Fluid foam, continuous

Preliminary remarks. Foam is a fluid multiphase continuous medium possessing an internal structure. The disperse phase consists of gaseous bubbles capsulated into multilayer elastic envelopes consisting of some adsorption layers of surfactants and submersed into a continuous phase. The capsules are in a close contact with one another so that they are locally deformed and form a structure with an anisotropic distribution of the continuous phase around each cell. 

Foams are used industrially and are important in rubber preparations (foamed-latex) and in fire fighting. The foam floats as a continuous layer across the burning surface, so preventing the evolution of inflammable vapours. Foams are also used in gas absorption and in the separation of proteins from biological fluids. See anti-foaming agents. 

One simple rheological model that is often used to describe the behavior of foams is that of a Bingham plastic. This appHes for flows over length scales sufficiently large that the foam can be reasonably considered as a continuous medium. The Bingham plastic model combines the properties of a yield stress like that of a soHd with the viscous flow of a Hquid. In simple Newtonian fluids, the shear stress T is proportional to the strain rate y, with the constant of proportionaHty being the fluid viscosity. In Bingham plastics, by contrast, the relation between stress and strain rate is r = where is... 

Chemical additives for gas-based drilling fluids are limited to surfactants (qv), certain polymers, and occasionally salts such as sodium or potassium chloride. An aqueous solution of the additives is iajected iato the air or gas flow to generate a mist or foam. No additives are used ia dry air or gas drilling operations. Gas-based fluids are not recirculated and materials are added continuously. As the fluid exits the well, air or water vapor escapes to the atmosphere, gas and oil are burned, and water and formation soflds are collected into a pit for later disposal. Stable foams must be destabili2ed to separate the air from the Hquid phase for disposal. 

Stable Foam. When a well is drilled with stable foam as the drilling fluid, there is a back pressure valve at the blooey line. The back pressure valve allows for a continuous column of foam in the annulus while drilling operations are under way. Thus, while drilling, this foam column can have significant bottom-hole pressure. This bottomhole pressure can be sufficient to counter formation pore pressure and thus control potential production fluid flow into the well annulus. 

The primary factor controlling how much gas is in the form of discontinuous bubbles is the lamellae stability. As lamellae rupture, the bubble size or texture increases. Indeed, if bubble coalescence is very rapid, then most all of the gas phase will be continuous and the effectiveness of foam as a mobility-control fluid will be lost. This paper addresses the fundamental mechanisms underlying foam stability in oil-free porous media. 

This study was reported with another set of experiments that confirmed the growth of fibroblasts in connection with an experimental bum dressing. " While our work was positive enough to warrant further research, a technical problem prevented continued work. While we felt the surface chemistry was a necessary component of a successful artificial liver, it was not sufficient. In order to build a successful device, fluids must be able to enter and exit the environment freely. We discussed the differences in structure between open-celled polyurethanes and reticulated foam earlier. 

Acid-in-oil emulsion can extend the propagation of acid considerable distances into a reservoir because the continuous (oil) phase prevents or minimizes contact between the acid and the rock [4,678,689]. Emulsification also increases viscosity and will improve the distribution of the acid in layered and heterogeneous reservoirs. Acidizing foams are aqueous, in which the continuous phase is usually hydrochloric acid (carbonate reservoirs) or hydrofluoric acid (sandstone reservoirs), or a blend, together with suitable surfactants and other stabilizers [345,659]. Foaming an acidizing fluid increases its effective viscosity, providing mobility control when it is injected [678]. 

Achievement of low mobility ratios at the fronts between displacing and displaced fluids is of even greater concern in enhanced oil recovery than in waterflooding owing to the high costs and/or low viscosities of the injected fluids. One response to this concern has been the continuing effort to develop a fundamental understanding of so-called foam flow, which employs aqueous solutions of properly chosen surfactants at relatively low capillary numbers to reduce the effective mobility of low viscosity fluids (see 5,6 and papers on foam flow in this volume). 

If the foam phase is thought of as a pseudo continuous fluid with an apparent viscosity Vapp = it follows that Papp is greater than that of the aqueous liquid phase. (For the tests here, values of Uapp were on the order of 1 to 50 times that of water). Because of this, when foam and liquid move through a porous medium under an applied pressure drop, the foam, being the most viscous phase, must occupy a larger region of the pore space. Consequently, as observed, the gas saturation is increased over that of non-dispersed phase flow and the liquid permeability is correspondingly decreased. 

Final laboratory testing of CO2 foam was performed in Shell s CT facility (11-12L Tertiary miscible and immiscible CO2 corefloods, with and without foam mobility control, were scanned during flow at reservoir conditions. The cores were horizontally mounted continuous cylinders of Berea sandstone. Table I lists pertinent core and fluid data. 

Below we consider mostly liquid dispersions, i.e., dispersions with liquid continuous phase, such as foams, emulsions, and suspensions. Sometimes these are called complex fluids. 

Foams (cellular structures) made by expanding a material by growing bubbles in it [11]. A foam has at least two components. At a macroscopic scale, there are the solid and liquid phases. The solid phase can be a polymer, ceramic or metal. The fluid phase is a gas in most synthetic foams, and a liquid in most natural foams. At a microscopic scale, the solid phase may itself consist of several components. For example, the solid phase of an amorphous polystyrene foam has only one component. On the other hand, the solid phase of a polyethylene foam or a flexible polyurethane foam typically has two components. These components are the crystalline and amorphous phases in polyethylene foams, and the hard and soft phases formed by the phase separation of the hard and soft segment blocks in flexible polyurethane foams. The solid phase of a polyurethane foam may, in fact, have even more than two components, since additional reinforcing components such as styrene-acrylonitrile copolymer or polyurea particles are often incorporated [12,13]. The solid is always a continuous phase in a foam. Foams can generally be classified as follows, based on whether the fluid phase is co-continuous with the solid phase ... 

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