High-nickel stainless steel plates corrosion

P3-4 Corrosion of high-nickel stainless steel plates was found to occur in a distillation column used at DuPont to separate HCN and water. Sulfuric acid is always added at the top of the column to prevent polymerization of HCN. Water collects at the bottom cf the column and HCN at the top. The amount of corrosion on each tray is shown in Figure P3-4 as a function of plate location in the column. 

Electroplating passive alloys Another application of strike baths reverses the case illustrated in the previous example. The strike is used to promote a small amount of cathode corrosion. When the passivation potential of a substrate lies below the cathode potential of a plating bath, deposition occurs onto the passive oxide film, and the coating is non-adherent. Stainless steel plated with nickel in normal baths retains its passive film and the coating is easily peeled off. A special strike bath is used with a low concentration of nickel and a high current density, so that diffusion polarisation (transport overpotential) depresses the potential into the active region. The bath has a much lower pH than normal. The low pH raises the substrate passivation potential E pa, which theoretically follows a relation... 

Valves must be made of fatigue-resistant carbon or alloy steel or 18-8 stainless steel, depending upon the service. The 18-8 stainless and 12-14 chrome steel is often used for corrosive and/or high temperature service. Any springs, as in the plate-type valves, are either carbon or nickel steel. Valve passages must be smooth, streamlined, and as large as possi-... 

Metal foams have been used in the past in the development of FF plates. However, Gamburzev and Appleby [53] used Ni foams as both a DL and a flow field plate with an MPL layer on one of its surfaces. They observed that such a design had high contact resistance between the nickel foam and the MPL and also increased gas diffusion resistance due to the required MPL thickness. Arisetty, Prasad, and Advani [54] were able to demonstrate that these materials can also be used as potential anode diffusion layers in DMFCs (see Figure 4.10). In fact, the nickel foam used in this study performed better than a carbon cloth (Avcarb 1071HCB) and a stainless steel mesh. However, it was recognized that a major drawback for these foams is their susceptibility to corrosion. 

Researchers have tried to fabricate plates using many different metals— mainly, stainless steel, aluminum alloys, titanium alloys, nickel alloys, copper alloys, intermetallic alloys, and metal-based composites such as carbon fiber-reinforced aluminum alloys, carbon fiber reinforced copper alloys, etc. [26]. Although Ta, Hf, Nb, Zr, and Ti metals show good corrosion resistance and chemical stability [6], the cost of fhese metals is too high for them to be used as materials in metal plates. That is why relatively cheaper iron-based alloys, particularly stainless steel, have been popularly studied as plate material. In the following secfions, we will infroduce sfainless sfeel (SS) and SS plates, which have been extensively investigated and show promise for the final applications [6,11]. 

Nickel is used mostly for the production of stainless steel and other nickel alloys with high corrosion and temperature resistance. Nickel alloys and nickel platings are used in vehicles, processing machinery, armaments, tools, electrical equipment, household appliances, and coins. Nickel compounds also are used as catalysts, pigments, and in batteries. 

Injection molds are machined from a variety of tool steels and then hardened or in some cases plated with chromium, nickel, or proprietary materials. Large molds use prehardened tool steels because they cannot be hardened after machining. 124 Stainless steel is employed for some smaller molds, particularly those used for optical and medical parts and for corrosion resistance. Since they provide better heat transfer and, thus, shorter molding cycles, materials such as beryllium copper are used as inserts in critical areas. Injection molds are usually cooled or heated with water, although oil or electric heater cartridges are employed for high-mold temperatures. Mold-temperature controllers pump water into the manifolds and then into cooling fine machine into the molds. 

Nickel. Nickel is a hard, malleable, and ductile metal that is highly resistant to corrosion. Like chromium, it is used to make stainless steel. Alloyed with copper, it is used for ship propellers and chemical industry plumhing. Other uses include rechargeable batteries, coins e, foundry products, plating, burglar-proof vaults, armor plates, and crucibles. 

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