Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Incidental factor

It is follows from Equations (6.23) and (6.24) that the coefficient a in the Polany-Semenov equation depends not only on parameters Are and a but also on the incidental factor such as the range of variation of enthalpies of the selected series of reactions. The same situation is observed for coefficient p in the Hammett and Taft equations (see Equation [6.2]) [11],... [Pg.252]

Figure 10.3 The responses of three hypothetical participants in a trial. Patient A has a good response, B a minimal improvement and C drops out as condition is deteriorating. In this case, in a LOCF analysis, overall symptom deterioration will be underestimated by the size of the arrow and the treatment will appear better, especially with large numbers of dropouts. However, depending on the disorder, the opposite is possible if drop-outs are due to improvement or incidental factors then these patients may also improve and sometimes those deteriorating/improving after drop-out will be equal. The point is, we just don t know what happened to these people. Figure 10.3 The responses of three hypothetical participants in a trial. Patient A has a good response, B a minimal improvement and C drops out as condition is deteriorating. In this case, in a LOCF analysis, overall symptom deterioration will be underestimated by the size of the arrow and the treatment will appear better, especially with large numbers of dropouts. However, depending on the disorder, the opposite is possible if drop-outs are due to improvement or incidental factors then these patients may also improve and sometimes those deteriorating/improving after drop-out will be equal. The point is, we just don t know what happened to these people.
A series of systematic studies on hydrolysis per se were undertaken by Sayer, Whalen, Islam, Jerina and others [147-150], The thrust of their research has been to identify the stereoelectronic, conformational and other incidental factors affecting the kinetics and product distribution in the solvolysis of various PAHDE s under diverse reaction conditions. The aim is, of course, elucidation of reaction mechanisms of PAHDE s in biological systems. Geacintov et al have conducted detailed investigations of reactions of BaPDE s with aqueous solutions of double stranded DNA as a function of temperature, pH and NaCl concentration at different levels of DNA contents [151]. [Pg.473]

Accident or mishap deviation models as used in system safety processes can permit analysis of events in terms of deviations. The value assigned to a system variable becomes a deviation whenever it falls outside an established norm. When measuring system variables, these deviations can assume different values depending on the situation. Hazard control policies and procedures should detail any specified requirements. A deviation from a specified requirement could result in a human error for failure to follow procedures. Therefore, we must consider incidental factors as deviations from an accepted practice. An unsafe act relates to a personal action that violates or deviates from a commonly accepted safe procedure. Time functions as the basic dimension in a system deviation... [Pg.34]

Systems ergonomics Failure modes and effect analysis Fault tree analysis Incidental factor analysis (IFA) Hammer 1972 Meister 1971 Leplat 1978... [Pg.37]

Both the integrative model by Smillie Ayoub (1975) and the deviation concept by Kjellen (1984a) connect the general systems theory to the sequencing and energy models of accident causation. They encompass technical, organizational and human components of the system. Various methods of system safety analysis (e.g. fault tree analysis, incidental factor analysis) support the identification of technical and human deviations as well as the analysis of the conditions and consequences of these deviations. From the discussion of near misses and conflicts it became clear that frameworks of accident causation should cover all kinds of incidents, thus becoming frameworks of incidents. [Pg.43]

One or more of the three principal factors, including wear due to operation, corrosion and incidental damage, may limit the life of a sling. The first may be a function of the times the mast is raised, and the second will be related to time and atmospheric conditions. The third will bear no relation to either, since incidental damage may occur at the first location as well as any other. [Pg.516]

There clearly must be effects from other elements present in the steel incidentally or functionally, but a reasonable relationship between this factor and the measured pitting potential is shown for a large number of steels in Fig. 3.19. Of interest, but not yet explained, is the shape of the curve as discussed elsewhere . [Pg.536]

One factor that complicates the kinetic picture is the salt effect. An increase in ionic strength of the solution usually increases the rate of an SnI reaction (p. 451). But when the reaction is of charge type II, where both Y and RX are neutral, so that X is negatively charged (and most solvolyses are of this charge type), the ionic strength increases as the reaction proceeds and this increases the rate. This effect must be taken into account in studying the kinetics. Incidentally, the fact that the addition of outside ions increases the rate of most SnI reactions makes especially impressive the decrease in rate caused by the common ion. [Pg.395]

The danger to domestic animals, including pets, is an important hazard in the use of all newer economic poisons. Drift dusts or sprays from carelessly applied materials may set back the useful development of many valuable chemicals. Only recently have authorities finally decided that we should slow down on the use of DDT on cows until we know more about the occurrence of the chemical in rtiilk, butter, and steaks. Our sportsmen and, incidentally, a major economic factor in our pleasant way of life—the fish, game, and wildlife activities—are part and parcel of the problem of chemical usage in forests and streams. We need continued and expanded investigations of the effects of the newer pesticides on wild life. [Pg.15]

An incidental conclusion discussed in Section 5 is that exposure of freshly etched silicon surfaces to a given ambient of plasma products seems always to produce a chemical potential of hydrogen just beneath the surface that varies only modestly (no more than a factor ten) over a wide range of the bulk donor or acceptor doping. [Pg.248]

