Laser homogeneous

Gortschakov G, Loffhagen D and Winkler R 1998 The homogeneity of a stabilized discharge-pumped XeCI laser Appl. Phys B 66 313-22... 

The most spectacular applications of ECLs are the possibiUty of direct overwrite (DOW) with laser modulation (79,80) and of magnetically iaduced superresolution (81,82). The stacks comprise at least a storage layer s and a bias layer b. For both appHcations, the storage layer s has the lower and the higher at room temperature when compared to the bias layer b. At room temperature, b is homogeneously magnetized (initialized) by an external permanent magnet is about 400 kA/m (5 kOe)). 

Laser sampling is more a physical phenomenon than a chemical one. The energy of the laser is used to nonselectively ablate the sample. This insures homogeneous sampling of a physically defined area regardless of the nature of the components Solubilities are not a factor. This technique shows much promise for ceramics, glasses, and geologic samples. 

A very important characteristic of laser radiation is the beam shape. So far most LA experiments have been performed with Gaussian laser beams. Lasers with uniform distribution of the beam cross-section have been used only recently to achieve high lateral and depth resolution. Specially designed beam homogenizers must be used for this purpose [4.226-4.228]. The Cetac LSX-200 system has a flat-top distribution of the laser beam. 

A commercial fs-laser (CPA-10 Clark-MXR, MI, USA) was used for ablation. The parameters used for the laser output pulses were central wavelength 775 nm pulse energy -0.5 mj pulse duration 170-200 fs and repetition rate from single pulse operation up to 10 Hz. In these experiments the laser with Gaussian beam profile was used because of the lack of commercial beam homogenizers for femtosecond lasers. 

A second problem in these studies concerns cavitation dynamics on the nanometer length scale [86]. If sufficiently energetic, the ultrafast laser excitation of a gold nanoparticle causes strong nonequilibrium heating of the particle lattice and of the water shell close to the particle surface. Above a threshold in the laser power, which defines the onset of homogeneous nucleation, nanoscale water bubbles develop around the particles, expand, and collapse again within the first nanosecond after excitation (Fig. 9). The size of the bubbles may be examined in this way. 

Particle Size Laser Refractometiy is based upon Mie scattering of particles in a liquid medium. Up until about 1985, the power of computers supplied with laser diffraction instruments was not sufficient to utilize the rigorous solution for homogeneous spherical particles formulated by Gustave Mie in 1908. Laser particle instrument manufacturers therefore used approximations conceived by Fraunhofer. 

Sato et al. " measured the viscosities of some binary and ternary alkali carbonates. Since melt creep must be prevented, a highly sintered alumina crucible was used instead of a gold-plated nickel crucible. Homogeneity of a mixture sample was achieved by gas bubbling. A laser beam is combined with a computer-assisted time counter to obtain the logarithmic decrement. Roscoe s equationi3i has been used for calculation of the viscosity, while it has been claimed by Abe et al. that the viscosities calculated from Roscoe s equation are 0.6-1.5% lower than those from more rigorous equations. 

Another intermediate of the photolysis of TiO was observed in experiments with platinized particles (in the absence of polyvinyl alcohol). The spectrum shown in Fig. 22 is prraent immediately after the laser flash. The signal decays as shown by the inset in the figure. The rate of decay is not influenced by oxygen but is increased by oxidizable compounds such as Br ions in the solution. The broad absorption band in Fig. 22 with a maximum at 430 nm was attributed to trapped positive holes. Chemically, a trapped hole is an 0 radical anion. In homogeneous aqueous solution, 0 ... 

Another improvement that will allow quick simultaneous oligoelement homogeneity determinations in milligram samples can be expected by the use of solid sampling ETV-ICP-MS/AES and laser ablation ICP-MS which are now being studied in detail (Moens et al. 1995 Schiffer and Krivan 1999 Dobney et al. 2000). 

Automated organic and elemental ion mapping of TLC plates by LMMS techniques, without focus correction, has been reported [802,839]. One of the early TLC-MS scanners used laser desorption combined with Cl detection [807,808]. The use of laser desorption mass spectrometry (LDMS), in connection with TLC separations, allows sampling of a very small area of a spot (ca. 5 im). In this way spot homogeneity can be determined (e.g. in the case of overlapping components), and also leaves the bulk of the material unaffected for further study. An important advantage... 

Nondestructive radiation techniques can be used, whereby the sample is probed as it is being produced or delivered. However, the sample material is not always the appropriate shape or size, and therefore has to be cut, melted, pressed or milled. These handling procedures introduce similar problems to those mentioned before, including that of sample homogeneity. This problem arises from the fact that, in practice, only small portions of the material can be irradiated. Typical nondestructive analytical techniques are XRF, NAA and PIXE microdestructive methods are arc and spark source techniques, glow discharge and various laser ablation/desorption-based methods. On the other hand, direct solid sampling techniques are also not without problems. Most suffer from matrix effects. There are several methods in use to correct for or overcome matrix effects ... 

When investigating opaque or transparent samples, where the laser light can penetrate the surface and be scattered into deeper regions, Raman light from these deeper zones also contributes to the collected signal and is of particular relevance with non-homogeneous samples, e.g., multilayer systems or blends. The above equation is only valid, if the beam is focused on the sample surface. Different considerations apply to confocal Raman spectroscopy, which is a very useful technique to probe (depth profile) samples below their surface. This nondestructive method is appropriate for studies on thin layers, inclusions and impurities buried within a matrix, and will be discussed below. 

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