Instrument requirements

The X-ray instrumentation requires a commercial small angle X-ray camera, a standard fine structure X-ray generator and a sample manipulator if scanning is requested. The essential signal is the relative difference between the refraction level Ir and the absorption level Ia. Both levels are measured simultaneously by two scintillation detectors. At fixed angles of deflection this signal depends solely on the inner surface density factor C and thickness d of the sample [2] ... 

More microprocessor-based process equipment, such as smart instruments and single-loop controllers, with digital communications capability are now becoming available and are used extensively in process plants. A fieldbus, which is a low-cost protocol, is necessary to perform efficient communication between the DCS and these devices. So-called mini-MAP architec ture was developed to satisfy process control and instrumentation requirements while incorporating existing ISA standards. It is intended to improve access time while... 

These are employed for the measurement of power circuit currents through an ammeter, kW, kWh or KVAr and power factor meter, or similar instruments requiring a current measurement. They must have a specified accuracy class as in lEC 60044-1 and the secondary current substantially proportional to the primary within a working range of about 5-120% of its primary rated current. They... 

It is essential that instrumentation requirements be tailored to the requirements of the machine being monitored. However, the instrumentation requirements should exist to cover the requirements for both vibration and aerothermal monitoring. 

The instrumentation required to measure the hysteresis loop of a ferromagnetic surface with MOKE can be very simple. Figure 4a shows one such implementation of the experimental setup for analysis of ultrathin film samples maintained in a... 

How do you identify whether any quality control, inspection and testing techniques, and instrumentation requires updating to meet specified requirements ... 

NFPA 69 (NFPA 1997) contains information on basic design considerations, design and operating requirements, and instrumentation requirements. Appendix D presents methods for ventilation calculations, including the time required for ventilation to reduce the concentration to a safe limit, the number of air changes required for reaching a desired... 

Column dimension i.d. X L (mm) Typical flow rate (ml/min) Sample load (mg) Instrument requirements... 

The basic instrument required for packed-column unified chromatography is shown schematically in Figure 7.9. This is essentially a two-pump HPLC instrument utilizing high-pressure mixing with just a few new components. At least one pump must... 

SFC has been performed with either open capillary columns similar to those used in GC or packed columns transferred from LC, and the instrumentation requirements differ for these two approaches [12]. This chapter will focus on the use of packed column technology because of its dominance in the area of pharmaceutical compound separations. Current commercial instrumentation for packed column SFC utilizes many of the same components as traditional LC instruments, including pumps, injection valves, and detectors. In fact, most modem packed column SFC instm-ments can also be used to perform LC separations, and many of the same stationary phases can be used in both LC and SFC [9]. 

Figure 12-61D. Centrifugal compressor surge control schematic diagram shows instrumentation required when primary flow-measuring device is located in centrifugal compressor discharge line. Symbols T = temperature P = pressure A = differential across compressor outlet to inlet. See Reference 89 for a detailed discussion. (Used by permission White, M. H. Chemical Engineering, p. 54, Dec. 25,1972. McGraw-Hill, Inc. All rights reserved.)...

The zero-resistance ammeter is seldom employed for routine testing. This instrument requires careful handling to avoid damage, in particular to the galvanometer. Usually two permanent test leads are installed at a set distance apart, and by the initial use of a zero-resistance ammeter a calibration chart of potential between the two leads and current in the structure is drawn up. Thus when routine testing is made, it is only necessary to measure the... 

The potentiostatic technique discussed here involves the polarisation of a metal electrode at a series of predetermined constant potentials. Potentio-stats have been used in analytical chemistry for some time Hickling was the first to describe a mechanically controlled instrument and Roberts was the first to describe an electronically controlled instrument. Greene has discussed manual instruments and basic instrument requirements. 

Campbell (6) was perhaps the first to investigate the relationship between tenderometer values for raw peas and the texture characteristics of collateral samples after freezing and cooking. A high degree of correlation was observed. The investigations of Nielsen and co-workers (31) indicate the usefulness of the instrument for estimation of maturity in peas intended for freezing preservation. In order to secure consistent and reproducible results, the instrument requires standardization and calibration, and the measurements must be made under standardized conditions of temperature and interval after harvest. 

For greater details on the techniques of LS counting in general, including the specialized nuclear instrumentation required and sample handling and preparation, see Refs 5, 6 7... 

The basic instrumentation required for controlled-potential experiments is relatively inexpensive and readily available commercially. The basic necessities include a cell (with a three-electrode system), a voltammetric analyzer (consisting of a potentiostatic circuitry and a voltage ramp generator), and an X-Y-t recorder (or plotter). Modem voltammetric analyzers are versatile enough to perform many modes of operation. Depending upon the specific experiment, other components may be required. For example, a faradaic cage is desired for work with ultramicroelectrodes. The system should be located in a room free from major electrical interferences, vibrations, and drastic fluctuations in temperature. 

Finally, the recording of many signals from the output of the analytic and electrochemical instrumentation requires a reliable multi-pen recorder or an equivalent recording system based on a data acquisition card and appropriate software. The recorded signals are normally in the range of a few mV to 10V. The use of reliable temperature controllers and thermocouples is also crucial for the success of the experiments. A lot of suppliers of such equipment can be easily found and will not be reported here. 

In contrast, an instrument required for method development must be as versatile as possible and all the alternative detectors and accessories should be available to reduce the time spent on the development... 

The real time strip chart mode is especially useful for instruments requiring user interaction or to monitor process sensors. 

Sodium and Potassium. For the electrolytes, sodium and potassium the flame pho meter is the instrument of choice (29). This instrument permits readily the dilution of the serum 200 fold, for analysis, using an internal lithium standard. Most instruments require 1 ml for analysis. It is therefore practicable to measure out 3pi and dilute it to 1 ml. This is best done with a sampler-diluter of high precision. The tip of the diluter needs to be a drawn out polyethylene tip, or the 5 pi will not be measured with any degree of accuracy. 

Ten-year horizon. Based on recent trends in the production of analytical instruments, requirements for RMs should grow by more than 5% per annum. Because PT material usage is growing from a smaller and less structured base, its growth should be about 15 % per annum. 

The instrumental requirements for supercritical fluid extraction are quite simple. A pump is essential to generate the extraction pressure in a themostated extraction vessel. The soluble sample components are then swept from the vessel through a flow restrictor into a collection device that is normally at ambient pressure. The fluid used for supercritical fluid... 

Instrumentation requirements for SEC are somewhat simpler than those of other modes of HPLC, since mobile phase gradients are not used however, adequate computer support for data acquisition and processing is essential. Method development involves finding a suitable solvent for the sample and choosing a mixed bed column or, more often, a set of columns in series to match the pore size of the column(s) with the size distribution of the sample. 

Mineral acid dissolution is an important sample preparation process for instrumental analysis, as it liberates element ions into a solution that can be directly introduced into an analytical instrument. For quantitative analysis, most instruments require a solution. 

This example illustrates how the techniques used in an operability study can be used to decide the instrumentation required for safe operation. Figure 9.5a shows the basic instrumentation and control systems required for the steady-state operation of the reactor section of the nitric acid process considered in Example 4.4. Figure 9.5b shows the... 

Prepare a chemical engineering design of the preheater vaporiser superheater-reactor system and indicate the type of instrumentation required. 

---