Explosives 334 Subject

The criteria for insensitive explosives subjected to ha2ard tests permit no reaction more violent than burning in slow and fast cook-off tests and fragment and bullet tests, no propagation in sympathetic detonation tests, no detonation when stmck by a shaped charge jet, no sustained burning when hit by a small fragment, and such special tests as may be required by the use of the explosive. 

Sprengstoff, m. explosive, -fiillung,/. explosive filler or charge, -kammer,/. explosives maga zine. -ladung, /. explosive ch ge. -wesen, n. all that concerns explosives, subject of explosives. 

This method of initiation is particularly important because of the function of detonators and booster explosives as discussed under the topic of explosives train technology in Volume 2, Chapter 5. In the larger context of secondary explosives it is often associated with the premature or unwanted functioning of explosives subjected to mechanical and other forms of shock. 

Explosion subjection to friction/shock can causa explosion. in case of fire Iwep tanks/drums cool by spraying with water, fight fire from sheltered location. 

Sharma, J., Hoffsommer, J.C., Glover, D.J., Coffey, C.S., Forbes, J.W., Liddiard, T.P., Elban, W.L., and Santiago, F., (1985), "Sub-Ignition Reactions at Molecular Levels in Explosives Subjected to Impact and Underwater Shock", Proceedings of the Eighth Symposium (International) on Detonation, Albuquerque, New Mexico, 725. 

Certain types of equipment are specifically excluded from the scope of the directive. It is self-evident that equipment which is already regulated at Union level with respect to the pressure risk by other directives had to be excluded. That is the case with simple pressure vessels, transportable pressure equipment, aerosols and motor vehicles. Other equipment, such as carbonated drink containers or radiators and piping for hot water systems are excluded from the scope because of the limited risk involved. Also excluded are products which are subject to a minor pressure risk which are covered by the directives on machinery, lifts, low voltage, medical devices, gas appliances and on explosive atmospheres. A further and last group of exclusions refers to equipment which presents a significant pressure risk, but for which neither the free circulation aspect nor the safety aspect necessitated their inclusion. 

This chapter concludes our discussion of applications of surface chemistry with the possible exception of some of the materials on heterogeneous catalysis in Chapter XVIII. The subjects touched on here are a continuation of Chapter IV on surface films on liquid substrates. There has been an explosion of research in this subject area, and, again, we are limited to providing just an overview of the more fundamental topics. 

A laser beam is capable of putting so much energy into a substance in a very short space of time that the substance rapidly expands and volatilizes. The resulting explosive shock wave travels through the sample, subjecting it to high temperatures and pressures for short times. This process is also known as ablation. 

When dispersed as a dust, adipic acid is subject to normal dust explosion hazards. See Table 3 for ignition properties of such dust—air mixtures. The material is an irritant, especially upon contact with the mucous membranes. Thus protective goggles or face shields should be worn when handling the material. Prolonged contact with the skin should also be avoided. Eye wash fountains, showers, and washing faciUties should be provided in work areas. However, MSDS Sheet400 (5) reports that no acute or chronic effects have been observed. 

Annual Proceedings of the Safety Seminars, Dept, of Defense, Explosive Safety Board, Washington, D.C. International symposia on explosives and closely related subjects are excellent sources of information, ie, international symposia on detonation symposia on combustion symposia on chemical problems connected with the stabiUty of explosives international pyrotechnics seminars symposia on compatibiUty of plastics and other materials with explosives, propellants, and pyrotechnics, and processing of explosives, propellants, and ingredients and symposia on explosives and pyrotechnics Mineral Industy Surveys, U.S. Bureau of Mines, Pittsburgh, Pa. Periodic pubhcations dedicated primarily to explosive studies in Propellants and Explosives Journal of Ha yardous Materials, and apparent consumption of industrial explosives and blasting agents in the United States. 

Ra.m Tensile. A ram tensile test has been developed to evaluate the bond-2one tensile strength of explosion-bonded composites. The specimen is designed to subject the bonded interface to a pure tensile load. The cross-section area of the specimen is the area of the aimulus between the outer and inner diameters of the specimen. The specimen typically has a very short tensile gauge length and is constmcted so as to cause failure at the bonded interface. The ultimate tensile strength and relative ductihty of the explosion-bonded interface can be obtained by this technique. 

Methanol is stable under normal storage conditions. Methanol is not subject to hazardous polymerization reactions, but can react violendy with strong oxidizing agents. The greatest hazard involved in handling methanol is the danger of fire or explosion. The NFPA classifies methanol as a serious fire hazard. 

Another safety issue to be considered which might be exacerbated in the reprocessing option is that the plutonium generated in power reactors, called reactor-grade plutonium because it is made up of a variety of plutonium isotopes, contains plutonium-241, which is subject to spontaneous fission (8). The mixture of isotopes makes it extremely difficult to build an effective nuclear weapon. However, an explosive device could be built using this mixture if control of detonation is sacrificed (48). 

The sulfur nitrides have been the subject of several reviews (206—208). Although no commercial appHcations have as yet been developed for these compounds, some interest was stimulated by the discovery that polythiazyl, a polymeric sulfur nitride, (SN), with metallic luster, is electroconductive (see Inorganic highpolymers) (208,209). Other sulfur nitrides are unstable. Tetrasulfur nitride is explosive and shock-sensitive. 

Bromates represent a potential fire and explosion hazard if heated, subjected to shock, or acidified. They should not be allowed to contact reactive organic matter, including paper and wood. Industrial quantities are packed in fiber dmms with polyethylene liners or in metal dmms. Laboratory quantities are supphed in glass bottles. For shipment, a yellow oxidizer label is required under DOT regulations. 

According to the National Board of Fire Underwriters, activated carbons normally used for water treatment pose no dust explosion ha2ard and are not subject to spontaneous combustion when confined to bags, dmms, or storage bins (64). However, activated carbon bums when sufficient heat is appbed the ignition point varies between about 300 and 600°C (65). 

CeUulose is soluble only in unusual and complex solvent systems. The subject has been reviewed (84—87). Commercially, dissolving pulps, which have lower molecular weights, are used along with strong alkaU and derivatization. CeUulose subjected to high temperature and pressure during the steam explosion process can be dissolved in strong base (88). 

Explosibility and Fire Control. As in the case of many other reactive chemicals, the fire and explosion hazards of ethylene oxide are system-dependent. Each system should be evaluated for its particular hazards including start-up, shut-down, and failure modes. Storage of more than a threshold quantity of 5000 lb (- 2300 kg) of the material makes ethylene oxide subject to the provisions of OSHA 29 CER 1910 for "Highly Hazardous Chemicals." Table 15 summarizes relevant fire and explosion data for ethylene oxide, which are at standard temperature and pressure (STP) conditions except where otherwise noted. 

Relationships Between Objects, Processes, and Events. Relationships can be causal, eg, if there is water in the reactor feed, then an explosion can take place. Relationships can also be stmctural, eg, a distiUation tower is a vessel containing trays that have sieves in them or relationships can be taxonomic, eg, a boiler is a type of heat exchanger. Knowledge in the form of relationships connects facts and descriptions that are already represented in some way in a system. Relational knowledge is also subject to uncertainty, especiaUy in the case of causal relationships. The representation scheme has to be able to express this uncertainty in some way. 

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