Indicator calibration

Barcol Indenter. The Barcol hardness tester is a hand-held, spring-loaded instrument with a steel indenter developed for use on hard plastics and soft metals (ASTM D2583) (2). In use the indenter is forced into the sample surface and a hardness number is read direcdy off the integral dial indicator calibrated on a 0 to 100 scale. Barcol hardness numbers do not relate to nor can they be converted to other hardness scales. The Barcol instrument is calibrated at each use by indenting an aluminum alloy standard disk supplied with it. The Barcol test is relatively insensitive to surface condition but may be affected by test sample size and thickness. 

This instrument was designed to operate with the Kanne ionization chambers built for UWNR. The positive current output of the Kanne chamber is displayed on one of two (normal and abnormal) ranges in microcuries/ml. The signal is integrated to produce a register indication calibrated to indicate microcuries discharged from the stack. 

To this purpose, let us consider the following mental experiment. A transparent cylinder, with a cross-sectional area of 10 cm, is fitted with a piston and immersed into a constant temperature bath at 420 K. The piston has a plate, on which we can place weights, and a volume indicator calibrated to read cm. We assume, for simplicity, that the piston is weightless and frictionless and that the outside pressure is zero. 

The operation is quite simple One sets the frequency to the lowest value, adjusts the gain and phase to the desired sensitivity using a special calibration standard discussed below and performs a zero-compensation on a defect free zone of the standard. Now one is ready to test. As one slides the probe across the surface of an aluminum structure, a signal response will be indicative of the presence of corrosion or of the presence of a subsurface edge. 

The calibration graph for the probe using a strength machine, has been shown in Fig. 7 It can be observed that the dependence of indications of the device of Wirotest type on the loading is linear within the proportionality limit scope. After unloading the indications do not return to zero, but show own stress caused in effect of plastic deformation of the tested sample... 

Two different types of calibration marks are used in our experiments, planar circles and circular balls. The accuracy of the calibration procedure depends on the accuracy of the feature detection algorithms used to detect the calibration marks in the images. To take this in account, a special feature detection procedure based on accurate ellipses fitting has been developed. Detected calibration marks are rejected, if the feature detection procedure indicates a low reliability. 

Measure Wall Thickness This window is used for the dialog to calibrate the algorithm aceording formula (3) and for point wise measurements after calibration. The row Ideal indicates the nominal wall thickness used, IQI indicates the wall thickness values used for calibration and the detected optical density. Local can be used for noise reduction and compensation of geometric effects. 

Equatiou B1.5.44 indicates that if we know -. /i and we may infer infonnation about the third-order orientational moments ( T.., Tjj, Since calibration of absolute magnitudes is difficult, we are generally concerned with a comparison of the relative magnitudes of the appropriate molecular (a ) and macroscopic (... 

When the correct solvent for recrystallisation is not known a procedure similar to that given on pp. 15-16 should be followed, but on the semi-micro scale not more than 10 mg. of the solid should be placed in the tapered-end test-tube (Fig. 29(B)) and about o i ml. of the solvent should be added from the calibrated dropping-pipette (Fig. 30(B)). If the compound dissolves readily in the cold, the solvent is unsuitable, but the solution should not be discarded. [In this case recourse should be had to the use of mixed solvents (p. 18). For example if the substance is very soluble in ethanol, water should be added from a calibrated pipette with shaking to determine whether crystallisation will now take place, indicated by a cloudiness or by the separation of solid.]... 

Personal Errors Finally, analytical work is always subject to a variety of personal errors, which can include the ability to see a change in the color of an indicator used to signal the end point of a titration biases, such as consistently overestimating or underestimating the value on an instrument s readout scale failing to calibrate glassware and instrumentation and misinterpreting procedural directions. Personal errors can be minimized with proper care. 

A second example is also informative. When samples are obtained from a normally distributed population, their values must be random. If results for several samples show a regular pattern or trend, then the samples cannot be normally distributed. This may reflect the fact that the underlying population is not normally distributed, or it may indicate the presence of a time-dependent determinate error. For example, if we randomly select 20 pennies and find that the mass of each penny exceeds that of the preceding penny, we might suspect that the balance on which the pennies are being weighed is drifting out of calibration. 

