Line methods

With line methods, the spin density along one line of n voxels in the object is interrogated simultaneously (Fig. 5.0.1 (b)) [Manl ]. Thus the sensitivity improves by a factor of n compared to point methods. 

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At the end of the project life a residual unrecovered asset value will remain. This is usually accepted in full as a capital allowance in the final year of the project. Hence the total asset value is fully recovered over the life of the field, but at a slower rate than in the straight line method. 

On-Hne Procedures The growing trend toward automation in industry has resiilted in many studies of rapid procedures for generating size information so that feedback loops can be instituted as an integral part of a process. Many of these techniques are modifications of more traditional methods. The problems associated with on-line methods include allocation and preparation of a representative sample analysis of the sample evaluation of the results. The interface between the measuring apparatus and the process has the potential of high complexity, and consequently, high costs [Leschonsld, Paiticle Cha racterization, 1, 1 (July 1984)]. 

Manipulations involving materials sensitive to air or water vapour can be carried out by these procedures. Vacuum-line methods make use of quantitative transfers, and P(pressure)-V(volume)-T(temperature) measurements, of gases, and trap-to-trap separations of volatile substances. 

Fixed capital investments are characterized by the fact that they have to be replaced after a number of years commonly referred to as service life or useful life period. This replacement is not necessarily due to wear and tear of equipment. Other factors include technological advances that may render the equipment obsolete. Furthermore, over the usefiil life of the equipment, the plant should plan to recover the capital cost expenditure. In this regard, the notion of depreciation is useful. Depreciation or amortization is an annual allowance which is set aside to account for the wear, tear, and obsolescence of a process such that by the end of the useful life of the process, enough fund is accumulated to replace the process. The simplest method for determining depreciation is referred to as the straight line method in which... 

Coupled liquid chromatography-gas chromatography is an excellent on-line method for sample enrichment and sample clean-up. Recently, many authors have reviewed in some detail the various LC-GC transfer methods that are now available (1, 43-52). For the analysis of normal phase eluents, the main transfer technique used is, without doubt, concurrent eluent evaporation employing a loop-type interface. The main disadvantage of this technique is co-evaporation of the solute with the solvent. 

Although SFE and SFC share several common features, including the use of a superaitical fluid as the solvent and similar instrumentation, their goals are quite distinct. While SFE is used mainly for the sample preparation step (extraction), SFC is employed to isolate (chr-omatography) individual compounds present in complex samples (11 -15). Both techniques can be used in two different approaches off-line, in which the analytes and the solvent are either vented after analysis (SFC) or collected (SFE), or on-line coupled with a second technique, thus providing a multidimensional approach. Off-line methods are slow and susceptible to solute losses and contamination the on-line coupled system makes possible a deaease in the detection limits, with an improvement in quantification, while the use of valves for automation results in faster and more reproducible analyses (16). The off-line... 

Methods developed for on-line technological control have to be tested for the variation of the product composition due to process variations. However, if rugged analytical procedures are developed these multidimensional methods may only require minimal attention during on-line operation. Multidimensional chromatography for the analysis of complex polymer and industrial samples offers chromatogra-phers high productivity and efficiency and is an excellent alternative to off-line methods. 

Statistical process control (SPC) is an important on-line method in real time by which a production process can be monitored and control plans can be initiated to keep quality standards within acceptable limits. Statistical quality control (SQC) provides off-line analysis of the big picture such as what was the impact of previous improvements. It is important to understand how SPC and SQC operate. 

Fig. la-c. Theoretical 2H NMR line shapes for axially symmetric FGT (r = 0) in rigid solids, cf. Equ. (1). a Line shapes for the two NMR transitions b 2H spectrum (Pake diagram) in absorption mode as obtained by Fourier transform methods c 2H spectrum in derivative mode as obtained by wide line methods... 

By incorporating the entire analytical scheme (enzyme reaction and electrochemical detection) into the flow system a great improvement in precision can be realized. Sample manipulation is minimized because only a single injection into the flow system is required versus sampling of aliquots for the off-line method. Precision is also improved because the timing of the enzyme reaction and detection are much better controlled in the flow system. Finally, less of both enzyme and sample are needed with on-line enzyme reactor methods. 

