Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

IF determination

NOTE This chart assumes oxygen scavenger, polymer, and other necessary water chemistry controls are in place. If determining TDS via a conductivity meter, use an un-neutralized sample. [Pg.429]

In summary, we say the voltage of a cell is the same as a cell s emf if determined at zero current. From Faraday s laws of electrolysis, this criterion implies that none of the compositions within the cell can change. In other words, a cell emf is an equilibrium quantity. [Pg.295]

Atomic absorption spectrometric methods and, more recently, the inductively coupled plasma atomic emission method, are, of course, mandatory if determination of elements is required (arsenic, selenium, boron, phosphorus and silicon). [Pg.115]

Note if determinations of certain volatile elements such as mercury or selenium are required it is necessary to carry out these analyses on the wet sample as received (to avoid loss of element by drying at 105°C). The dry weight of material in the sample is obtained by determining moisture in a separate position of the sample and applying a correction to the sample weight used in metals determination. [Pg.439]

Changes in clinical chemistry parameters (e.g., semm protein levels, immunoglobulin concentrations if determined)... [Pg.140]

A similar rearrangement of a racemic a-deuteriated ether 84-rf afforded 70% yield of S5-d (98% D-content) with significantly decreased enantioselectivity (14% ee) (equation 47). This result suggests that the enantioselectivity may be determined substantially at the lithiation step, since the enantioselectivity should be the same as observed with the non-deuteriated substrate, if determined at the post-lithiation step. [Pg.770]

Note 3 Young s modulus may he evaluated using tensile or compressive uniaxial deformation. If determined using tensile deformation it may be termed tensUe modulus. Note 4 For non-Hookean materials the Young s modulus is sometimes evaluated as ... [Pg.160]

Figure 12 shows time courses of IF determined for single droplets with r = 5 and 13 /im using DPA as a fluorescer. Upon electrolysis of Fe(II) in the water phase, the /F value increases with a time constant of several tens of seconds and saturates at a certain value. The result indicates that ET between Fe(III) in the water phase and FeCp-H in the droplet takes place as expected from Figure 11. The saturated IF value has been used as /F0 for a given experiment. Figure 13 shows the time dependence of ln [/F0//F(t)] -1. As predicted from Eq. 3, the ln [/F0//F( )] — 1 value decreases linearly with t. Since we know fcq of DPA by FeCp-H and t0 to be 8.9 x 109M-1s-1 and 9 ns for TBP droplets (r 5 fim), respectively, the intercept value should be 1.4 irrespective of r as predicted from... Figure 12 shows time courses of IF determined for single droplets with r = 5 and 13 /im using DPA as a fluorescer. Upon electrolysis of Fe(II) in the water phase, the /F value increases with a time constant of several tens of seconds and saturates at a certain value. The result indicates that ET between Fe(III) in the water phase and FeCp-H in the droplet takes place as expected from Figure 11. The saturated IF value has been used as /F0 for a given experiment. Figure 13 shows the time dependence of ln [/F0//F(t)] -1. As predicted from Eq. 3, the ln [/F0//F( )] — 1 value decreases linearly with t. Since we know fcq of DPA by FeCp-H and t0 to be 8.9 x 109M-1s-1 and 9 ns for TBP droplets (r 5 fim), respectively, the intercept value should be 1.4 irrespective of r as predicted from...
The value of RAF obtained in the first approach is about 1.1 for both locations and is slightly higher (1.15) if determined in the second approach. This discrepancy may be due to some hidden factor which affects the erythemal irradiance and is correlated with total ozone but not included in UV-ERY versus total ozone regression. Overall, the values of RAF are in good agreement with other authors [1, 11, 13]. [Pg.181]

She nodded, keeping her eyes downcast even behind the veil. Workmen at the far end of the hall were laying out lumber to start crating up the pictures, as if determined to make the interview even more difficult. [Pg.100]

Summarizing, experimentally determined Kow-values of surfactants, even if determined properly, are reflective of the experimental conditions. Hence, they cannot be used as a general measure of surfactant hydrophobidty as they are for neutral apolar compounds. [Pg.452]

Due to poor laboratory technique, statistically determined limits may be inadequately wide. For example, recovery limits of zero to 200 percent are not acceptable for any analyte, even if determined statistically they indicate only a poor quality of laboratory work. Such control limits should not satisfy a data user who is concerned with data quality. [Pg.259]

Are inspection and test frequencies consistent with the manufacturers recommendation and good engineering practice Are inspections and tests performed more frequently if determined necessary by operating experience ... [Pg.207]

The generation, accumulation, treatment, storage, and disposal of hazardous wastes are regulated under RCRA and the Hazardous Solid Waste Amendments of 1984. Wastes derived from the management and destruction of chemical agents and munitions, i.e., secondary wastes, must be assessed under this authority and, if determined to be hazardous, must be managed under it. [Pg.34]

