Material properties composition

The characteristic features of a cord—mbber composite have produced the netting theory (67—70), the cord—iaextensible theory (71—80), the classical lamination theory, and the three-dimensional theory (67,81—83). From stmctural considerations, the fundamental element of cord—mbber composite is unidirectionaHy reinforced cord—mbber lamina as shown in Figure 5. From the principles of micromechanics and orthotropic elasticity laws, engineering constants of tire T cord composites in terms of constitutive material properties have been expressed (72—79,84). The most commonly used Halpin-Tsai equations (75,76) for cord—mbber single-ply lamina L, are expressed in equation 5 ... 

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Poly(ethyl methacrylate) (PEMA) yields truly compatible blends with poly(vinyl acetate) up to 20% PEMA concentration (133). Synergistic improvement in material properties was observed. Poly(ethylene oxide) forms compatible homogeneous blends with poly(vinyl acetate) (134). The T of the blends and the crystaUizabiUty of the PEO depend on the composition. The miscibility window of poly(vinyl acetate) and its copolymers with alkyl acrylates can be broadened through the incorporation of acryUc acid as a third component (135). A description of compatible and incompatible blends of poly(vinyl acetate) and other copolymers has been compiled (136). Blends of poly(vinyl acetate) copolymers with urethanes can provide improved heat resistance to the product providing reduced creep rates in adhesives used for vinyl laminating (137). 

Variations in measurable properties existing in the bulk material being sampled are the underlying basis for samphng theory. For samples that correctly lead to valid analysis results (of chemical composition, ash, or moisture as examples), a fundamental theoiy of sampling is applied. The fundamental theoiy as developed by Gy (see references) employs descriptive terms reflecting material properties to calculate a minimum quantity to achieve specified sampling error. Estimates of minimum quantity assumes completely mixed material. Each quantity of equal mass withdrawn provides equivalent representation of the bulk. 

Burchell, T.D., and Oku, T., Material properties data for fusion reactor plasma facing carbon-carbon composites. Nuclear Fusion, 1994, 5(Suppl.), 77 128. 

Environmental composition is one of the most critical factors to consider. It is necessary to simulate as closely as possible all constituents of the service environment in their proper concentrations. Sufficient amounts of corrosive media, as well as contact time, must be provided for test samples to obtain information representative of material properties degradation. If an insufficient volume of corrosive media is exposed to the construction material, corrosion will subside prematurely. 

The values in Figures 2-11 and 2-12 are not entirely typical of all composite materials. For example, follow the hints in Exercise 2.6.7 to demonstrate that E can actually exceed both E., and E2 for some orthotropic laminae. Similarly, E, can be shown to be smaller than both E. and E2 (note that for boron-epoxy in Figure 2-12 E, is slightly smaller than E2 in the neighborhood of 6 = 60°). These results were summarized by Jones [2-6] as a simple theorem the extremum (largest and smallest) material properties do not necessarily occur in principal material coordinates. The moduli Gxy xy xyx exhibit similar peculiarities within the scope of Equation (2.97). Nothing should, therefore, be taken for granted with a new composite material its moduli as a function of 6 must be examined to truly understand its character. 

Stephen W. Tsai and Nicholas J. Pagano, Invariant Properties of Composite Materials, in Composite Materials Workshop, S. W. Tsai, J. C. Haipin, and Nicholas J. Pagano (Editors), St. Louis, Missouri, 13-21 July 1967, Technomic, Westport, Connecticut, 1968, pp. 233-253. Also AFML-TR-67-349, March 1968. 

Predicted results for E2 are plotted in Figure 3-10 for three values of the fiber-to-matrix-modulus ratio. Note that if Vj = 1, the modulus predicted is that of the fibers. However, recognize that a perfect bond between fibers is then implied if a tensile <32 is applied. No such bond is implied if a compressive 02 is applied. Observe also that more than 50% by volume of fibers is required to raise the transverse modulus E2 to twice the matrix modulus even if E, = 10 x E ,l That is, the fibers do not contribute much to the transverse modulus unless the percentage of fibers is impractically high. Thus, the composite material property E2 is matrix-dominated. 

The term r Vf in Equation (3.71) can be interpreted as a reduced fiber-volume fraction. The word reduced is used because q 1. Moreover, it is apparent from Equation (3.72) that r is affected by the constituent material properties as well as by the reinforcement geometry factor To further assist in gaining appreciation of the Halpin-Tsai equations, the basic equation. Equation (3.71), is plotted in Figure 3-39 as a function of qV,. Curves with intermediate values of can be quickly generated. Note that all curves approach infinity as qVf approaches one. Obviously, practical values of qV, are less than about. 6, but most curves are shown in Figure 3-39 for values up to about. 9. Such master curves for various vaiues of can be used in design of composite materiais. 

Consider a dispersion-stiffened composite material. Determine the Influence on the upper bound for the apparent Young s modulus of different Poisson s ratios in the matrix and In the dispersed material. Consider the following three combinations of material properties of the constituent materials ... 

The constituent material properties are substituted in Equations (3.61) and (3.57) to obtain the upper bound on E of the composite material and in Equation (3.47) to obtain the lower bound on E. In addition, the mechanics of materials approach studied in Problems 3.2.1 through... 

The existence of interlaminar stresses means that laminated composite materials can delaminate near free edges whether they be at the edge of a plate, around a hole, or at the ends of a tubular configuration used to obtain material properties. In all cases, delamination could cause premature failure so must be considered in specimen design because othen/vise the specimen does not represent the true physical situation. 

As a starting point, the book reviews the general properties of the raw materials. This is followed by the different techniques used to convert these raw materials to the intermediates, which are further reacted to produce the petrochemicals. The first chapter deals with the composition and the treatment techniques of natural gas. It also reviews the properties, composition, and classification of various crude oils. Properties of some naturally occurring carbonaceous substances such as coal and tar sand are briefly noted at the end of the chapter. These materials are targeted as future energy and chemical sources when oil and natural gas are depleted. Chapter 2 summarizes the important properties of hydrocarbon intermediates and petroleum fractions obtained from natural gas and crude oils. 

The availability of high-intensity, tunable X-rays produced by synchrotron radiation has resulted in the development of new techniques to study both bulk and surface materials properties. XAS methods have been applied both in situ and ex situ to determine electronic and structural characteristics of electrodes and electrode materials [58, 59], XAS combined with electron-yield techniques can be used to distinguish between surface and bulk properties, In the latter procedure X-rays are used to produce high energy Auger electrons [60] which, because of their limited escape depth ( 150-200 A), can provide information regarding near surface composition. 

Isotropic material In an isotropic material the properties at a given point are the same, independent of the direction in which they are measured (Fig. 3-19). The term isotropic means uniform. As one moves from point-to-point in this type of homogeneous plastic the material s composition remains constant. Also, the smallest samples of material... 

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