Transports equations

The motion of particles in a fluid is best approached tlirough tire Boltzmaim transport equation, provided that the combination of internal and external perturbations does not substantially disturb the equilibrium. In otlier words, our starting point will be the statistical themiodynamic treatment above, and we will consider the effect of botli the internal and external fields. Let the chemical species in our fluid be distinguished by the Greek subscripts a,(3,.. . and let f (r, c,f)AV A be the number of molecules of type a located m... 

Finally, all of the F-tenns can be inserted in (A3,1,31). and dividing by St5r5v gives the Boltzmaim transport equation... 

This completes the heuristic derivation of the Boltzmann transport equation. Now we trim to Boltzmaim s argument that his equation implies the Clausius fonn of the second law of thennodynamics, namely, that the entropy of an isolated system will increase as the result of any irreversible process taking place in the system. This result is referred to as Boltzmann s H-theorem. 

These models are usually categorized according to the number of supplementary partial differential transport equations which must be solved to supply the modeling parameters. The so-called zero-equation models do not use any differential equation to describe the turbulent quantities. The best known example is the Prandtl (19) mixing length hypothesis ... 

One-equation models relax the assumption that production and dissipation of turbulence are equal at all points of the flow field. Some effects of the upstream turbulence are incorporated by introducing a transport equation for the turbulence kinetic energy k (20) given by... 

Using this simplified model, CP simulations can be performed easily as a function of solution and such operating variables as pressure, temperature, and flow rate, usiag software packages such as Mathcad. Solution of the CP equation (eq. 8) along with the solution—diffusion transport equations (eqs. 5 and 6) allow the prediction of CP, rejection, and permeate flux as a function of the Reynolds number, Ke. To faciUtate these calculations, the foUowiag data and correlations can be used (/) for mass-transfer correlation, the Sherwood number, Sb, is defined as Sh = 0.04 S c , where Sc is the Schmidt... 

The generalized transport equation, equation 17, can be dissected into terms describing bulk flow (term 2), turbulent diffusion (term 3) and other processes, eg, sources or chemical reactions (term 4), each having an impact on the time evolution of the transported property. In many systems, such as urban smog, the processes have very different time scales and can be viewed as being relatively independent over a short time period, allowing the equation to be "spht" into separate operators. This greatly shortens solution times (74). The solution sequence is... 

Dialysis transport relations need not start with Eickian diffusion they may also be derived by integration of the basic transport equation (7) or from the phenomenological relationships of irreversible thermodynamics (8,9). 

In modeling an RO unit, two aspects should be considered membrane transport equations and hydrodynamic modeling of the RO module. The membrane transport equations represent the phenomena (water permeation, solute flux, etc.) taking place at the membrane surface. On the other hand, the hydrodynamic model deals with the macroscopic transport of the various species along with the momentum and energy associated with them. In recent years, a number of mathematical... 

In addition to material balance, two transport equations can be used to predict the flux of water and solute. For instance, the following simplified model can be used (Dandavati etai, 1975 Evangelista, 1986). 

C) and Cgm denote the mean concentration in the occupied zone, concentration at a given point P, the mean concentration in the room, and the concentration at the outlet, respectively. To numerically simulate these parameters, the velocity field is first computed. Then a contaminant source is introduced at a cell (or cells) of a region to be studied, and the transport equation for contaminant C is solved. The transport equation for C is... 

The governing equations for mass flow, energy flow, and contaminant flow in a room will be the continuity equation, Navier-Stokes equations (one in each coordinate direction), the energy equation, and the mass transport equation, respectively. 

The mass transport equation for gas in air (binary mixture) has a similar structure ... 

Equation (12.43) is called an Eulerian approach because the behavior of the species is described relative to a fixed coordinate system. The equation can also be considered to be a transport equation for particles when they are... 

Using turbulenee models, this new system of equations ean be elosed. The most widely used turbulenee model is the k-e model, whieh is based on an analogy of viseous and Reynolds stresses. Two additional transport equations for the turbulent kinetie energy k and the turbulent energy dissipation e deseribe the influenee of turbulenee... 

More advanced models, for example the algebraic stress model (ASM) and the Reynolds stress model (RSM), are not based on the eddy-viscosity concept and can thus account for anisotropic turbulence thereby giving still better predictions of flows. In addition to the transport equations, however, the algebraic equations for the Reynolds stress tensor also have to be solved. These models are therefore computationally far more complex than simple closure models (Kuipers and van Swaaij, 1997). 

General solution of the population balance is complex and normally requires numerical methods. Using the moment transformation of the population balance, however, it is possible to reduce the dimensionality of the population balance to that of the transport equations. It should also be noted, however, that although the mathematical effort to solve the population balance may therefore decrease considerably by use of a moment transformation, it always leads to a loss of information about the distribution of the variables with the particle size or any other internal co-ordinate. Full crystal size distribution (CSD) information can be recovered by numerical inversion of the leading moments (Pope, 1979 Randolph and Larson, 1988), but often just mean values suffice. 

Consider a thin layer solid bowl centrifuge as shown in Figure 4.20. In this device, particles are flung to the wall of the vessel by centrifugal force while liquor either remains stationary in batch operation or overflows a weir in continuous operation. Separation of solid from liquid will be a function of several quantities including particle and fluid densities, particle size, flowrate of slurry, and machine size and design (speed, diameter, separation distance, etc.). A relationship between them can be derived using the transport equations that were derived in Chapter 3, as follows. 

Figure 4.20 Thin layer sedimenting centrifuge Transport equations...

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