Foam permeability

Table 3 shows values for the foam permeability to air, deduced from creep experiments. Verdejo (a.9) measured a value of 70 x lO m2 -i foam... 

PP bead foams of a range of densities were compressed using impact and creep loading in an Instron test machine. The stress-strain curves were analysed to determine the effective cell gas pressure as a function of time under load. Creep was controlled by the polymer linear viscoelastic response if the applied stress was low but, at stresses above the foam yield stress, the creep was more rapid until compressed cell gas took the majority of the load. Air was lost from the cells by diffusion through the cell faces, this creep mechanism being more rapid than in extruded foams, because of the small bead size and the open channels at the bead bonndaries. The foam permeability to air conld be related to the PP permeability and the foam density. 15 refs. 

This result indicates that the gas (foam) permeability increases with capillary number and average bubble size. Also, k varies with... 

Figure 9. Observed dependence of gas (foam) permeability on gas flow rate for low liquid rates. The data shown correspond to different displacement histories and A for gas only displacements with the pressure being increased between each test for gas only displacement, but with the pressure being lowered and O to Ql = 0.3 jjJL/s and the pressure being increased.

Exerowa and co-workers [201] suggest that surfactant association initiates black film formation the growth of a black film is discussed theoretically by de Gennes [202]. A characteristic of thin films important for foam stability, their permeability to gas, has been studied in some depth by Platikanov and co-workers [203, 204]. A review of the stability and permeability of amphiphile films is available [205]. 

Eresh fmit and vegetable packaging is often in bulk in a variety of traditional wooden boxes and crates, and cormgated fiberboard cases. At or near the retail level, bulk produce may be repackaged in oxygen-permeable flexible materials such as PVC, with or without a tray of foamed polystyrene. 

Foamed or Cellular CeUular plastics such as polyurethane and polystyrene do not hold up or perform well in the ciyogenic temperature range because of permeation of the cell strnc tnre by water vapor, which in turn increases the heat-transfer rate. CeUular glass holds up better and is less permeable. 

In suspension processes the fate of the continuous liquid phase and the associated control of the stabilisation and destabilisation of the system are the most important considerations. Many polymers occur in latex form, i.e. as polymer particles of diameter of the order of 1 p.m suspended in a liquid, usually aqueous, medium. Such latices are widely used to produce latex foams, elastic thread, dipped latex rubber goods, emulsion paints and paper additives. In the manufacture and use of such products it is important that premature destabilisation of the latex does not occur but that such destabilisation occurs in a controlled and appropriate manner at the relevant stage in processing. Such control of stability is based on the general precepts of colloid science. As with products from solvent processes diffusion distances for the liquid phase must be kept short furthermore, care has to be taken that the drying rates are not such that a skin of very low permeability is formed whilst there remains undesirable liquid in the mass of the polymer. For most applications it is desirable that destabilisation leads to a coherent film (or spongy mass in the case of foams) of polymers. To achieve this the of the latex compound should not be above ambient temperature so that at such temperatures intermolecular diffusion of the polymer molecules can occur. 

Typically, large-scale gas filling makes the main characteristics of foam plastics — coefficients of heat and temperature conductivity, dielectric permeability, and the tangent of the dielectric loss angle — totally independent of the chemical structure of the original polymer [1],... 

Peelable film in case-ready ground beef package add color and shelf life. As an example Cryovac Div. of W. R. GRACE CO uses a peelable barrier lid and foam tray system. It is two packages in one there is an oxygen barrier structure, which is peeled off, leaving an oxygen-permeable film over the meat. 

The results at 75°C are consistent with results of steam foam sand pack floods reported by Muys and Keizer [63]. They observed lower sand pack permeability with increased AOS carbon number. Isaacs et al. reported similar results [64]. 

Marquis [86] described a method of enhancing the permeability profile of an oil-bearing formation during the injection of a foam-forming composition or a... 

Fig. 2.1 Sequence of events in atherogenesis and role of low-density lipoprotein. Native LDL, in the subendothelial space, undergoes progressive oxidation (mmLDL) and activates the expression of MCP-1 and M-CSF in the endothelium (EC). MCP-1 and M-CSF promote the entry and maturation of monocytes to macrophages, which further oxidise LDL (oxLDL). Ox-LDL is specifically recognised by the scavenger receptor of macrophages and, once internalised, formation of foam cells occurs. Both mmLDL and oxLDL induce endothelial dysfunction, associated with changes of the adhesiveness to leukoc)des or platelets and to wall permeability.