As can be seen from equation 8.14, we may improve a method s sensitivity in two ways. The most obvious way is to increase the ratio of the precipitate s molar mass to that of the analyte. In other words, it is desirable to form a precipitate with as large a formula weight as possible. A less obvious way to improve the calibration sensitivity is indicated by the term of 1/2 in equation 8.14, which accounts for the stoichiometry between the analyte and precipitate. Sensitivity also may be improved by forming precipitates containing fewer units of the analyte. 

A pH electrode is normally standardized using two buffers one near a pH of 7 and one that is more acidic or basic depending on the sample s expected pH. The pH electrode is immersed in the first buffer, and the standardize or calibrate control is adjusted until the meter reads the correct pH. The electrode is placed in the second buffer, and the slope or temperature control is adjusted to the-buffer s pH. Some pH meters are equipped with a temperature compensation feature, allowing the pH meter to correct the measured pH for any change in temperature. In this case a thermistor is placed in the sample and connected to the pH meter. The temperature control is set to the solution s temperature, and the pH meter is calibrated using the calibrate and slope controls. If a change in the sample s temperature is indicated by the thermistor, the pH meter adjusts the slope of the calibration based on an assumed Nerstian response of 2.303RT/F. 

To circumvent this need for calibration as well as to better understand the separation process itself, considerable effort has been directed toward developing the theoretical basis for the separation of molecules in terms of their size. Although partially successful, there are enough complications in the theoretical approach that calibration is still the safest procedure. If a calibration plot such as Fig. 9.14 is available and a detector output indicates a polymer emerging from the column at a particular value of Vj, then the molecular weight of that polymer is readily determined from the calibration, as indicated in Fig. 9.14. 

Polydisperse polymers do not yield sharp peaks in the detector output as indicated in Fig. 9.14. Instead, broad bands are produced which reflect the polydispersity of synthetic polymers. Assuming that suitable calibration data are available, we can construct molecular weight distributions from this kind of experimental data. An indication of how this is done is provided in the following example. 

Total Radiation Pyrometers In total radiation pyrometers, the thermal radiation is detec ted over a large range of wavelengths from the objec t at high temperature. The detector is normally a thermopile, which is built by connec ting several thermocouples in series to increase the temperature measurement range. The pyrometer is calibrated for black bodies, so the indicated temperature Tp should be converted for non-black body temperature. 

Static Voltmeter These instruments are calibrated to indicate the potential (V) on an ungrounded conductor and usually have more than one calibrated meter/surface spacing. They can be used, for example, to indicate the potential on ungrounded persons or equipment. A meter that indicates in volts or kilovolts is not an electric field meter. 

Electric Field Meter These meters are calibrated to indicate the polarity and magnitude of the electric field (V/m) at the sensor. They should have only one calibrated meter/surface spacing and should be... 

Instrumentation Calibration may be required for the instruments installed in the field. This is typically the job of an instrument mechanic. Orifice plates should be inspected for physical condition and suitabihty. Where necessary, they should be replaced. Pressure and flow instruments should be zeroed. A prehminary material balance developed as part of the prehminary test will assist in identifying flow meters that provide erroneous measurements and indicating missing flow-measurement points. 

The PVFj gauge has been calibrated up to 4 GPa (Bauer, 1984) for both shock loading and release. Graham and Lee (1986) have extended these calibration studies to about 20 GPa, and have measured both a shock loading and release profile in sapphire at 12 GPa, as indicated in Fig. 3.15. 

Two separate flowmeter differentials should be read. These will probably have to be read with DP transmitter. It is suggested both DP units have one quality calibrated 6-in. gauge on transmitter output to directly read differential in %FS, FR, or psi. DP transmitters should be carefully bench-checked/calibrated, retaining indicated versus actual calibration data. 

A crystal material is excited by the force imposed on it by an internal I v mounted mass. A voltage is produced by the crystal proportional to accel eration. This voltage is then amplified by a charge amplifier type signal conditioner from whence the signal can be transmitted long distance. (1.000 feet is not uncommon) to the monitor/readout unit. It is calibrated in terms of gravitational units (g), which are proportional to force. Force is ttnc of the most reliable indicators of equipment distress. 

Zelements, with some indication of compositional changes with depth PIXE provides unequivocal identification of the elements present and, with appropriate calibrations, the absolute areal densities of these elements. 

---