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Modeling energy balance

In this model, energy balances are set up for the reactor and the separator tube separately, and two equations are obtained. The gas holdup can then be obtained from combining these two equations. Details can be found in Zhang et al. [7]. The comparison between the measured and calculated cross-sectional mean gas holdups is shown in Fig. 5. It can be seen that there is a satisfactory agreement between the experimental and calculated gas holdup in the different operating conditions. Therefore, it is reasonable to conclude that the energy balance model used in this work can describe the circulation flow behavior in the novle internal-loop airlift reactor proposed in this work. [Pg.524]

The RNG model provides its own energy balance, which is based on the energy balance of the standard k-e model with similar changes as for the k and e balances. The RNG k-e model energy balance is defined as a transport equation for enthalpy. There are four contributions to the total change in enthalpy the temperature gradient, the total pressure differential, the internal stress, and the source term, including contributions from reaction, etc. In the traditional turbulent heat transfer model, the Prandtl number is fixed and user-defined the RNG model treats it as a variable dependent on the turbulent viscosity. It was found experimentally that the turbulent Prandtl number is indeed a function of the molecular Prandtl number and the viscosity (Kays, 1994). [Pg.321]

Isothermal cases are modeled energy balances are thus omitted. [Pg.331]

Heat Transfer in Rotary Kilns. Heat transfer in rotary kilns occurs by conduction, convection, and radiation. In a highly simplified model, the treatment of radiation can be explained by applying a one-dimensional furnace approximation (19). The gas is assumed to be in plug flow the absorptivity, a, and emissivity, S, of the gas are assumed equal (a = e ) and the presence of water in the soHds is taken into account. Energy balances are performed on both the gas and soHd streams. Parallel or countercurrent kilns can be specified. [Pg.49]

Distillation Columns. Distillation is by far the most common separation technique in the chemical process industries. Tray and packed columns are employed as strippers, absorbers, and their combinations in a wide range of diverse appHcations. Although the components to be separated and distillation equipment may be different, the mathematical model of the material and energy balances and of the vapor—Hquid equiUbria are similar and equally appHcable to all distillation operations. Computation of multicomponent systems are extremely complex. Computers, right from their eadiest avadabihties, have been used for making plate-to-plate calculations. [Pg.78]

Packed Red Reactors The commonest vessels are cylindrical. They will have gradients of composition and temperature in the radial and axial directions. The partial differential equations of the material and energy balances are summarized in Table 7-10. Example 4 of Modeling of Chemical Reactions in Sec. 23 is an apphcation of such equations. [Pg.702]

A key featui-e of MPC is that a dynamic model of the pi ocess is used to pi-edict futui e values of the contmlled outputs. Thei-e is considei--able flexibihty concei-ning the choice of the dynamic model. Fof example, a physical model based on fifst principles (e.g., mass and energy balances) or an empirical model coiild be selected. Also, the empirical model could be a linear model (e.g., transfer function, step response model, or state space model) or a nonhnear model (e.g., neural net model). However, most industrial applications of MPC have relied on linear empirical models, which may include simple nonlinear transformations of process variables. [Pg.740]

Those based on strictly empirical descriptions Mathematical models based on physical and chemical laws (e.g., mass and energy balances, thermodynamics, chemical reaction kinefics) are frequently employed in optimization apphcations. These models are conceptually attractive because a gener model for any system size can be developed before the system is constructed. On the other hand, an empirical model can be devised that simply correlates input-output data without any physiochemical analysis of the process. For... [Pg.742]

Develop via mathematical expressions a valid process or equipment model that relates the input-output variables of the process and associated coefficients. Include both equality and inequality constraints. Use well-known physical principles (mass balances, energy balances), empirical relations, implicit concepts, and external restrictions. Identify the independent and dependent variables (number of degrees of freedom). [Pg.742]

Material and energy balances of the steady-state model. [Pg.745]