The structures of the CuL6 chromophores may be temperature variable with bond-length changes of the order of the Jahn-Teller radius, Fig. 1(A), Rjj = 0.1-0.4 A, accessible by low temperature X-ray crystallography, which if determined at low enough temperature may yield AE values. [Pg.65]

Are inspections and tests performed more frequently if determined necessary by operating experience ... [Pg.172]

In 1955, Born wrote an article entitled Is classical mechanics in fact deterministic (reprinted in Born (1969)). In this article Born tried to expose the emptiness of the concept of determinism. His argument is the following If determinism is not a useful concept to begin with, an... [Pg.21]

To repeat, sampling must be done uniformly and at equal intervals for the probabihty distribution analysis to be applicable. Otherwise, the apphcahon of the method will be difficult, since the probabihty of each element wih be undetermined or, if determinable, is calculated with difficulty. Of course, the probabihty of each element can always be assumed equal, even if the sampling is irregular. If you see this done in practice, the concept upon which the probabihty distribution analysis is based has been violated and you are guaranteed that whatever is the result, it is wrong. [Pg.136]

At a constant 0 value, the [A]d/[B]d term, if it remains constant, must lead to the resolution of binding curves, if determined at different [B] values, that parallel to each other with the distance between them expressed by Z log[B]. Also, by use of the polyion domain volume, Vp, [A]d can be expressed as... [Pg.285]

Hydrophobicity or lipophilicity is understood as a measure of the relative tendency of an analyte to prefer a non-aqueous to an aqueous environment. The partition coefficients of the substances may differ if determined in different organic-water eluent systems but their logarithms are often linearly related [117]. Octanol-water partitioning is a common reference system which provides the most commonly recognized hydrophobicity measurement, the logarithm of the partition coefficient, log P [8,45,46]. [Pg.531]

The ambient ratio NO2/NO is controlled by a combination of the interconversion reactions (Equations (11) and (5)) and the ozone-producing reactions (3) and (4). Because the ozone-producing reactions involve conversion of NO to NO2 and affect the ratio NO2/NO, measured values of this ratio can be used (especially in the remote troposphere) to identify the process of ozone formation. When the ratio NO2/NO is higher than it would be if determined solely by reactions (5) and (11), it provides evidence for ozone formation (e.g., Ridley et al., 1992). Reactions (3)-(5), and (11) can be combined to derive the summed concentration of HO2 and RO2 radicals from measured O3,... [Pg.4957]

If determinations are to be done on two or three samples that dilfer in melting point by as much as 10°C, two or three capillaries can be secured to the thermometer together and the melting points observed in succession without removal of the thermometer from the bath. As a precaution against interchange of tubes while they are being attached, use some system of identification, such as one, two, and three dots made with a marking pencil. [Pg.53]

Automation of cell counting (total cells) is possible with electronic counters, especially for non-clumping single suspension cells. A method that is widely used for total cell numbers is counting cell nuclei after dissolving the cytoplasm. This is particularly useful for large clumps of cells, where cells are inaccessible (e.g. in matrices) or where cells are difficult to trypsinize off substrates (e.g. microcarriers). If determination of viability is the prime consideration, then the most accurate method is to count the cells that have the ability to divide by the mitotic index method. [Pg.55]

Aliquot 10 pL of this reaction mixture into a microcentrifuge tube containing 1 pg of total cellular RNA in 10 pL depH20. Heat at 37°C for 45 min, then at 95°C for 5 min to terminate the reverse transcription. The resulting cDNAs can be diluted for PCR. The cDNA not used in serial dilutions can be stored at -20°C for reuse if needed. If determination of other genes is anticipated, then the random primer protocol ought to be used to generate the cDNA (see Note 9). [Pg.73]


See other pages where IF determination is mentioned: [Pg.169]    [Pg.32]    [Pg.537]    [Pg.275]    [Pg.20]    [Pg.205]    [Pg.224]    [Pg.122]    [Pg.202]    [Pg.239]    [Pg.581]    [Pg.230]    [Pg.430]    [Pg.239]    [Pg.581]    [Pg.50]    [Pg.37]    [Pg.448]    [Pg.535]    [Pg.535]    [Pg.745]    [Pg.2956]    [Pg.3288]    [Pg.48]    [Pg.22]   
See also in sourсe #XX -- [ Pg.142 ]




SEARCH



Criteria for Determining if Mass loading (Saltation) Occurs

Determining if the Mass Loading Effect will Occur

How to Determine if Your Facility Must Submit EPA Form

Howto Determine if a SNUR Exists

© 2024 chempedia.info