Successful combination of a chromatographic procedure for separating and isolating additive components with an on-line method for obtaining the IR spectrum enables detailed compositional and structural information to be obtained in a relatively short time frame, as shown in the case of additives in PP [501], and of a plasticiser (DEHP) and an aromatic phenyl phosphate flame retardant in a PVC fabric [502], RPLC-TSP-FTIR with diffuse reflectance detection has been used for dye analysis [512], The HPLC-separated components were deposited as a series of concentrated spots on a moving tape. HPLC-TSP-FTIR has analysed polystyrene samples [513,514], The LC Transform has also been employed for the identification of a stain in carpet yarn [515] and a contaminant in a multiwire cable [516], HPLC-FTIR can be used to maintain consistency of raw materials or to characterise a performance difference. 

Many traditional laboratory/off-line methods are now moving in the direction of in-process applications. Online GC had already been introduced in the 1950s. Using chip- and microsystem technology, xGC is now being introduced, which achieves analysis times of 30 seconds and is therefore suitable for quality control. SPME-p,GC is potentially useful for process analysis. 

What must be the selling price if the return on the investment before taxes of the fully operating plant is to be 30% Assume that the plant is to be fully depreciated in 12 years using a straight-line method. 

For Example 11-1 compute the depreciation rate per year. Assume the plant will last 11 years. Use the straight-line method of depreciation. 

If, however, in the fourth year the straight-line depreciation method had been adopted, the full plant could be depreciated by the end of 6 years. At the beginning of the fourth year the book value was 1,778,000 and there were 3 years of expected life remaining. By the straight-line method this would mean the plant should be depreciated 593,000 in each of the last 3 years. 

But earnings are not the only consideration. In 1968 the Union Carbide Corporation, along with many other companies, had a very bad year financially. In order to make its financial picture look better it switched from the double declining balance method of depreciation to the straight-line method. This reduced expenses (deprecitation being considered an expense) and hence increased profits. This is a semipermanent move, however, since a return to the double declining balance method would require approval of the Internal Revenue Service. 

Progress in the Study of Methanol Oxidation by In Situ, Ex Situ and On-Line Methods... 

The mechanism of the cocatalytic effect is still a matter of investigation. For most of the systems of interest in electrocatalysis, data for characterization of the surface by means of spectroscopic UHV methods are still missing. Also measurements of changes in the electronic properties of the metal in the presence of adatoms in addition to more intensive application of in situ and on-line methods are desirable for a systematic search of new catalytic materials. 

Comparing on-line and off-line methods of column switching, which of the following advantages and limitations do you think would apply to the on-line technique ... 

On-line techniques are easily automated, but are more expensive as they require additional valves with associated switching equipment. Off-line methods are rather easier to carry out, but, because of the sample collection and re-injection steps, they are slower and tend... 

Although the library of catalysts was actually very small, this combinatorial approach was shown to work surprisingly well. It remains to be seen if truly high throughput can be put into practice, which would require on-line methods for the detection and characterization of the particles bearing the polymers. 

Warnken et al. [956] have reported an online preconcentration - ultrasonic nebulisation - ICP-MS method that achieved detection limits of 0.26,0.86,1.5, 10, and 0.44 ng/1 for manganese, nickel, copper, zinc, and lead in seawater. This online preconcentration method compares favourably to the state of-the-art off-line methods. 

Fig. 13.2. Results of the reaction path shown in Figure 13.1, plotted to allow the overall reaction to be extracted using the slopes-of-the-lines method.

We can write the overall reaction by which hematite forms, using the slopes-of-the-lines method discussed in Chapter 13. Initially, the reaction proceeds as,... 

We can readily derive the overall reactions in the buffer from Figure 15.3 using the slopes-of-the-lines method, described in Chapter 13. In the first stage, the overall reaction is,... 

Fig. 15.3. Species masses in the Na2C()3 solution plotted so that the overall reaction can be determined using the slopes-of-the-lines method.

The most important on-line methods are discussed below along with the hazard criteria used by each technique. 

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