The couphng equation is a vapor mass balance written at the vent system entrance and provides a relationship between the vent rate W and the vent system inlet quahty Xq. The relief system flow models described in the following section provide a second relationship between W and Xo to be solved simultaneously with the coupling equation. Once W andXo are known, the simultaneous solution of the material and energy balances can be accomplished. For all the preceding vessel flow models and the coupling equations, the reader is referred to the DIERS Project Manual for a more complete and detailed review. [Pg.2292]

Parameter Estimation Relational and physical models require adjustable parameters to match the predicted output (e.g., distillate composition, tower profiles, and reactor conversions) to the operating specifications (e.g., distillation material and energy balance) and the unit input, feed compositions, conditions, and flows. The physical-model adjustable parameters bear a loose tie to theory with the limitations discussed in previous sections. The relational models have no tie to theory or the internal equipment processes. The purpose of this interpretation procedure is to develop estimates for these parameters. It is these parameters hnked with the model that provide a mathematical representation of the unit that can be used in fault detection, control, and design. [Pg.2573]

With a three-parameter model of the intermolecular potential, the theoretical spall strength is not simply a constant times the bulk modulus. Although the slightly greater accuracy obtained is not critical to the present investigation, an energy balance is revealed in the analysis which is not immediately transparent in the Orowan approach. [Pg.268]

Case Type Model Mass Balaaccs Energy Balance Chemical Equilibrium Kircrics/Transpor. [Pg.406]

Case Type Model Mass Balances Energy Balance Kinetics/Transpori... [Pg.407]

A model can be defined as a set of relationships between the variables of interest in the system being investigated. A set of relationships may be in the form of equations the variables depend on the use to which the model is applied. Therefore, mathematical equations based on mass and energy balances, transport phenomena, essential metabolic pathway, and physiology of the culture are employed to describe the reaction processes taking place in a bioreactor. These equations form a model that enables reactor outputs to be related to geometrical aspects and operating conditions of the system. [Pg.868]

The room model consists of nodes, which are interconnected by heat exchange paths (Fig. 11.36). The nodes represent either surface temperatures of the individual walls or the zone air temperature. For each node, an energy balance is formulated. From the resulting set of equations, the temperatures and heat fluxes can be determined. [Pg.1070]

The room models implemented in the codes can be distinguished further by how detailed the models of the energy exchange processes are. Simple models use a combined convective-radiative heat exchange. More complex models use separate paths for these effects. Mixed forms also exist. The different models can also be distinguished by how the problem is solved. The energy balance for the zone is calculated in each time step of the simulation. [Pg.1070]

In this section we present the system of quasi-one-dimensional equations, describing the unsteady flow in the heated capillary tube. They are valid for flows with weakly curved meniscus when the ratio of its depth to curvature radius is sufficiently small. The detailed description of a quasi-one-dimensional model of capillary flow with distinct meniscus, as well as the estimation conditions of its application for calculation of thermohydrodynamic characteristics of two-phase flow in a heated capillary are presented in the works by Peles et al. (2000,2001) and Yarin et al. (2002). In this model the set of equations including the mass, momentum and energy balances is ... [Pg.440]

A homogeneous flow basis must be used when thermodynamic equilibrium is assumed. For furtl er simplification it is assumed there will be no reaction occurring in the pipeline. The vapor and liquid contents of the reactor are assumed to be a homogeneous mass as they enter the vent line. The model assumes adiabatic conditions in the vent line and maintains constant stagnation enthalpy for the energy balance. [Pg.332]

In gridpoint models, transport processes such as speed and direction of wind and ocean currents, and turbulent diffusivities (see Section 4.8.1) normally have to be prescribed. Information on these physical quantities may come from observations or from other (dynamic) models, which calculate the flow patterns from basic hydrodynamic equations. Tracer transport models, in which the transport processes are prescribed in this way, are often referred to as off-line models. An on-line model, on the other hand, is one where the tracers have been incorporated directly into a d3mamic model such that the tracer concentrations and the motions are calculated simultaneously. A major advantage of an on-line model is that feedbacks of the tracer on the energy balance can be described... [Pg.75]


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