Interfaces characteristics required

Connection to the utility grid provides many advantages to on-site power producers such as reliability improvement and increase of load factor, as well as giving the electric utilities a chance to improve the supply capability. When a fuel cell power plant is used for electric utility applications, the inverter is the interface equipment between the fuel cell and the electrical network. The inverter acts as the voltage and frequency adjuster to the final load. The interface conditions require the following characteristics for the inverter ... 

The above formulas may become inapplicable for systems with adsorption processes or/and coupled chemical steps in solution whose characteristic times are comparable with the inverse frequency within the impedance measurement interval. In this case the charge-transfer resistance, Rct, must be replaced by a complex charge-transfer impedance, Zct. Another restriction of this treatment is its assumption of the uniform polarization of the m s interface which requires to ensure a highly symmetrical configuration of the system. Refs. [i] Sluyters-Rehbach M, Sluyters JH (1970) Sine wave methods in the study of electrode processes. In Bard A/ (ed) Electroanalytical chemistry, vol. 4. Marcel Dekker, New York, p 1 [ii] Bard A], Faulkner LR (2001) Electrochemical methods, 2nd edn. Wiley, New York [iii] Retter U, Lohse H (2005) Electrochemical impedance spectroscopy. In Scholz F (ed) Electroanalytical methods. Springer, Berlin, pp 149-166 [iv] Bar-soukov E, Macdonald JR (ed) (2005) Impedance spectroscopy. Wiley, Hoboken... 

The membrane in a broad sense is a thin layer that separates two distinctively different phases, i.e., gas/gas, gas/liquid, or liquid/liquid. No characteristic requirement, such as polymer, solid, etc., applies to the nature of materials that function as a membrane. A liquid or a dynamically formed interface could also function as a membrane. Although the selective transport through a membrane is an important feature of membranes, it is not necessarily included in the broad definition of the membrane. The overall transport characteristics of a membrane depends on both the transport characteristics of the bulk phase of membrane and the interfacial characteristics between the bulk phase and the contacting phase or phases, including the concentration polarization at the interface. The term membrane is preferentially used for high-throughput membranes, and membranes with very low throughput are often expressed by the term barrier. ... 

Problem frames are a means to describe software development problems. They were invented by Jackson [12], who describes them as follows A problem frame is a kind of pattern. It defines an intuitively identifiable problem class in terms of its context and the characteristics of its domains, interfaces and requirement. Problem frames are described hy frame diagrams, which consist of rectangles, a dashed oval, and links between these (see Fig. 1). All elements of a problem frame diagram act as placeholders, which must be instantiated to represent concrete problems. Doing so, one obtains a problem description that belongs to a specific problem class. 

The effects of small Ge additions on physical and mechanical properties were also studied. It was concluded that small additions of Ge contribute to enhance both surface and interface characteristics to improve bonding and bulk materials properties. It was reported that Ge-containing solders have similar or better performance and higher reliability than eutectic Sn-Pb solders. Although these results are very promising, this solder family must be appropriately tested and exercised under actual assembly conditions in manufacturing. The interfacial microstructures and joint rehability require further investigation. 

The Concept of Operations, or ConOps, is a document generated early in the system life cycle and is used to capture behavioral characteristics required of the system in the context of other systems with which it interfaces and it captures the manner in which people will interact with the systan for which the system must provide capabilities. Generation of the ConOps will allow the requirements analysis team to clearly understand operational needs. The rationale for performance requirements will be incorporated into the decision mechanism for later inclusion in the System Design Document and lower-level specifications. The ConOps will help identify safety cases that must be proven in the V V test plans. The ConOps will... 

Detention efficiency. Conversion from the ideal basin sized by detention-time procedures to an actual clarifier requires the inclusion of an efficiency factor to account for the effects of turbulence and nonuniform flow. Efficiencies vaiy greatly, being dependent not only on the relative dimensions of the clarifier and the means of feeding but also on the characteristics of the particles. The cui ve shown in Fig. 18-83 can be used to scale up laboratoiy data in sizing circular clarifiers. The static detention time determined from a test to produce a specific effluent sohds concentration is divided by the efficiency (expressed as a fraction) to determine the nominal detention time, which represents the volume of the clarifier above the settled pulp interface divided by the overflow rate. Different diameter-depth combinations are considered by using the corresponding efficiency factor. In most cases, area may be determined by factors other than the bulksettling rate, such as practical tank-depth limitations. 

Operation When operated correctly, thickeners require a minimum of attention and, if the feed characteristics do not change radically, can be expected to maintain design performance consistently. In this regard, it is usually desirable to monitor feed and underflow rates and sonds concentrations, flocculant dosage rate, and pulp interface level, preferably with dependable instrumentation systems. Process variations are then easily handled by changing the principal operating controls—underflow rate and floccirlant dose—to maintain stability. 

The kinetic principles operating during the initiation and advance of interface-controlled reactions are identical with the behaviour discussed for the decomposition of a single solid (Chaps. 3 and 4). The condition that overall rate control is determined by an interface process is that a chemical step within this zone is slow compared with the rate of arrival of the second reactant. This condition is not usually satisfied during reaction between solids where the product is formed at the contact of a barrier layer with a reactant. Particular systems that satisfy the specialized requirements can, however, be envisaged for example, rate processes in which all products are volatilized or a solid additive catalyzes the decomposition of a solid yielding no solid residue. Even here, however, the kinetic characteristics are likely to be influenced by changing effectiveness of contact as reaction proceeds, or the deactivation of the catalyst surface. 

The maintenance of product formation, after loss of direct contact between reactants by the interposition of a layer of product, requires the mobility of at least one component and rates are often controlled by diffusion of one or more reactant across the barrier constituted by the product layer. Reaction rates of such processes are characteristically strongly deceleratory since nucleation is effectively instantaneous and the rate of product formation is determined by bulk diffusion from one interface to another across a product zone of progressively increasing thickness. Rate measurements can be simplified by preparation of the reactant in a controlled geometric shape, such as pressing together flat discs at a common planar surface that then constitutes the initial reaction interface. Control by diffusion in one dimension results in obedience to the... 

Thermodynamic and mechanical equilibrium on a curved vapor-liquid interface requires a certain degree of superheat in order to maintain a given curvature. Characteristics of homogeneous and heterogeneous nucleation can be estimated in the frame of classical theory of kinetics of nucleation (Volmer and Weber 1926 Earkas 1927 Becker and Doring 1935 Zel dovich 1943). The vapor temperature in the bubble Ts.b can be computed from equations (Bankoff and Flaute 1957 Cole 1974 Blander and Katz 1975 Li and Cheng 2004) for homogeneous nucleation in superheated liquids... 

In this chapter, seven types of LC-MS interfaces have been described and their performance characteristics compared. Any modifications to the HPLC conditions that are required to allow the interface to operate effectively have been highlighted. 

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