Lubricating oils, manufacture

Two-Stage Crude Distillation (Atmospheric and Vacuum) The vacuum stage can be used alternately to produce heavy gas oil for catalytic cracking feed or raw lube distillate cuts for lubricating oil manufacture. 

Lubricating Oil Manufacture This consists of solvent deasphalting, phenol treating, and solvent dewaxing. In dewaxing, waxy lube is diluted with a solvent such as propane or methyl ethyl ketone (MEK), and cooled to crystallize the wax which is then removed by filtration. 

The source of paraffin wax is the lighter lubricating oil fractions after distillation from the crudes. The wax content of these is commonly 10 zfc 5% (103). These oils set to gels due to crystallization of the wax and therefore wax removal is a necessity for lubricating-oil manufacture. Wax is a true by-product, yet one of such great value that at times it is prepared as a primary product and the oils are cracked. 

A cluster of prostate cancer deaths was reported among a group of oil refinery workers. These workers used a mixture of chemicals to remove wax from crude oil in a lubricating oil manufacturing processJ5 The chemicals used included... 

Use Waterproofing agent, thickener for lubricating oils, manufacture of solidified oils. Available only as technical grade. 

A hydrocarbon and lubricating oil manufacturing company, located in the center of Calcutta city was emitting noxious fumes into the atmosphere causing burning of eyes, conjunctivitis and eczema-like illnesses among the local residents. The company produced light liquid paraffin, white oil and sodium sulfonate [9]. 

Furfural Process. The use of furfural for lubricating-oil manufacture has been gaining in comparison with most other solvents. The yield of high Viscosity Index raffinate varies with the stocks being treated but is about 70 per cent for intermediate-base stocks and 95 per cent for par-... 

C4H8O, CH3COCH2CH3. Colourless liquid with a pleasant odour, b.p. 80°C. It occurs with propanone in the products of the destructive distillation of wood. Manufactured by the liquid or vapour phase dehydrogenation of 2-butanol over a catalyst. Used as a solvent, particularly for vinyl and acrylic resins, and for nitrocellulose and cellulose acetate, also for the dewaxing of lubricating oils. U.S. production 1978 300 000 tonnes. 

The low molecular weight materials produced by this process are used as lubricants, whereas the high molecular weight materials, the polyisobutylenes, are used as VI improvers and thickeners. Polybutenes that are used as lubricating oils have viscosity indexes of 70—110, fair lubricating properties, and can be manufactured to have excellent dielectric properties. Above their decomposition temperature (ca 288°C) the products decompose completely to gaseous materials. 

Lubricating oils are also used in industrial and process appHcations such as hydrauhc and turbine oils, machine oil and grease, marine and railroad diesel, and metalworking oils. Process oils are used in the manufacture of mbber, textiles, leather, and electrical goods. The distribution of lube oils used in these apphcations in 1992 is as follows automotive, 45711 industrial, 2229 t and process, 1070 t (- SIS, 000 gal) (11). 

MEK is also used iu solvent-based adhesives, iu printing ink formulations, as a solvent iu magnetic tape manufacture, and is the most common solvent used iu dewaxing lubricating oils. Of all these appHcations only an increasing consumption of magnetic tapes is likely to grow ia methyl ethyl ketone use. 

Although synthetic lubrication oil production amounts to only about 2% of the total market, volume has been increasing rapidly (67). Growth rates of the order of 20% per year for poly( a-olefin)s, 10% for polybutenes, and 8% for esters (28) reflect increasing automotive use and these increases would accelerate if synthetics were adopted for factory fill of engines by automotive manufacturers. The estimated production of poly( a-olefin)s for lubricants appears to be approximately 100,000 m /yr, esters 75,000, poly(alkylene glycol)s 42,000, polybutenes 38,000, phosphates 20,000, and dialkyl benzene 18,000 (28,67). The higher costs reflected in Table 18 (18,28) have restricted the volume of siUcones, chlorotrifluoroethylene, perfluoroalkylpolyethers, and polyphenyl ethers. 

Higher a-olefins can also be polymerized with cationic initiators to fiquid oligomeric materials with isomerized stmctures. These fiquids are manufactured commercially and used as lubricating oils. 

Uses. Phosphoms(V) sulfide is used in the manufacture of lubricating oil additives, insecticides, ore flotation agents, and specialty chemicals. Phosphoms sesquisulfide, P4S2, has been used extensively in the manufacture of stnkeanywhere matches (qv). In addition, small quantities are used in fireworks (see Pyrotechnics). 

Oil whose characteristics have changed since original manufacture and which is suitable for recycling. This is an umbrella category that includes used lubricating oils of all types as well as dirty or contaminated fuel or other oils that can be economically recycled. 

Orifice. Orifice viscometers, also called efflux or cup viscometers, are commonly used to measure and control flow properties in the manufacture, processing, and appHcation of inks, paints, adhesives, and lubricating oils. Their design answered the need for simple, easy-to-operate viscometers in areas where precision and accuracy are not particularly important. In these situations knowledge of a tme viscosity is uimecessary, and the efflux time of a fixed volume of Hquid is a sufficient indication of the fluidity of the material. Examples of orifice viscometers include the Ford, Zahn, and Shell cups used for paints and inks and the Saybolt Universal and Furol instmments used for oils (Table 5). 

The principal commercial uses of sulfur monochloride are in the manufacture of lubricant additives and vulcanising agents for mbber (147,154,155) (see Lubrication AND lubricants Rubber chemicals). The preparation of additives for wear and load-bearing improvement of lubricating oils is generally carried out in two steps and the technology is described in numerous patents (155) (see Sulfurization and sulfchlorination). 

There is a wide range of conversion levels. The term maximum conversion type has no precise definition but is often used to describe a level of conversion, where there is no net fuel oil manufactured. A fuel products refinery with specialities may manufacture lubricating oils, asphalts, greases, solvents, waxes and chemical feed stocks in addition to the primary fuel products. The number and diversity of products will naturally vary from one refinery to another. Refineries produce chemical feed stocks for sale to the chemical affiliates and do not have responsibility for the manufacture of chemical products directly. Both operations may be carried out at the same physical location but the corporate product responsibilities are usually separate. 

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