Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Methyl methacrylate, manufacture

The outstanding chemical property of cyanohydrins is the ready conversion to a-hydroxy acids and derivatives, especially a-amino and a,P-unsaturated acids. Because cyanohydrins are primarily used as chemical intermediates, data on production and prices are not usually pubUshed. The industrial significance of cyanohydrins is waning as more direct and efficient routes to the desired products are developed. Acetone cyanohydrin is the world s most prominent industrial cyanohydrin because it offers the main route to methyl methacrylate manufacture. [Pg.410]

One of the most important appHcations of this process is that of methyl methacrylate manufacture. In this process (81), acetone cyanohydrin is treated with sulfuric acid at 100°C, affording the corresponding methacrylamide sulfate which is esterified with methanol. After purification, methyl methacrylate (99.8% purity) is obtained in a yield of ca 85%. [Pg.381]

The environmental benefit of this route is evident when compared to the traditional methyl methacrylate manufacturing process, which uses hazardous hydrogen cyanide and produces stoichiometric amounts of ammonium hydrogen sulfate waste. [Pg.112]

Mitral valve repair, 3 717 Mitsubishi Gas Chemical Company process, for methyl methacrylate manufacture, 16 245, 248-250 Mitsubishi Kasei one-step MIBK process, 16 339... [Pg.591]

FIGURE 3-44 Lucite poly(methyl methacrylate)] manufacture at DuPont circa 1940s (reproduced with the kind permission of the Hagley Museum and Library),... [Pg.80]

The U.S. and European production figures for acetone are approximately M and 0-5 Mt per annum respectively. The largest single chemical use (approx. 30%) is in methyl methacrylate manufacture. Of the aldol derivatives, methyl isobutyl ketone (MIBK) (4-methylpentan-2-one) takes some 10-15%, but several others, such as diacetone alcohol and isophorone, have individual sales of 10 to 25 kt per annum (for brake fluids, speciality solvents, etc.). [Pg.383]

Perspex Poly(methyl methacrylate). Manufactured by ICI, Great Britain. [Pg.709]

Manufacture of Monomers. The various commercial processes for the manufacture of methyl methacrylate have been reviewed (31) (see... [Pg.263]

Bulk Polymerization. This is the method of choice for the manufacture of poly(methyl methacrylate) sheets, rods, and tubes, and molding and extmsion compounds. In methyl methacrylate bulk polymerization, an auto acceleration is observed beginning at 20—50% conversion. At this point, there is also a corresponding increase in the molecular weight of the polymer formed. This acceleration, which continues up to high conversion, is known as the Trommsdorff effect, and is attributed to the increase in viscosity of the mixture to such an extent that the diffusion rate, and therefore the termination reaction of the growing radicals, is reduced. This reduced termination rate ultimately results in a polymerization rate that is limited only by the diffusion rate of the monomer. Detailed kinetic data on the bulk polymerization of methyl methacrylate can be found in Reference 42. [Pg.265]

Fig. 2. Continuous process for manufacturing poly(methyl methacrylate) plastic sheet. Fig. 2. Continuous process for manufacturing poly(methyl methacrylate) plastic sheet.
Plastic Sheet. Poly(methyl methacrylate) plastic sheet is manufactured in a wide variety of types, including cleat and colored transparent, cleat and colored translucent, and colored semiopaque. Various surface textures ate also produced. Additionally, grades with improved weatherabiUty (added uv absorbers), mat resistance, crazing resistance, impact resistance, and flame resistance ate available. Selected physical properties of poly(methyl methacrylate) sheet ate Hsted in Table 12 (102). [Pg.269]

Optics. Good optical properties and low thermal resistance make poly(methyl methacrylate) polymers well suited for use as plastic optical fibers. The manufacturing methods and optical properties of the fibers have been reviewed (124) (see Fiber optics). Methods for the preparation of Fresnel lenses and a Fresnel lens film have been reported (125,126). Compositions and methods for the industrial production of cast plastic eyeglass lenses are available (127). [Pg.271]