The foam, having a viscosity greater than the displacing medium, will preferentially accumulate in the well-swept and/or higher permeability zones of the formation. The displacing medium is thus forced to move into the unswept or underswept areas of the formation. It is from these latter areas that the additional oil is recovered. However, when a foam is used to fill a low oil content area of the reservoir, the oil contained therein is, for all practical purposes, lost. This is because the foam functions to divert the displacement fluid from such areas [1574-1576]. 

Laboratory studies of foam flow in porous media suggest that the relative foam mobility is approximately inversely proportional to the permeability. This means that foam has potential as a flow-diverting agent, in principle sweeping low-permeability regions as effectively as high-permeability regions [716]. 

The literature is replete with references to various foaming agents which are employed to lower permeability in steam swept zones. The vast majority of the foaming agents require the injection of a non-condensable gas to generate the foam in conjunction with the injection of steam and the foaming agent [1372]. 

C12 to Ci5 alcohols and a-olefin sulfonate are highly effective with steam foaming agents or carbon dioxide foaming agents in reducing the permeability of flood-swept zones [1372]. 

Foamed cement slurries have been used to provide a low density cement slurry to reduce permeability damage to highly sensitive formations through reduced fluid loss (29). Glass microspheres have also been used to substantially reduce cement slurry density (30, 31). Other additives which reduce cement slurry density to a lesser extent include bentonite, fly ash, silicates, perlite, gilsonite, diatomaceous earth, and oil emulsions (see citations in reference 29). 

It is now possible to explain the origin of a critical capillary pressure for the existence of foam in a porous medium. For strongly water-wet permeable media, the aqueous phase is everywhere contiguous via liquid films and channels (see Figure 1). Hence, the local capillary pressure exerted at the Plateau borders of the foam lamellae is approximately equal to the mean capillary pressure of the medium. Consider now a relatively dry medium for which the corresponding capillary pressure in a... 

Since, in general, lower permeability media exhibit higher capillary-pressure suction, we argue that it is more difficult to stabilize foam when the permeability is low. Indeed the concept of a critical capillary pressure for foam longevity can be translated into a critical permeability through use of the universal Leverett capillary-pressure J-function (.13) and, by way of example, the constant-charge model in Equation 2 for II ... 

We can conclude that the stability of static foam in porous media depends on the medium permeability and wetting-phase saturation (i.e., through the capillary pressure) in addition to the surfactant formulation. More importantly, these effects can be quantified once the conjoining/disjoining pressure isotherm is known either experimentally (8) or theoretically (9). Our focus... 

Figure 5. The critical absolute permeability necessary to sustain the stability of a static foam as a function of liquid saturation. Calculations are for the constant-charge electrostatic model.

For transporting foam, the critical capillary pressure is reduced as lamellae thin under the influence of both capillary suction and stretching by the pore walls. For a given gas superficial velocity, foam cannot exist if the capillary pressure and the pore-body to pore-throat radii ratio exceed a critical value. The dynamic foam stability theory introduced here proves to be in good agreement with direct measurements of the critical capillary pressure in high permeability sandpacks. 

High pressure equipment has been designed to measure foam mobilities in porous rocks. Simultaneous flow of dense C02 and surfactant solution was established in core samples. The experimental condition of dense CO2 was above critical pressure but below critical temperature. Steady-state CC -foam mobility measurements were carried out with three core samples. Rock Creek sandstone was initially used to measure CO2-foam mobility. Thereafter, extensive further studies have been made with Baker dolomite and Berea sandstone to study the effect of rock permeability. 

In this section the laboratory measurements of CC -foam mobility are presented along with the description of the experimental procedure, the apparatus, and the evaluation of the mobility. The mobility results are shown in the order of the effects of surfactant concentration, CC -foam fraction, and rock permeability. The preparation of the surfactant solution is briefly mentioned in the Effect of Surfactant Concentrations section. A zwitteronic surfactant Varion CAS (ZS) from Sherex (23) and an anionic surfactant Enordet X2001 (AEGS) from Shell were used for this experimental study. 

The Effect of Surfactant Concentrations, The effect of surfactant concentrations on CC -foam mobility is plotted on a log-log scale in Figure 3. The presented data points are the average mobility values obtained from a superficial velocity range of 2-10 ft/day, with the CC -foam fraction was kept constant around 80%. With Berea sandstone, ZS and AEGS surfactants were used. The measured average permeability of the Berea sandstone with 1% brine was 305 md. With Baker dolomite, AEGS was used to make comparison with Berea sandstone. The permeability of the Baker dolomite was 6.09 md measured with 1% brine solution. 

Thus, in the very approximate sense in which "foam" is considered to be a single fluid that saturates the porespace (so that singlephase permeability could be used to characterize the rock), the "effective viscosity" of the foam could be taken to be the reciprocal of the relative mobility. 

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