Fluids containing

The fluids contained within petroleum accumulations are mixtures of organic compounds, which are mostly hydrocarbons (molecules composed of hydrogen and carbon atoms), but may also include sulphur, nitrogen, oxygen and metal compounds. This section will concentrate on the hydrocarbons, but will explain the significance of the other compounds in the processing of the fluids. 

So far we have considered only a single component. However, reservoir fluids contain a mixture of hundreds of components, which adds to the complexity of the phase behaviour. Now consider the impact of adding one component to the ethane, say n-heptane (C7H.,g). We are now discussing a binary (two component) mixture, and will concentrate on the pressure-temperature phase diagram. 

The example of a binary mixture is used to demonstrate the increased complexity of the phase diagram through the introduction of a second component in the system. Typical reservoir fluids contain hundreds of components, which makes the laboratory measurement or mathematical prediction of the phase behaviour more complex still. However, the principles established above will be useful in understanding the differences in phase behaviour for the main types of hydrocarbon identified. 

In many cases the dynamical system consists of fast degrees of freedom, labeled x, and slow degrees of freedom, labeled y. An example is that of a fluid containing polyatomic molecules. The internal vibrations of the molecules are often very fast compared to their translational and orientational motions. Although this and other systems, like proteins, have already been treated using RESPA,[17, 34, 22, 23, 24, 25, 26] another example, and the one we focus on here, is that of a system of very light particles (of mass m) dissolved in a bath of very heavy particles (mass M).[14] The positions of the heavy particles are denoted y and the positions of the light particles rire denoted by X. In this case the total Liouvillian of the system is ... 

Preparation of the polymer can be carried out in glass equipment at atmospheric pressure at temperatures typically above 100°C, but the higher pressures in an autoclave result in much faster reaction rates. Each polymer molecule which used butanol as a starter contains one hydroxyl end group as it comes from the reactor diol-started polymers contain two terminal hydroxyls. Whereas a variety of reactions can be carried out at this remaining hydroxyl to form esters, ethers, or urethanes, this is normally not done and therefore lubricant fluids contain at least one terminal hydroxyl group (36). 

Wetting. Films can be formed on surfaces by wetting the surface with a fluid containing the desired material usually dissolved in a solvent. 

Human toxicity, aquatic toxicity, and the environmental impact of engine coolants and deicing fluids ate typically measured on the fresh fluid only. Spent fluids contain varied contaminants that can drastically affect the toxicity and environmental impact of the fluid. Most pronounced is the impact of heavy-metal contaminants in spent antifreeze. Data on spent and recycled antifreeze, compiled by the ASTM Committee on Engine Coolants, show an average lead level 11 ppm, as weU as various other metal contaminants (iron, copper, zinc) (18). The presence of these contaminants in a used fluid may require special disposal techniques for the fluids. 

The laser-Doppler anemometer measures local fluid velocity from the change in frequency of radiation, between a stationary source and a receiver, due to scattering by particles along the wave path. A laser is commonly used as the source of incident illumination. The measurements are essentially independent of local temperature and pressure. This technique can be used in many different flow systems with transparent fluids containing particles whose velocity is actually measured. For a brief review or the laser-Doppler technique see Goldstein, Appl. Mech. Rev., 27, 753-760 (1974). For additional details see Durst, MeUing, and Whitelaw, Principles and Practice of Laser-Doppler Anemometry, Academic, New York, 1976. 

Precipitation fouling (ex.—Scahng). A fluid containing some dissolved material becomes supersaturated with respect to this mate-... 

A second convention is the placement of an imaginaiy envelope around the outermost boundaiy of a porous particle, so that all solute and nonadsorbing fluid contained within the pores of the particle is considered adsorbed. 

Silicone fluids containing Si—H groups are also used for paper treatment. The paper is immersed in a solution or dilute emulsion of the polymer containing either a zinc salt or organo-tin compound. The paper is then air-dried and heated for two minutes at 80°C to cure the resin. The treated paper has a measure of water repellency and in addition some anti-adhesive properties. 

Metalworking fluids contain mineral oils (refer to p. 80) or synthetic lubricants they are used neat or in admixture with water. They may contain small amounts of biocides, stabilizers, emulsifiers, coiTosion inhibitors, fragrances and extreme pressure additives. The formulations render them suitable for application to metal being worked, generally from a recirculatory system, to provide lubrication, corrosion protection, swarf removal and cooling of the tool and machined surface. 

Avoid the use of water-mix synthetic fluids containing nitrites if there is a technologically effective alternative. 

So far, since we have been treating the flow as being dominated by the jet, we have ignored the effects of the exhaust flow. Of course, the exhaust flow will increase the overall movement of the air, to a small extent far from the ex haust hood but quite significantly close to the hood. We shall discount these positive effects, and consider only the fact that the exhaust hood should remove all the fluid contained within the jet. This can be expressed as... 

Placing the fluid through the tubes is a consideration when special alloy materials aie needed for corrosion control, because the materials would be needed only on the tubes. If the corrosive material is in the shell, both the tubes and the shell would need to be protected with special alloy. It the fluid is at high pressure, it should be put in tubes because tubes can contain high pressure much more cheaply as they are much smaller in diameter than the shell. The low-pressure fluid would be in the shell. If the fluid contains vapor and non-condensable gases, heat transfer will be greater if it is placed in the tubes. If the fluid is scale forming it should be in the tubes, which can be reamed out. 

Pre.ssure vessels handling salt water and fluids containing signficiant amounts ot HiS and COi require corrosion protection. Common corro-... 

As the refractive index of fluids varies with the temperature, it is of importance to know the temperature of the fluid contained in the double prism during the process of measurement. 

O-rIng sealing lor positive secondary fluid containment. 

Figures 10-101, lO-lOJ, and 10-1 OK indicate the process flow patterns for single tube units and for multiple corrugated tubes in a single plain shell. These units are suitable for heating or cooling process fluids containing high pulp or fiber content or suspended particulates. The heat transfer coefficients are improved when compared to plain tubes as the turbulence improves the performance. The units can be arranged in multiple shells for parallel or series flow. The manufacturers should be contacted for details.

Oil-Base Systems. Oil-base completion and workover fluids contain oil as the continuous phase. Their application is limited by their density to formations with... 

The tool Joint holds drill pipe together, and the shoulders (similar to drill collars) form a metal-to-metal seal to avoid leakage. The tool Joint threads are designed to be made up with drilling fluid containing solids. Clearance must be provided at the crest and root of threads in order to accommodate these solids. Therefore, the shoulder is the only seal. To keep the shoulders together, proper makeup torque is required. 

Basically all formations penetrated during drilling are porous and permeable to some degree. Fluids contained in pore spaces are under pressure that is overbalanced by the drilling fluid pressure in the well bore. The bore-hole pressure is equal to the hydrostatic pressure plus the friction pressure loss in the annulus. If for some reason the borehole pressure falls below the formation fluid pressure, the formation fluids can enter the well. Such an event is known as a kick. This name is associated with a rather sudden flowrate increase observed at the surface. 

This pressure of lOpsi acts on all parts of the fluid container, including the bottom of the output piston. The upward force on the output piston is 200pounds (lOpsi x piston area). In this case, the original force has been multiplied tenfold while using the same pressure in the fluid as before. In any system with these dimensions, the ratio of output force to input force is always 10 to 1, regardless of the applied force. For example, if the applied force of the input piston is 50 pounds, the pressure in the system will be 25 psi. This will support a resistant force of 500 pounds on the output piston. The system works the same in reverse. 

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