blends of rubber, phenolic resin, and additives supplied in solvent or aqueous dispersion form they are typically applied to both surfaces to be joined (98). Evaporation of the solvent leaves an adhesive film that forms a strong, peel-resistant bond. Contact adhesives are used widely in the furniture and construction industries and also in the automotive and footwear industries. The phenolic resins promote adhesion and act as tackifiers, usually at a concentration of 20-40%. In solvent-based contact adhesives, neoprene is preferred, whereas nitrile is used in specialty applications. The type and grade of phenolic resin selected control tack time, bond strength, and durability. 

Phenolic epoxy, polyester-isocyanate, polyvinyl acetate, vinyl chloride—acetate copolymer, polyvinyl formal-phenolic, nitrile rubber, nitrile rubber-phenolic, reclaim rubber, neoprene rubber, polyurethane rubber, butyl rubber, melamine-formaldehyde, neoprene-phenolic, and polyvinyl formal-phenolic... 

Phenolic-neoprene contact cements are used for structural metal-metal bonding. especially where fatigue resistance and low temperature performance are important [209]. They are also used for bonding textiles, wood, rubbers, plastics, ceramics, and glass to metal and to one another. Solvent toxicity and flammability has greatly reduced the use of contact cements in the wood products industry. Water-based contact cements persist, but generally do not perform as well as the solvent systems, thus allowing market erosion by alternative binders. 

In an acetone extract from a neoprene/SBR hose compound, Lattimer et al. [92] distinguished dioctylph-thalate (m/z 390), di(r-octyl)diphenylamine (m/z 393), 1,3,5-tris(3,5-di-f-butyl-4-hydroxybenzyl)-isocyanurate m/z 783), hydrocarbon oil and a paraffin wax (numerous molecular ions in the m/z range of 200-500) by means of FD-MS. Since cross-linked rubbers are insoluble, more complex extraction procedures must be carried out (Chapter 2). The method of Dinsmore and Smith [257], or a modification thereof, is normally used. Mass spectrometry (and other analytical techniques) is then used to characterise the various rubber fractions. The mass-spectral identification of numerous antioxidants (hindered phenols and aromatic amines, e.g. phenyl-/ -naphthyl-amine, 6-dodecyl-2,2,4-trimethyl-l,2-dihydroquinoline, butylated bisphenol-A, HPPD, poly-TMDQ, di-(t-octyl)diphenylamine) in rubber extracts by means of direct probe EI-MS with programmed heating, has been reported [252]. The main problem reported consisted of the numerous ions arising from hydrocarbon oil in the recipe. In older work, mass spectrometry has been used to qualitatively identify volatile AOs in sheet samples of SBR and rubber-type vulcanisates after extraction of the polymer with acetone [51,246]. 

Elastomers Solutions of NR have been used for laminating textiles for over a century. The Macintosh raincoat, invented in 1825, consisted of two sheets of cotton adhered by an inner layer of natural rubber. SBR is used as an adhesive in carpet backing and packaging. Neoprene (polychloroprene) may be blended with a terpene or phenolic resin and used as a contact adhesive for shoes and furniture. 

Resorcinol is used primarily in the rubber industry for tyres and reinforced rubber products (conveyer belts, driving belts) and in high-quality wood adhesives, which are made from resorcinol, phenol and fonnaldehyde. It is also used in the preparation of dyes and pharmaceuticals, as a cross-linking agent for neoprene and a rubber tackifier, and in cosmetics (Lewis, 1993 Schmiedel Decker, 1993 Krumenacker et al., 1995). 

Chlorinated rubber is also an effective bonding agent. It can be used for bonding neoprene, nitrile and natural rubbers to metals. Phenol formaldehyde resins have been used alone or in conjunction with chlorinated rubbers, but curing time is lengthy. 

The First plastic sabots were made of glass-fiber filled diallylphthalate sheathed in nylon and they included metal reinforcements whenever it was felt necessary to redistribute the stresses. The nylon sheath was necessitated by the abrasive nature of glass-filled materials. Nylon also is used for rotating bands on projectiles and on metal sabots. Other plastics used for the structural portions of sabots include poly propylenes, polycarbonates, celluloses, epoxies and phenolics. Polyethylene, neoprene, and silicone rubbers are used for seals and obturators... 

Polyester Adhesives used include neoprene or nitrile-phenolic, epoxy, epoxy-polyamide, phenolic-epoxies, polyesters, modified acrylics, cyanoacrylates, polyurethanes, butyl rubber, polyisobutylene, neoprene, and polymethylmethacrylate (1). 

Urea-Formaldehyde Adhesives used are epoxies, nitrile-phenolics, phenol-formaldehyde, resorcinol-formaldehyde, furan, polyesters, butadiene-nitrile rubber, neoprene, cyanoacrylate, and phenolic-polyvinyl butyral (1). 

Combination with neoprene results in rubber coatings used for waterproofing concrete and for general-purpose maintenance (15). In these coatings the phenolic resin is complexed with a tetravalent metal oxide such as magnesium or zinc oxide to form a stable infusible compound. This treatment improves the adhesion and hardness of the neoprene. 

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