Process Raw Material. Industrial solvents are raw materials in some production processes. Eor example, only a small proportion of acetone is used as a solvent, most is used in producing methyl methacrylate and bisphenol A. Alcohols are used in the manufacture of esters and glycol ethers. Diethylenetriamine is also used in the manufacture of curing agents for epoxy resins. Traditionally, chlorinated hydrocarbon solvents have been the starting materials for duorinated hydrocarbon production. [Pg.280]

The acetone supply is strongly influenced by the production of phenol, and so the small difference between total demand and the acetone suppHed by the cumene oxidation process is made up from other sources. The largest use for acetone is in solvents although increasing amounts ate used to make bisphenol A [80-05-7] and methyl methacrylate [80-62-6]. a-Methylstyrene [98-83-9] is produced in controlled quantities from the cleavage of cumene hydroperoxide, or it can be made directly by the dehydrogenation of cumene. About 2% of the cumene produced in 1987 went to a-methylstyrene manufacture for use in poly (a-methylstyrene) and as an ingredient that imparts heat-resistant quaUties to polystyrene plastics. [Pg.364]

Cyanohydrins are used primarily as intermediates in the production of other chemicals. Manufacture of methyl methacrylate, used to make acrylic mol ding resins and clear sheet, eg, Plexiglas acrylic sheet, from acetone cyanohydrin is the most economically important cyanohydrin process (see Methacrylic polymers). Cyanohydrins are also used as solvents in appHcations including fiber-spinning and metals refining. Cyanohydrins and derivatives reportedly act as antiknock agents in fuel oil and motor fuels and serve as electrolytes in electrolytic capacitors. [Pg.413]

Acetone Cyanohydrin. This cyanohydrin, also known as a-hydroxyisobutyronitnle and 2-methyUactonitrile [75-86-5], is very soluble in water, diethyl ether, and alcohol, but only slightly soluble in carbon disulfide or petroleum ether. Acetone cyanohydrin is the most important commercial cyanohydrin as it offers the principal commercial route to methacrylic acid and its derivatives, mainly methyl methacrylate [80-62-6] (see Methacrylic acid AND derivatives). The principal U.S. manufacturers are Rohm and Haas Co., Du Pont, CyRo Industries, and BP Chemicals. Production of acetone cyanohydrin in 1989 was 582,000 metric tons (30). [Pg.413]

Pure polymeric acrylonitrile is not an interesting fiber and it is virtually undyeable. In order to make fibers of commercial iaterest acrylonitrile is copolymerized with other monomers such as methacrylic acid, methyl methacrylate, vinyl compounds, etc, to improve mechanical, stmctural, and dyeing properties. Eibers based on at least 85% of acrylonitrile monomer are termed acryHc fibers those containing between 35—85% acrylonitrile monomer, modacryhc fibers. The two types are in general dyed the same, although the type and number of dye sites generated by the fiber manufacturing process have an influence (see Eibers, acrylic). [Pg.362]

During this period, the ICI laboratories were also making their other great contribution to the range of plastics materials—the product which they marketed as Perspex, poly(methyl methacrylate). As a result of work by two of their chemists, R. Hill and J. W. C. Crawford, it was found that a rigid transparent thermoplastics material could be produced at a commercially feasible cost. The material became invaluable during World War II for aircraft glazing and to a lesser extent in the manufacture of dentures. Today poly(methyl methacrylate) is... [Pg.6]


See other pages where Methyl methacrylate, manufacture is mentioned: [Pg.584]    [Pg.331]    [Pg.331]    [Pg.417]    [Pg.528]    [Pg.584]    [Pg.331]    [Pg.331]    [Pg.417]    [Pg.528]    [Pg.329]    [Pg.217]    [Pg.92]    [Pg.182]    [Pg.72]    [Pg.242]    [Pg.249]    [Pg.251]    [Pg.261]    [Pg.265]    [Pg.265]    [Pg.265]    [Pg.373]    [Pg.18]    [Pg.376]    [Pg.422]    [Pg.396]    [Pg.411]   
See also in sourсe #XX -- [ Pg.9 ]




SEARCH



Manufacturing methyl methacrylate

Manufacturing methyl methacrylate

Methyl methacrylate

Photograph of decomposition furnace methyl methacrylate manufacture

© 2024 chempedia.info