It is a gram-negative, nonsporing, oval-shaped bacterium. It is primarily a zoonotic disease of birds and mammals, with humans as incidental hosts. Often seen in hamsters, guinea pigs, and chinchillas. It has also been associated with enterocolitis and diarrhea in young sheep at pasture that are debilitated from factors such as starvation and cold weather. This is a biosafety level 2 agent. [Pg.521]

Different rules apply to individuals at the site of an attack. They must be concerned about potential radiation exposure, inhalation of airborne contaminants, contamination on skin and clothing, and incidental ingestion of contaminated substances. For individuals at the site of an attack, the following time factor rules apply ... [Pg.128]

Third, if a weight is only incidental to the overall result of an accurate quantitative analysis, then it need not be made on an analytical balance. This means that if the weight measurement to be performed has no bearing whatsoever on the quantity of the analyte tested, but is only needed to support the chemistry or other factor of the experiment, then it need not be measured on an analytical balance. [Pg.40]

Incidentally, since the newly defined coefficients in Eq. (4.6.9) are products of factors, there is more than one way to choose the new correlations. In the choice made in Eqs. (4.6.I0)-(4.6.13), all sites are identical and all six pair correlations are identical. Another possible choice is obtained by replacing condition (4.6.11) by the requirement... [Pg.94]

There is strong evidence for a dissociative type of mechanism for base hydrolysis. There is an =10 -fold rate enhancement (steric acceleration) for base hydrolysis of Co(iso-BuNH2)5CP+ compared to Co(NH3)jCF (mainly residing in while the corresponding factor for aquation is only =<10, emphasizing the different degrees of dissociation D vs /j). There is, incidentally, a LFER for log Atqh vs log slope 1.0, for reactions of a series of Co(III) complexes. Finally, on the basis of a mechanism, the estimated pro-... [Pg.217]

The nondimensionalized frequencies are related to linear and angular frequencies by equation 3.36. The conversion factor from linear frequencies in cm to undimension-alized frequencies is chik = 1.4387864 cm (where c is the speed of hght in vacuum). Acoustic branches for the various phases of interest may be derived from acoustic velocities through the guidelines outlined by Kieffer (1980). Vibrational modes at higher frequency may be derived by infrared (IR) and Raman spectra. Note incidentally that the tabulated values of the dispersed sine function in Kieffer (1979c) are 3 times the real ones (i.e., the listed values must be divided by 3 to obtain the appropriate value for each acoustic branch see also Kieffer, 1985). [Pg.141]

The T25 value may either be incidentally obtained from the experimental smdy or calculated from other mmor incidences at the selected tumorigenic dose (determined above), using linear extrapolation, i.e., by multiphcahon of the dose with the factor 25/p where p is the acmal mmor incidence (e.g., in case of a net 15% incidence, multiply by 25/15). [Pg.310]

Dermal/Ocular Effects. Very few reports mention any effect of carbon tetrachloride inhalation on the skin. Inhalation exposure to carbon tetrachloride for several days in the workplace caused a blotchy, macular rash in one man (but not in six others) (McGuire 1932). Similarly, a hemorrhagic rash occurred in a woman exposed to carbon tetrachloride fumes for several days in the workplace (Gordon 1944), and black and blue marks were seen in a patient exposed intermittently to carbon tetrachloride vapors for several years (Straus 1954). Because observations of dermal effects are so sporadic, it is difficult to judge whether these effects are related to carbon tetrachloride exposure, or are incidental. Conceivably, they may have been secondary to reduced synthesis of blood coagulation factors resulting from carbon tetrachloride-induced hepatotoxicity. No studies were located regarding ocular effects in humans or animals after inhalation exposure to carbon tetrachloride. [Pg.33]

The physical environment within a crystal, of course, is not identical to that in solution or in a living cell. A crystal imposes a space and time average on the structure deduced from its analysis, and x-ray diffraction studies provide little information about molecular motion within the protein. The conformation of proteins in a crystal could in principle also be affected by nonphysiological factors such as incidental... [Pg.137]

How do each of these functions help the salesmen to sell Prior to making the decision to produce a new product based on a company s proprietary technology or to produce a product currently on the market based on self-developed or licensed technology, management should have considerable detail on market size, end use industries and applications, prices, competition, possible market share under varying conditions, product mix requirements, and a list of prospective customers. Forecasts for each of these factors should be made for three, five, and possibly ten year time spans. Incidentally, this type of information is much more difficult to develop for new products than for established products. [Pg.102]

Incidentally, the telegrapher s equation (17) with x = ihjlmc2 is satisfied by the Klein-Gordon (also Dirac) wavefunction for a free particle, if the factor exp [—(ijh)mc2f is split off from it. Thus, the time lag according to relativity corresponds to an imaginary relaxation time x. [Pg.368]


See other pages where Incidental factor is mentioned: [Pg.240]    [Pg.46]    [Pg.38]    [Pg.240]    [Pg.46]    [Pg.38]    [Pg.261]    [Pg.261]    [Pg.367]    [Pg.775]    [Pg.121]    [Pg.164]    [Pg.167]    [Pg.248]    [Pg.133]    [Pg.247]    [Pg.132]    [Pg.897]    [Pg.45]    [Pg.275]    [Pg.189]    [Pg.301]    [Pg.52]    [Pg.197]    [Pg.288]    [Pg.3]    [Pg.350]    [Pg.254]   


SEARCH



Incidental

Incidental factor analysis

© 2024 chempedia.info